(4-Iodophenyl)boronic acid 4-碘苯硼酸
CAS 5122-99-6 MFCD01319014
化学结构图
SMILES: OB(O)c1ccc(I)cc1
化学属性
| Mol. Formula | C6H6BIO2 |
|---|---|
| Mol. Weight | 247.83 |
| Melting Point | 326-330°C |
| Solubility | 25 g/L |
| Boiling Point | 333.1°C at 760 mmHg |
别名和识别编码
| Chemical Name | (4-Iodophenyl)boronic acid |
|---|---|
| CAS Number | 5122-99-6 |
| Alfabeta Name | IODOPHENYLBORONICACID 4- |
| MDL Number | MFCD01319014 |
| Synonym | 4-Iodophenylboronic acid {LY} 4-Iodophenylboronic acid {} {LY} 4-Iodophenylboronic acid {} {} {LY} 4-Iodophenylboronic acid {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylbor |
| PubChem Substance ID | 151254 |
| Chemical Name Translation | 4-碘苯硼酸 |
| Reaxys-RN | 2936348 |
| InChIKey | PELJYVULHLKXFF-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00008579 |
| InChI | InChI=1S/C6H6BIO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H |
| Canonical SMILES | IC1=CC=C(B(O)O)C=C1 |
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分类
- {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
相关文献及参考
- 1. Qi, Q.; Shen, Q.; Lu, L., Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature J. Am. Chem. Soc. 15th ed., 134 , 6548-6551, (2012) 摘要
- 2. Chen, M.; et al. , C-X (X=Br, I) Bond-Tolerant Aerobic Oxidative Cross- Coupling: A Strategy to Selectively Construct ß-Aryl Ketones and Aldehydes Adv. Synth. Catal. 2-3th ed., 354 , 341-346, (2012)
- 3. Zhang, X.; et al. , An efficient and recyclable magnetic-nanoparticle-supported palladium catalyst for the Suzuki coupling reactions of organoboronic acids with alkynyl bromides Synthesis 18 , 2975-2983, (2011)
- 4. Inamoto, K.; et al. , Micellar system in copper-catalyzed hydroxylation of arylboronic acids: facile access to phenols Chem. Commun. 42th ed., 47 , 11775-11777, (2011) 摘要
- 5. Tang, J-S.; et al. , Efficient palladium-catalyzed Suzuki-Miyaura cross-coupling of iodoethynes with arylboronic acids under aerobic conditions Synthesis 17 , 2789-2795, (2011)
- 6. Matsuda, T.; et al. , Homocoupling of arylboronic acids catalyzed by simple gold salts Tetrahedron 37th ed., 52 , 4779-4781, (2011)
- 7. Li, H.; et al. , Synthesis of arylketones by ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids Chem. Commun. 27th ed., 47 , 7880-7882, (2011) 摘要
- 8. Wang, S.; et al. , CuI-catalyzed Suzuki coupling reaction of organoboronic acids with alkynyl bromides Tetrahedron 26th ed., 67 , 4800-4806, (2011)
- 9. Yahiaoui, S.; et al. , Chelation-Mediated Palladium(II)-Catalyzed Domino Heck-Mizoroki/Suzuki-Miyaura Reactions Using Arylboronic Acids: Increasing Scope and Mechanistic Understanding J. Org. Chem. 8th ed., 76 , 2433-2438, (2011) 摘要
- 10. Dickschat, A.; Studer, A., Radical Addition of Arylboronic Acids to Various Olefins und
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302 Harmful if swallowed 吞食有害
- H319 Causes serious eye irritation 严重刺激眼睛
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- 4-碘苯硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 AC35948DA 4-碘苯硼酸 4-iodophenylboronic acid 1 GR 345元 2010/06/21 359480250 4-碘苯硼酸 4-Iodophenylboronic acid 97% 25 GR 3459元 2010/06/21 359480010 4-碘苯硼酸 4-Iodophenylboronic acid 97% 1 GR 301元
- MOL 文件:5122-99-6.mol
- Sigma Aldrich:5122-99-6(sigmaaldrich)
- Acros Organics:4-碘苯硼酸 4-Iodophenylboronic acid(5122-99-6)
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