(Ethoxycarbonylmethyl)dimethylsulfonium bromide (乙氧基羰基甲基)二甲基溴化硫鎓

CAS 5187-82-6 MFCD00031604

化学结构图

5187-82-6
SMILES: CCOC(=O)C[S+](C)C.[Br-]

化学属性

Mol. FormulaC6H13BrO2S
Melting Point90-94 °C
TSCANo
Mol. Weight229.14

别名和识别编码

MDL NumberMFCD00830557
Synonym (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium b
EC Number225-968-3
CAS Number5187-82-6
Beilstein Registry Number4161472
InChIKeyJXFPTJYKYKVENJ-UHFFFAOYSA-M
Chemical Name(Ethoxycarbonylmethyl)dimethylsulfonium bromide
Chemical Name Translation(乙氧基羰基甲基)二甲基溴化硫鎓
PubChem Substance ID78861
InChIInChI=1S/C6H13O2S.BrH/c1-4-8-6(7)5-9(2)3;/h4-5H2,1-3H3;1H/q+1;/p-1
Canonical SMILESC[S+](CC(OCC)=O)C.[Br-]
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相关文献及参考

  • The derived ylide does not add to carbonyl compounds, although it does undergo 1,4-addition to enones, with formation of cyclopropanecarboxylic esters: Tetrahedron, 23, 545, (1967); J. Org. Chem., 34, 1240 (1969).
  • Review of the chemistry of sulfonium ylides: Russ. Chem. Rev., 50, 481 (1981).

安全信息

RTECSWR7600000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {}

系列性分类


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