2-Chloroprop-1-ene 2-氯丙-1-烯

CAS 557-98-2 MFCD00000859

化学结构图

557-98-2
SMILES: C=C(C)Cl

化学属性

Mol. FormulaCH3CCl=CH2
Mol. Weight77
Refractive indexn20/D 1.395(lit.)
Boiling Point23°C
Density0.899 g/mL at 25 °C(lit.)
Melting Point-138.6 °C(lit.)
Flash Point-34°(-29°F)
TSCAYes
Solubility不溶于水,溶于乙醇、乙醚等多数有机溶剂。

别名和识别编码

Chemical Name2-Chloroprop-1-ene
Synonym β-Chloropropene 2-Chloro-1-propene 2-chloro-propan ISOPROPENYL CHLORIDE 2-CHLOROPROP-1-ENE 2-氯丙烷,99% Propane,2-chloro- 2-CHLOROPROPENE 2-chloropropylene 2-CHLOROPROPYLENE 氯异丙烷 2-CHLORO-1-PROPENE Narcosop beta-Chloropropylene 2-Chlor-1-propen 2-Propylchloride ß-Chloropropylene Propene, 2-chloro- 1-propene,2-chloro- β-Chloropropylene propene, 2-chloro- Propane-2-chloro 2-chloropropane(isopropylchloride) 2-氯丙烯 异丙烯基氯 isopropenyl chloride iso-C3H7Cl 氯代异丙烷 beta-Chloropropene ISOPROPYL CHLORIDE 异丙基氯 2-Chlorpropen 2-Chloropropene-1 2-chloro-propene ISOPROPHYL CHLORIDE 1-propene, 2-chloro- 2-CHLOROPROPANE Isopropenyl chloride 2-chloro-1-propene 2-chloro-propen R280da 2-chloropropene propene,2-chloro- ß-Chloropropene 2-chloro-1-propen 2-chloro-prop-1-ene 2-氯-1-丙烯 异丙烯基氯 1-Methylvinyl chloride Isoprid 1-Methylvinylchloride 2-氯丙烷 Chlorodimethylmethane 2-Chlorprop-1-en 2-氯-1-丙烯 2-Chlorpropan 2-Chloro-1-propene, Isopropenyl chloride 1-Propene, 2-chloro- 2-Propyl chloride 2-氯代丙烷
MDL NumberMFCD00000859
CAS Number557-98-2
PubChem Substance ID87566143
EC Number209-187-5
Beilstein Registry Number1(4)737
Chemical Name Translation2-氯丙-1-烯
Merck Number14,5211
Reaxys-RN1361376
Wiswesser Line NotationGY1&U1
LabNetwork Molecule IDLN01741080
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分类

  • {Chemicalbook} 农药中间体: 杀菌剂中间体: 酰胺类杀菌剂
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
  • Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
  • Short: II/19c Title: Molecular Constants: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Constants of Diamagnetic Molecules Author: Demaison, J.; Hüttner, W.; Tiem

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECSUC7200000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P305+P351+P338+P337+P313
  • P303+P361+P353
Signal word Danger
Packing GroupI
UN Number UN 2456 3/PG 1 2456 UN2456
Risk Statements
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R12 Extremely flammable 极端易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R11 Highly flammable 非常易燃
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S29 Do not empty into drains 不要排入下水道;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S3 Keep in a cool place 保存在阴凉处;
Hazard Codes F+,Xi,Xn,F F+,Xi
Hazard Class3
Storage condition 0-10 0-10°C 2-8°C
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 267 gm/m3
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Lungs, Thorax, or Respiration - respiratory depression
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   UCPHAQ University of California, Berkeley, Publications in Pharmacology.
   (Berkeley, CA)  V.1-3, 1938-57.  Discontinued.  Volume(issue)/page/year:
   2,39,1941

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 umol/plate
REFERENCE :
   BCPCA6 Biochemical Pharmacology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1958-  Volume(issue)/page/year:
   29,2611,1980

其他信息

  • Sigma Aldrich:75-29-6(sigmaaldrich)
  • MOL 文件:75-29-6.mol
  • 毒性分级:中毒
  • 可燃性危险特性:易燃; 受热分解或燃烧产物含有毒氯化物气体
  • Sigma Aldrich:557-98-2(sigmaaldrich)
  • 急性毒性:口服- 大鼠 LD50 5000 毫克/ 公斤;
  • {Chemica
  • 方法二:由丙烯与无水氯化氢反应而得。将干燥的氯化氢与丙烯按摩尔比1:1.2混合,通入装有活性白土催化剂的反应器,在120-140℃反应,产物经冷凝即得2-氯丙烷。收率为65%。也可由异丙醇与氯化氢在氯化锌存在下反应而得。
  • 用途五:用作溶剂和用于异丙胺制造。
  • 上游原料:盐酸 --> 异丙醇 --> 氯化锌 --> 活性漂土CS-1040 --> 无水氯化氢
  • {Chemicalb
  • 图谱信息:2-氯丙烯(557-98-2)核磁图( 13 CNMR) 2-氯丙烯(557-98-2)质谱(MS) 2-氯丙烯(557-98-2)核磁图( 1 HNMR)
  • 蒸气压:28.11 psi ( 55 °C)
  • 2-氯丙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1112 2-氯-1-丙烯 2-Chloro-1-propene 10ML 1560元 2010/05/25 L12374 2-氯丙烯, 99% 2-Chloropropene, 99% 5g 416元 2010/05/25 L12374 2-氯丙烯, 99% 2-Chloropropene, 99% 25g 1362元
  • 下游产品:氰戊菊酯 --> 6-三氟甲基吡啶-3-醛 --> 残杀威 --> 3-甲基-5-溴吡啶-2-醛 --> 2,6-二甲基苯甲醛 --> 2-吡啶硼酸 --> α-异丙基对氯苯基乙腈 --> 溴灭菊酯 --> 氟担菌宁 --> α-异丙基对氯苯基乙酸 --> 噻唑-5-甲酸 --> 百里酚 --> 毒草安 --> 异丙基氯化镁 --> 2-异丙氧基苯酚 --> 5-溴噻唑 --> 3-醛基-6-甲基吡啶 --> 3-甲基-4-异丙基苯酚 --> 达舒平 --> 3-氨基苯异丙醚
  • 灭火剂:干粉, 泡沫, 二氧化碳, 1211, 砂土
  • 用途三:2-氯丙烷是杀菌剂灭锈胺、氟酰胺,杀虫剂氰戊菊酯、氟氰戊菊酯、残杀威,除草剂毒草胺、莎稗磷的中间体。
  • 方法一:其制备方法有以下几种。 (1)在反应瓶中加入异丙醇和催化剂氯化锌,通入氯化氢,在适宜的温度下反应得到2-氯丙烷,蒸馏即得成品。 (2)由丙烯与无水氯化氢反应,在活性土催化剂存在下进行,将干燥的氯化氢与碱洗后的丙烯以摩尔比1∶1.2进入混合器,再进入催化反应器,于120~140℃反应,产品经冷却得成品。
  • MOL 文件:557-98-2.mol
  • 类别:易燃液体
  • 爆炸物危险特性:受热. 明火可爆; 与空气混合形成爆炸性混合物
  • 用途四:有机合成原料,用于制农药毒草胺,也用作溶剂。
  • 用途一:用作农药中间体、有机合成原料、溶剂等
  • 下游产品:丙烯醇
  • 急性毒性:吸入-小鼠 LC50: 267 克/ 立方米
  • TCI Shanghai:2-氯-1-丙烯 2-Chloro-1-propene,>;95.0%(GC)(557-98-2)
  • Alfa Aesar:2-氯丙烯,99% 2-Chloropropene, 99%(557-98-2)
  • {Che
  • 2-氯丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80110826 氯代异丙烷(*) 100ml 50.3元 2011/04/16 C0267 2-氯丙烷 2-Chloropropane 500ML 380元 2011/04/16 C0267 2-氯丙烷 2-C

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