Triisopropoxyvanadium(V) oxide 三异丙氧基氧化钒(V)

CAS 5588-84-1 MFCD00015017

化学结构图

5588-84-1
SMILES: CC(C)O[V](=O)(OC(C)C)OC(C)C

化学属性

Mol. FormulaC9H21O4V
Mol. Weight244.20
Refractive index1.4780 to 1.4820
Boiling Point102°C/9mmHg(lit.)
Density1.04(lit.)
Flash Point70°C(lit.)
TSCAYes
Melting Point-11 °C
Appearance light yellow to light green liq.
Stabilitymoisture sensitive

别名和识别编码

Chemical NameTriisopropoxyvanadium(V) Oxide
Synonym Vanadium(V) oxytriisopropoxide {LY} Vanadium(V) oxytriisopropoxide {} {LY} Vanadium(V) oxytriisopropoxide {} {} {LY} Vanadium(V) oxytriisopropoxide {} {} {} {LY} Vanadium(V) oxytriisopropoxide {} {} {} {} {LY} Vanadium(V) oxytriisopropoxide {} {} {} {} {} {LY} Vanadium(V) oxytriisopropoxide {} {} {} {} {} {} {LY} Vanadium(V) oxytriisopropoxide {} {} {} {} {} {} {} {LY} Vanadium(V) oxytriisopropoxide {} {} {} {} {} {} {} {} {LY} Vanadium(V) oxytriisopropoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vanadium(V) oxytriisopropoxide {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Vanadium(V) oxytriisopropoxide {} {} {} {} {} {} {} {} {} {} {} {LY} Vanadium(V) oxytriisopropoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vanadium(V) oxytriisopropoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vanadium(V) oxytriisopropoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number5588-84-1
PubChem Substance ID79702
EC Number226-997-4
MDL NumberMFCD00015017
Reaxys-RN3662904
Beilstein Registry Number1(1)184
Chemical Name Translation三异丙氧基氧化钒(V)
InChIKeyDSGGJXAUQHKOGQ-UHFFFAOYSA-N
LabNetwork Molecule IDLN01743831
Canonical SMILESO=[V](OC(C)C)(OC(C)C)OC(C)C
InChIInChI=1S/3C3H8O.O.V/c3*1-3(2)4;;/h3*3-4H,1-2H3;;
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分类

  • {SNA} 23: Vanadium, CVD and ALD Precursors Packaged for Deposition Systems, CVD and ALD Precursors by Metal, Micro/NanoElectronics, Vanadium, Vapor Deposition Precursors, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Solution Deposition Precursors,
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Vanadium
  • {SNA} 23: Vanadium, CVD and ALD Precursors Packaged for Deposition Systems, CVD and ALD Precursors by Metal, Materials Science, Micro/NanoElectronics, Vanadium, Vapor Deposition Precursors
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Catalysis and Inorgan

相关文献及参考

  • Short: III/38A Title: Refractive Indices of Inorganic, Organometallic, and Organononmetallic Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38A Year: 1996 Keyword: organicmetallic compounds; inorganic compounds; refractive index; liquids; mixtures ISBN: 3-540-60539-8 ISBN: 978-3-540-60539-3 Internet Resource: DOI:10.1007/b55612 RefComment: VII, 400 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: IV/6 Title: Static Dielectric Constants of Pure Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch. Editor: Madelung, O. Source: Landolt-Börnstein, New Series Volume: IV/6 Year: 1991 Keyword: organic compounds; dielectric constant; liquids; mixtures ISBN: 3-540-54417-8 ISBN: 978-3-540-54417-3 Internet Resource: DOI:10.1007/b44266 RefComment: VIII, 521 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Jo
  • Beil. 1 ,IV,1242
  • FT-IR 2 (3), 4493:C / Structure Index 1 , 484:D:8

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S37 Wear suitable gloves 戴适当手套；
UN Number 1993
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Flammables area Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {}
Packing GroupIII
Hazard Class3
Restrict 危险品

其他信息

  • TCI Shanghai:三异丙氧基氧化钒 Triisopropoxyvanadium(V) Oxide,>;97.0%(T)(5588-84-1)
  • MOL 文件:5588-84-1.mol
  • 敏感性:Moisture Sensitive
  • Alfa Aesar:Vanadium(V) triisopropoxide oxide, 96%(5588-84-1)
  • Acros Organics:Triisopropoxyvanadium(V) oxide(5588-84-1)
  • 三异丙氧基氧化钒价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T2548 三异丙氧基氧化钒(V) Triisopropoxyvanadium(V) Oxide 5G 530元 2014/06/02 T2548 三异丙氧基氧化钒(V) Triisopropoxyvanadium(V) Oxide 25G 1370元 2010/05/25 89798 Vanadium(V) triisopropoxide oxide, 96% 1g 160元
  • Sigma Aldrich:5588-84-1(sigmaaldrich)
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Vanadium - Catalysis and Inorganic Chemistry
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors Packaged for Deposition Systems - Vapor Deposition Precursors
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Vanadium (V) Solution Deposition Precursors
  1. CVD & ALD Precursors
  1. Alkoxide
  2. Vanadium
  1. CVD & ALD Precursors
  2. Vanadium
  1. Metal Alkoxides for CVD & ALD
  2. Vanadium

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