Phenylhydrazine Hydrochloride 苯肼盐酸盐

CAS 59-88-1 MFCD00012924

化学结构图

59-88-1
SMILES: Cl.NNc1ccccc1

化学属性

Mol. FormulaC6H9ClN2
Mol. Weight145
Melting Point250-254 °C (dec.) (lit.)
TSCAYes
Solubility溶于水（50 mg/ml）和乙醇，不溶于醚。
Density1.125
Stability对光，空气和湿度敏感

别名和识别编码

Chemical NamePhenylhydrazine Hydrochloride
CAS Number59-88-1
Alfabeta NamePHENYLHYDRAZINEHYDROCHLORIDE
MDL NumberMFCD00012924
PubChem Substance ID87574433
EC Number200-444-7
Beilstein Registry Number15,67
Synonym PHENYLHYDRAZINIUM CHLORIDE R. G. PHENYLHYDRAZINE HYDROCHLORIDE Phenylhyfrazine hydrocholoride Phenylhydrazine monohydrochloride Hydrazine, phenyl-, monohydrochloride 苯肼盐酸盐,苯基联氨盐酸盐,肼基苯盐酸盐 phenyl-hydrazinhydrochloride PHENYLHYDRAZINE HYDROCHLORIDE, FOR THE D ETECTION OF SUGAR Phenylhydrazinium chloride PHENYLHYDRAZINE CHLORHYDRATE 苯肼 盐酸盐 Hydrazine,phenyl-,monohydrochloride phenylhydrazinemonohydrochloride 苯肼盐酸 HYDRAZINOBENZENE HYDROCHLORIDE PHENYLHYDRAZINE HYDROCHLORIDE REAGENT Phenylhydrazine hydrochloride PhenylHydrazineHydrochlorideGr PHNEYLHYDRAZINE HYDROCHLORIDE 苯肼单盐酸盐 苯肼盐酸盐
Reaxys-RN3594958
Merck Number7293
Chemical Name Translation苯肼盐酸盐
Wiswesser Line NotationZMR &GH
LabNetwork Molecule IDLN00141178
InChIInChI=1S/C6H8N2.ClH/c7-8-6-4-2-1-3-5-6;/h1-5,8H,7H2;1H
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Food & Beverage, Reagents for Analysis of Carbohydrates, Reagents for Food Analysis, 特定应用试剂
  • {SA} Building Blocks, Chemical Synthesis, Hematology and Histology, Hydrazines, Nitrogen Compounds, Organic Building Blocks,

产品应用

  • 醛、酮和糖的特殊试剂。主要用于合成农药、医药、染料及合成其它有机物。

相关文献及参考

  • Merck:14,7293 Beilstein:15,67
  • Merck:14,7293

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H350 May cause cancer 可能致癌
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H301+H311+H331
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes T,N T;N
RTECSMV9000000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310+P330
  • P308+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P403+P233
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+P350
  • P337+P313
  • P304+P340+P311
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P305+P351+P338+P337+P313
  • P302+P352+P312+P361+P364
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
Signal word Danger
UN Number UN 2811 6.1/PG 3 2811 UN2811
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R48/23/24/25
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R45 May cause cancer 可能致癌
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R50 Very toxic to aquatic organisms 对水生生物极毒
Packing GroupIII
Hazard Class6.1
Storage condition -20°C 充氩保存 密封阴凉干燥避光保存。 
TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 928 mg/kg/8W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   42,337,1969

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10 gm/kg/58W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Vascular - tumors
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   ZKKOBW Zeitschrift fuer Krebsforschung und Klinische Onkologie.  (Berlin,
   Fed. Rep. Ger.)  V.76-92, 1971-78.  For publisher information, see JCROD7.
   Volume(issue)/page/year: 87,267,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 464 mg/kg/8W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   42,337,1969

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 8000 mg/kg/42W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   34ZRA9 "Proceedings of the Quadrennial Conference on Cancer, 3rd, 1965,"
   Severi, L., ed., Perugia, Italy, Univ. of Perugia,

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - cyanosis
   Skin and Appendages - corrosive (after topical exposure)
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   FAATDF Fundamental and Applied Toxicol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 161 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ABMGAJ Acta Biologica et Medica Germanica.  (Berlin, Ger. Dem. Rep.) V.1-41,
   1958-82.  For publisher information, see BBIADT. Volume(issue)/page/year:
   18,617,1967

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECI

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 900 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   QJDRAZ Quarterly Journal of Crude Drug Research.  (Lisse, Netherlands)
   V.1-19, 1961-81.  For publisher information, see IJCREE.
   Volume(issue)/page/year: 9,1455,1969

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST            : LD

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 800 ug/plate
REFERENCE :
   NEZAAQ Nippon Eiseigaku Zasshi.  Japanese Journal of Hygiene.  (Nippon Eisei
   Gakkai, c/o Kyoto Daigaku Igakubu, Konoe-cho, Yoshida, Sakyo-ku, Kyoto 606,
   Japan)  V.1-    1946-  Volume(issue)/page/year: 33,474,1978

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Rodent - mouse Liver
DOSE/DURATION           : 10 umol/L
REFERENCE :
   JJCREP Japanese Journal of Cancer Research. (Elsevier Science Pub. BV, POB
   211, 1000 AE Amsterdam, Netherlands)  V.76-    1985-
   Volume(issue)/page/year: 79,204,1988

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 10 umol/L
REFERENCE :
   JJCREP Japanese Journal of Cancer Research. (Elsevier Science Pub. BV, POB
   211, 1000 AE Amsterdam, Netherlands)  V.76-    1985-
   Volume(issue)/page/year: 79,204,1988

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 30 mg/kg
SEX/DURATION            : female 17-19 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - behavioral
REFERENCE :
   SEIJBO Senten Ijo.  Congenital Anomalies.  (Nippon Senten Ijo Gakkai, c/o
   Kinki Daigaku Igakubu Kaibagaku Kyoshitsu, 380 Nishiyama, Sayama-cho,
   Mirami-Kawachi-gun, Osaka-fu, Japan) V.1-26, 1960-86. For publisher
   information, see CGANE7.  Volume(issue)/page/year: 14,95,1974

其他信息

  • 毒性分级:中毒
  • 急性毒性:口服-小鼠 LD50: 2100 毫克/公斤
  • Sigma Aldrich:59-88-1(sigmaaldrich)
  • 用途二:用作医药、农药中间体及染料中间体。
  • 用途三:醛、酮和糖的特殊试剂。主要用于合成农药、医药、染料及合成其它有机物。
  • Alfa Aesar:苯肼盐酸盐,99% Phenylhydrazine hydrochloride, 99%(59-88-1)
  • 可燃性危险特性:明火可燃; 受热放出有毒氯化氢和氧化氮气体
  • MOL 文件:59-88-1.mol
  • 盐酸苯肼价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80100714 盐酸苯肼 25g 30.8元 2011/08/23 80100724 盐酸苯肼 25g 25.7元 2011/04/16 P0184 苯肼盐酸盐 Phenylhydrazinium Chloride 25G 208元
  • F:3-8-10-23
  • 类别:有毒物品
  • 对光和湿敏感。能升华。易溶于水，溶于乙醇，几乎不溶于乙醚。加入浓盐酸则从溶液中析出沉淀。有毒，最小致死量(兔，经口)25mg/kg。有致癌可能性。
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • MSDS 信息:Phenylhydrazine hydrochloride(59-88-1).msds
  • TCI Shanghai:苯肼盐酸盐 Phenylhydrazinium Chloride,>;98.5%(T)(59-88-1)
  • 上游原料:盐酸 --> 氨基苯
  • 外观性质:白色叶片状结晶。对光和湿敏感。能升华。易溶于水，溶于乙醇，几乎不溶于乙醚。加入浓盐酸则从溶液中析出沉淀。有毒，最小致死量(兔，经口)25mg/kg。有致癌可能性。熔点：243-246℃
  • 图谱信息:盐酸苯肼(59-88-1)核磁图( 13 CNMR) 盐酸苯肼(59-88-1)核磁图( 1 HNMR) 盐酸苯肼(59-88-1)红外图谱(IR2) 盐酸苯肼(59-88-1)红外图谱(IR1) 盐酸苯肼(59-88-1)Raman光谱
  • Acros Organics:盐酸苯肼 Phenylhydrazine hydrochloride, 99+%(59-88-1)
  • 灭火剂:水、二氧化碳、砂土、泡沫
  • 下游产品:三唑磷 --> 甲基磺酰甲胺 --> 三唑磷乳油 --> 4-硝基苯肼 --> 1-苯基-5-三氟甲基-1H-吡唑-4-胺 --> 螺[1,3,3-三甲基吲哚-苯并二氢吡喃] --> 1-苯基-5-三氟甲基-1H-吡唑-4-腈 --> 1-苯基-5-三氟甲基吡唑-4-酰氯 --> (1-苯基-5-三氟甲基-1H-吡唑-4-基)甲醇 --> (1-苯基-5-三氟甲基-1H-吡唑-4-基)甲胺 --> 1-苯基-5-三氟甲基-1H-吡唑-4-酰胺 --> 1-苯基-5-三氟甲基-1H-吡唑-4-羧酸 --> 1-苯基-5-三氟甲基-1H-吡唑-4-羧酸乙酯 --> 6-羟基-2-苯基-3-哒酮 --> 苯胺基硫脲
  • 海关编码:29280090
  • 用途一:用作医药、农药及染料中间体

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Application Specific Reagents - Analytical Reagents
  4. Food & Beverage - Application Specific Reagents
  5. Reagents for Food Analysis - Food & Beverage
  6. Reagents for Analysis of Carbohydrates - Reagents for Food Analysis
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds

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