(Ethylsulfonyl)Benzene 乙基苯基砜

CAS 599-70-2 MFCD00025081

化学结构图

599-70-2
SMILES: CCS(=O)(=O)c1ccccc1

化学属性

Mol. FormulaC8H10O2S
Mol. Weight170.23
Melting Point35-40 °C
Density1.14
TSCANo
Flash Point>;230 °F
Boiling Point103 °C at 1 mmHg

别名和识别编码

Chemical Name(Ethylsulfonyl)Benzene
CAS Number599-70-2
Alfabeta NameETHYLPHENYLSULFONE
MDL NumberMFCD00025081
Synonym Ethyl phenyl sulfone {LY} Ethyl phenyl sulfone {} {LY} Ethyl phenyl sulfone {} {} {LY} Ethyl phenyl sulfone {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {} {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {} {} {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenyl sulfone {} {} {} {} {} {} {} {} {} {} {}
EC Number209-972-2
Beilstein Registry Number2045095
PubChem Substance ID69032
Reaxys-RN2045095
Chemical Name Translation乙基苯基砜
InChIKeyVBQUDDWATQWCPP-UHFFFAOYSA-N
LabNetwork Molecule IDLN00117412
InChIInChI=1S/C8H10O2S/c1-2-11(9,10)8-6-4-3-5-7-8/h3-7H,2H2,1H3
Canonical SMILESO=S(=O)(C=1C=CC=CC1)CC
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分类

  • {SNA} Building Blocks, Chemical Synthesis, E, Organic Building Blocks, Sulfones, Sulfur Compounds, 生物活性小分子, 细胞生物学
  • {SNA} Bioactive Small Molecules, Building Blocks, Cell Biology, Chemical Synthesis, E,
  • {SNA} Bioactive Small Molecule Alphabetical Index, Building Blocks, Chemical Synthesis, E, Organic Building Blocks, Sulfones, Sulfur Compounds, 生物活性小分子, 细胞生物学
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfones, Sulfur Compounds

相关文献及参考

  • Short: II/27B
  • Short: III/35E
  • Adds to aldehydes and ketones in the presence of base, e.g. n-BuLi, to give ß-hydroxy sulfones. Conversion of the OH to, e.g. mesylate, and elimination/desulfurative reduction with sodium amalgam provides a stereospecific route to (E)-alkenes (the Julia olefination reaction): Tetrahedron Lett., 4833 (1973); J. Chem. Soc., Perkin 1, 829 (1978):

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Hazard Codes Xi
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Alfa Aesar:苯乙硫醚,98+% Ethyl phenyl sulfone, 98+%(599-70-2)
  • Sigma Aldrich:599-70-2(sigmaaldrich)
  • MOL 文件:599-70-2.mol
  • TCI Shanghai:乙基苯基砜 Ethyl Phenyl Sulfone,>;97.0%(GC)(599-70-2)
  • Hazard Note:Irritant
  • 图谱信息:乙基苯基砜(599-70-2)质谱(MS) 乙基苯基砜(599-70-2)核磁图( 1 HNMR) 乙基苯基砜(599-70-2)红外图谱(IR1) 乙基苯基砜(599-70-2)核磁图( 13 CNMR) 乙基苯基砜(599-70-2)红外图谱(IR2)
  • Acros Organics:乙基苯基砜 Ethyl phenyl sulfone, 98%(599-70-2)
  • 乙基苯基砜价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 E0427 乙基苯基砜 Ethyl Phenyl Sulfone 10G 1210元 2010/06/21 351010050 乙基苯基砜 Ethyl phenyl sulfone 98% 5 GR 744元 2010/06/21 351010010 乙基苯基砜 Ethyl phenyl sulfone 98% 1 GR 312元
  • 乙基苯基砜价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0427 乙基苯基砜 Ethyl Phenyl Sulfone 10G 1150元 2010/06/21 351010050 乙基苯基砜 Ethyl phenyl sulfone 98% 5 GR 744元 2010/06/21 351010010 乙基苯基砜 Ethyl phenyl sulfone 98% 1 GR 312元

系列性分类

  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Bioactive Small Molecules - Cell Biology
  4. E - Bioactive Small Molecules
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfones - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiols/Mercaptans - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfur Compounds for Organic Synthesis 有机合成硫化物

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