Triphenylarsine 三苯基胂

CAS 603-32-7 MFCD00002994

化学结构图

603-32-7
SMILES: c1ccc([As](c2ccccc2)c2ccccc2)cc1

化学属性

Mol. FormulaC18H15As
Mol. Weight306.23
Melting Point58-61 °C
Flash Point265°(509°F)
TSCAYes
Boiling Point360 °C at 760 mmHg
Density1,225 g/cm3

别名和识别编码

Chemical NameTriphenylarsine
Synonym Triphenylarsane {LY} Triphenylarsane {} {LY} Triphenylarsane {} {} {LY} Triphenylarsane {} {} {} {LY} Triphenylarsane {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00002994
PubChem Substance ID11773
CAS Number603-32-7
EC Number210-032-9
Reaxys-RN1842037
Beilstein Registry Number16,828
Chemical Name Translation三苯基胂
LabNetwork Molecule IDLN00004606
InChIInChI=1S/C18H15As/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
Canonical SMILES[As](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
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分类

  • {SNA} Arsenic, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Vapor Deposition Precursors, 材料科学
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Arsenic, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors
  • {SA} Arsenic, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors

相关文献及参考

  • Short: III/35C4
  • Short: II/3
  • Can be cleaved to sodium diphenylarsenide by Na metal. A mole of PhNa is also produced, but can be selectively destroyed by protonation with NH4Br: Chem. Ber., 100, 1230 (1967). For use in the preparation of chelating ligands, see: Synthesis, 350 (1979). Similarly, Li metal gives Li diphenylarsenide: J. Org. Chem., 32, 2627 (1967). For a review of the chemistry of metal arsenides, see: Synthesis, 328 (1974).
  • Short: III/20b
  • Preferred to phosphines as a ligand in certain metal-catalyzed coupling reactions, e.g. in the Pd catalyzed Stille coupling of aryl stannanes with aryl halides: Tetrahedron Lett., 36, 2191 (1995), of silylated allylic stannanes with alkyl halides: J. Org. Chem., 60, 4647 (1995), the Pd catalyzed homocoupling of organostannanes: Synth. Commun., 27, 641 (1997), the Pd catalyzed coupling of aryl- or alkynylzinc chlorides with alkenyl halides: Synlett, 344 (1995), or the Suzuki coupling of arylboronic acids with sensitive halides: Org. Synth., 75, 69 (1997).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P301+P310+P330
  • P304+P340
  • P304+P340+P311
  • P308+P313
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H301+H331
  • H331 Toxic if inhaled 吸入中毒
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Hazard Codes T,N
Signal word Danger
RTECSCH8942500
UN Number UN 3465 6.1/PG 2 UN3465 3465
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S20/21 When using do not eat, drink or smoke 使用时,不得进食,饮水或吸烟;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R50/53
Packing GroupIII
Hazard Class6.1
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 6,373,1954

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • Alfa Aesar:三苯基胂,98% Triphenylarsine, 98%(603-32-7)
  • Acros Organics:三苯基胂 Triphenylarsine, 97%(603-32-7)
  • TCI Shanghai:三苯基胂 Triphenylarsine,>;95.0%(T)(603-32-7)
  • 三苯基胂价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0508 三苯基胂 Triphenylarsine 5G 290元 2010/06/21 140330250 三苯基胂 Triphenylarsine 97% 25 GR 693元 2010/05/25 L03616 三苯基胂, 98% Triphenylarsine, 98% 5g 223元
  • Sigma Aldrich:603-32-7(sigmaaldrich)
  • 图谱信息:三苯基胂(603-32-7)红外图谱(IR1) 三苯基胂(603-32-7)核磁图( 13 CNMR) 三苯基胂(603-32-7)质谱(MS) 三苯基胂(603-32-7)核磁图( 1 HNMR) 三苯基胂(603-32-7)红外图谱(IR2)
  • MOL 文件:603-32-7.mol
  • TSCA:Yes

系列性分类


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