Triphenylarsine 三苯基胂

CAS 603-32-7 MFCD00002994

化学结构图

603-32-7
SMILES: c1ccc([As](c2ccccc2)c2ccccc2)cc1

化学属性

Mol. FormulaC18H15As
Mol. Weight306.23
Melting Point58-61 °C
Flash Point265°(509°F)
TSCAYes
Boiling Point360 °C at 760 mmHg
Density1,225 g/cm3

别名和识别编码

Chemical NameTriphenylarsine
Synonym Triphenylarsane {LY} Triphenylarsane {} {LY} Triphenylarsane {} {} {LY} Triphenylarsane {} {} {} {LY} Triphenylarsane {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylarsane
MDL NumberMFCD00002994
PubChem Substance ID11773
CAS Number603-32-7
EC Number210-032-9
Reaxys-RN1842037
Beilstein Registry Number16,828
Chemical Name Translation三苯基胂
LabNetwork Molecule IDLN00004606
InChIInChI=1S/C18H15As/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
Canonical SMILES[As](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
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分类

  • {SNA} Arsenic, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Vapor Deposition Precursors, 材料科学
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Arsenic, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors
  • {SA} Arsenic, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors

相关文献及参考

  • Short: III/35C4
  • Short: II/3
  • Can be cleaved to sodium diphenylarsenide by Na metal. A mole of PhNa is also produced, but can be selectively destroyed by protonation with NH4Br: Chem. Ber., 100, 1230 (1967). For use in the preparation of chelating ligands, see: Synthesis, 350 (1979). Similarly, Li metal gives Li diphenylarsenide: J. Org. Chem., 32, 2627 (1967). For a review of the chemistry of metal arsenides, see: Synthesis, 328 (1974).
  • Short: III/20b
  • Preferred to phosphines as a ligand in certain metal-catalyzed coupling reactions, e.g. in the Pd catalyzed Stille coupling of aryl stannanes with aryl halides: Tetrahedron Lett., 36, 2191 (1995), of silylated allylic stannanes with alkyl halides: J. Org. Chem., 60, 4647 (1995), the Pd catalyzed homocoupling of organostannanes: Synth. Commun., 27, 641 (1997), the Pd catalyzed coupling of aryl- or alkynylzinc chlorides with alkenyl halides: Synlett, 344 (1995), or the Suzuki coupling of arylboronic acids with sensitive halides: Org. Synth., 75, 69 (1997).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P301+P310+P330
  • P304+P340
  • P304+P340+P311
  • P308+P313
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H301+H331
  • H331 Toxic if inhaled 吸入中毒
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Hazard Codes T,N
Signal word Danger
RTECSCH8942500
UN Number UN 3465 6.1/PG 2 UN3465 3465
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S20/21 When using do not eat, drink or smoke 使用时，不得进食，饮水或吸烟；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R50/53
Packing GroupIII
Hazard Class6.1 
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 6,373,1954

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Alfa Aesar:三苯基胂,98% Triphenylarsine, 98%(603-32-7)
  • Acros Organics:三苯基胂 Triphenylarsine, 97%(603-32-7)
  • TCI Shanghai:三苯基胂 Triphenylarsine,>;95.0%(T)(603-32-7)
  • 三苯基胂价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0508 三苯基胂 Triphenylarsine 5G 290元 2010/06/21 140330250 三苯基胂 Triphenylarsine 97% 25 GR 693元 2010/05/25 L03616 三苯基胂, 98% Triphenylarsine, 98% 5g 223元
  • Sigma Aldrich:603-32-7(sigmaaldrich)
  • 图谱信息:三苯基胂(603-32-7)红外图谱(IR1) 三苯基胂(603-32-7)核磁图( 13 CNMR) 三苯基胂(603-32-7)质谱(MS) 三苯基胂(603-32-7)核磁图( 1 HNMR) 三苯基胂(603-32-7)红外图谱(IR2)
  • MOL 文件:603-32-7.mol
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Arsenic - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Arsenic Compounds 砷化合物
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Arsenic - CVD and ALD Precursors by Metal
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Antimony

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