(4S)-4-(Chloromethyl)-2,2-Dimethyl-1,3-Dioxolane (S)-(-)-4-氯甲基-2,2-二甲基-1,3-二氧戊环

CAS 60456-22-6 MFCD00273365

化学结构图

60456-22-6
SMILES: CC1(C)OC[C@@H](CCl)O1

化学属性

Mol. FormulaC6H11ClO2
Mol. Weight151
Refractive index1.4330 to 1.4370
Boiling Point63
Density1.103
Flash Point53°C(lit.)
TSCANo

别名和识别编码

Chemical Name(4S)-4-(Chloromethyl)-2,2-Dimethyl-1,3-Dioxolane
CAS Number60456-22-6
PubChem Substance ID87566750
MDL NumberMFCD00273365
Reaxys-RN7409638
Beilstein Registry Number19(5)1,85
Synonym (S)-(-)-3-Chloro-1,2-propanediol acetonide
Chemical Name Translation(S)-(-)-4-氯甲基-2,2-二甲基-1,3-二氧戊环
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Protected Alcohols
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Protected Alcohols

相关文献及参考

  • Beil. 19 ,IV,70

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 3 T
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P310
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
RTECSJH6950000
UN Number 1992 1993 UN1992
Risk Statements
  • R10 Flammable 易燃
  • R25 Toxic if swallowed 吞咽有毒
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Packing GroupIII
Hazard Class3/6.1

系列性分类


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