(S,S)-BPPM (2S,4S)-4-二苯基膦-2-(二苯基膦甲基)-1-特丁氧羰基吡咯烷

CAS 61478-28-2 MFCD01631275

化学结构图

61478-28-2
SMILES: CC(C)(C)OC(=O)N1C[C@H](C[C@H]1CP(C1=CC=CC=C1)C1=CC=CC=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

化学属性

Mol. FormulaC34H37NO2P2
Mol. Weight553.61
Melting Point96-100 °C
TSCANo
Appearance white pwdr.
Stabilityair sensitive

别名和识别编码

Chemical Name(S,S)-BPPM
MDL NumberMFCD01631275
Synonym (2S,4S)-1-Boc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine BPPM (2S,4S)-BPPM (2S,4S)-1-叔丁氧基羰基-4-二苯基膦-2-(二苯基膦基甲基)吡咯烷
CAS Number61478-28-2
PubChem Substance ID57647836
Beilstein Registry Number466510
Chemical Name Translation(2S,4S)-4-二苯基膦-2-(二苯基膦甲基)-1-特丁氧羰基吡咯烷
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Heterocyclic Building Blocks, Hydrogenation, Pyrrolidines

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Hydrogenation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Heterocyclic Building Blocks - Chiral Building Blocks
  5. Pyrrolidines - Heterocyclic Building Blocks
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus

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