3-Methylthiophene 3-甲基噻吩

CAS 616-44-4 MFCD00005470

化学结构图

616-44-4
SMILES: CC1CCSC1

化学属性

Mol. FormulaC5H6S
Mol. Weight98.16
Density1.016
Refractive index1.5180 to 1.5210
Boiling Point114
Melting Point-69
Vapor Pressure42.4 mmHg ( 37.7 °C)
Flash Point11°C(lit.)
TSCAYes
SolubilitySoluble in water (0.4 mg/ml at 25 °C), ethanol, ether, acetone, and benzene.
pH:A

别名和识别编码

Chemical Name3-Methylthiophene
CAS Number616-44-4
Synonym {uni_hamburg} 3-Methylthiophene,98% 3-Methylthiophene, 99+% 3-甲基噻吩 ?-Methylthiophene β-Methylthiophene Thiophene, 3-methyl- β-Thiotolen methyl-3 thiophene 3-甲基噻吩,98% 3-Thiotolene 3-甲基噻吩(3-METHYLTHIOPHENE) thiophene, 3-methyl- 4-Methylthiophene 3-甲基噻吩,甲基硫茂 3-methyl-thiophen beta-Methylthiophene 3-Methylthiophene 3MT beta-methylthiophene 甲基硫茂 3-METHYLTHIOPHENE Methyl-3-thiophene 3-methyl-thiophene 3-Methyl-thiophen 3-methylthiophene
MDL NumberMFCD00005470
EC Number210-482-6
Beilstein Registry Number17(5)1,331
PubChem Substance ID12024
Reaxys-RN1300
Chemical Name Translation3-甲基噻吩
InChIKeyQENGPZGAWFQWCZ-UHFFFAOYSA-N
Wiswesser Line NotationT5SJ C1
LabNetwork Molecule IDLN00142031
InChIInChI=1S/C5H6S/c1-5-2-3-6-4-5/h2-4H,1H3
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分类

  • Pharmaceuticals
  • Sulfur & Selenium Compounds
  • Heterocycles
  • {SNA} Building Blocks, C4 to C6, Chemical Synthesis, Heterocyclic Building Blocks, Thiophenes
  • {uni_hamburg} no charge; sulfur heterocycle; aromatic; 5ring; sulfide; 1fragment
  • Intermediates & Fine Chemicals
  • Aromatics

产品应用

  • 导电聚合物前体

相关文献及参考

  • Short: II/25D
  • Short: II/14a
  • Waltman, R.J. et al.: J. Electrochem. Soc., 131, 740 (1984); Kankare, J. et al.: Synth. Metals, 55, 1395 (1993);
  • Short: II/2
  • Beilstein:17(5)1,331

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S29 Do not empty into drains 不要排入下水道;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20 Harmful by inhalation 吸入有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
Precautionary statements
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P301+P312+P330
  • P303+P361+P353
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSXM9800000
Packing GroupII
UN Number UN 1993 3/PG 2
Hazard Codes
Hazard Class3
Storage condition Flammables area
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(5),61,1986

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 18 gm/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(5),61,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,87,1982

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 18 gm/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,87,1

Restrict 危险品

其他信息

  • 不溶于水,溶于乙醇、醚、丙酮和苯。
  • 职业标准:STEL 20 毫克/ 立方米
  • 毒性分级:中毒
  • 用途一:用作医药中间体
  • MSDS 信息:616-44-4.msds
  • F:8-10-13-23
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • 检测方法:GC,NMR
  • 用途二:有机合成及医药中间体。
  • 类别:易燃液体
  • 图谱信息:3-甲基噻吩(616-44-4)质谱(MS) 3-甲基噻吩(616-44-4)红外图谱(IR1) 3-甲基噻吩(616-44-4)核磁图( 1 HNMR) 3-甲基噻吩(616-44-4)核磁图( 13 CNMR)
  • 外观性质:无色油状液体。
  • 蒸气压:42.4 mm Hg ( 37.7 °C)
  • Alfa Aesar:3-甲基噻吩,98+% 3-Methylthiophene, 98+%(616-44-4)
  • Hazard Note:Flammable/Harmful
  • 下游产品:3-噻吩乙酸 --> 4-溴-1,1-二(3-甲基-2-噻酚基)-1-丁醇 --> 3-甲基噻吩-2-硼酸 --> 2,5-二氯噻吩-3-羧酸甲酯 --> 2-乙酰-4-甲基噻吩 --> 2,5-二氯硫代苯-3-碳酰氯 --> 2,4-二甲基噻吩 --> 2,5-二氯-3-噻吩甲酸 --> 3-甲基噻吩-2-羰基氯 --> 2-乙酰-3-甲基噻吩 --> 4-甲基噻酚-2-甲醛 --> 2,5-二氯-3-甲基噻吩
  • MOL 文件:616-44-4.mol
  • 3-甲基噻吩价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0440 3-甲基噻吩 3-Methylthiophene 500G 1200元 2014/06/02 M0440 3-甲基噻吩 3-Methylthiophene 25G 228元 2010/06/21 127860500 3-甲基噻吩 3-Methylthiophene 99+% 50 ML 692元
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒硫氧化物烟雾
  • Acros Organics:3-甲基噻吩 3-Methylthiophene, 99+%(616-44-4)
  • 急性毒性:口服- 小鼠 LD50: 1800毫克/公斤; 吸入- 小鼠 LC50: 18克/立方米/2小时
  • 存储注意事项:光敏感;空气敏感
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • TCI Shanghai:3-甲基噻吩 3-Methylthiophene,>;98.0%(GC)(616-44-4)
  • Sigma Aldrich:616-44-4(sigmaaldrich)
  • 海关编码:29349990

系列性分类