Cobalt Naphthenate 环烷酸钴

CAS 61789-51-3 MFCD02094763

化学结构图

61789-51-3
SMILES:

化学属性

Density0.921
Refractive indexn20/D 1.4620
Mol. Formula
Flash Point48°C(lit.)
TSCAYes
Mol. Weight401.28
Melting Point140°C
Appearance solution
Solubility不溶于水,微溶于乙醇,溶于苯、甲苯、油类、石油溶剂、汽油。

别名和识别编码

MDL NumberMFCD02094763
CAS Number61789-51-3
PubChem Substance ID354334851
EC Number263-064-0
Chemical NameCobalt Naphthenate
Synonym Cobaltnaphthenate,~53%inmineralspirits(6%Co) Naphthenic Acid Cobalt Salt 环烷酸钴
Beilstein Registry Number87573691
Chemical Name Translation环烷酸钴
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分类

  • {SNA} Polymer Additives, Polymer Property Modifiers, Polymer Science, 材料科学
  • {SNA} Materials Science, Polymer Additives, Polymer Property Modifiers, Polymer Science
  • {SA} Materials Science, Polymer Additives, Polymer Science, Polymerization and Polymer Property Modifiers

产品应用

  • 氧化反应的催化剂。油漆和油墨的催干剂。不饱和聚酯树脂的促进剂,石油催化剂,如对二甲苯氧化制备对苯二甲酸,甲苯氧化制备苯甲酸,环己烷氧化制备己二酸等。

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P310+P331
  • P302+P350
  • P302+P352+P333+P313+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P311
  • P308+P313
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P337+P313
  • P342+P311
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H228 Flammable solid 易燃固体
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
Hazard Codes 3
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSQK8925000
UN Number 1993 2001
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R42/43
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R49 May cause cancer by inhalation 吸入会致癌
  • R50/53
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
Packing GroupIII
Storage condition 密封阴凉保存。 2-8°C
Hazard Class3
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3900 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 12,477,1955

其他信息

  • 用途:油漆催干剂、石油化工氧化催化剂和油晶添加剂
  • HazardClass:3
  • 有时呈深红色半固体或稠厚液体。组成不定。溶于乙醇、乙醚、苯和二甲苯、松节油和松香水等,不溶于水。易燃。
  • 生产方法:先将萘酸加入反应锅中,加入等量的水,升温95℃搅拌,加入15-20%氢氧化钠溶液进行皂化反应。维持90-95℃继续加碱,检查皂液pH值7-7.2为上,于90℃按计量加入钴盐进行复分解反应,再加入120#汽油洗涤,去掉杂质,脱水,脱油。最后加入200#汽油稀释至规定的含钴量作为成品。一般工业品为紫红色粘稠液体,1吨产品消耗萘酸约800kg,钴90kg。
  • EPA化学物质信息:Naphthenic acids, cobalt salts(61789-51-3)
  • RTECS号:QK8925000
  • PackingGroup:III
  • 环烷酸钴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80036727 环烷酸钴 250g 32元 2011/08/23 80036760 环烷酸钴 250g 32元 2011/04/16 N0338 环萘酸钴 Cobalt Naphthenate 500G 682元
  • 外观性质:紫色至深棕色非结晶粉末。

系列性分类


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