Ammonium acetate 乙酸铵

CAS 631-61-8 MFCD00013066

化学结构图

631-61-8
SMILES: CC(=O)O.N

化学属性

Mol. FormulaC2H7NO2
Mol. Weight77.08
Melting Point110-112 °C
Density1.07
SolubilitySoluble in cold water, approximately 148g/100ml. Decomposes in hot water. Soluble in methanol approximately 7.9g/100ml
TSCAYes
Boiling Point138.46 °C at 760 mmHg
Flash Point136°(277°F)
Stability易吸潮
Appearance 稍有乙酸气味的白色三角晶体,水溶液显中性!熔点112℃。 溶于水和乙醇,不溶于丙酮。易潮解,遇强碱分解出氨气。

别名和识别编码

Chemical NameAmmonium acetate
CAS Number631-61-8
EC Number211-162-9
Beilstein Registry Number4186741
MDL NumberMFCD00013066
PubChem Substance ID87561555
Reaxys-RN3564799
Merck Number14,495
Synonym Ammonium acetate AR 98% {LY} Ammonium acetate AR 98% {} {LY} Ammonium acetate AR 98% {} {} {LY} Ammonium acetate AR 98% {} {} {} {LY} Ammonium acetate AR 98% {} {} {} {} {LY} Ammonium acetate AR 98% {} {} {} {} {} {LY} Ammonium acetate AR 98% {} {} {} {} {} {} {LY} Ammonium acetate AR 98% {} {} {} {} {} {} {} {LY} Ammonium acetate AR 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium acetate AR 98% {} {} {} {} {} {} {} {} {} {LY} Ammonium acetate AR 98% {} {} {} {} {} {} {} {} {} {} {LY} Ammonium acetate AR 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium acetate AR 98% {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium acetate AR 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium acetate AR 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammon
Chemical Name Translation乙酸铵
Wiswesser Line NotationQV1 &ZH
LabNetwork Molecule IDLN00193858
InChIInChI=1S/C2H4O2.H3N/c1-2(3)4;/h1H3,(H,3,4);1H3
Canonical SMILESCC([O])=O.[NH4]
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分类

  • {SNA} Molecular Biology, Optimization Reagents, Protein Structural Analysis, Proteomics, X-Ray Crystallography
  • {SNA} Analytical Reagents, Analytical/Chromatography, Buffers & Reagents, Chromatography Reagents & Solvents, HPLC, HPLC Buffer - Solid, HPLC Buffers, Solid
  • {SNA} Ammonium,

产品应用

  • 缓冲液配制,测定铅及铁,从其它硫酸盐分离硫酸铅

相关文献及参考

  • Short: IV/1a
  • Short: III/5a
  • Merck: 14,495 Beilstein:2(4)94
  • Short: EINECS
  • Merck: 14,495

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSAF3675000
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
Signal word Warning
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number UN 9079 9079
Hazard Codes Xi
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 386 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JLCMAK Journal of Laboratory and Clinical Medicine.  (C.V. Mosby Co., 11830
   Westline Industrial Dr., St. Louis, MO 63141)  V.1-    1915-
   Volume(issue)/page/year: 29,809,1944

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : 1735 mg/kg
TOXIC EFFECTS :
   Behavioral - altered sleep time (including change in righting reflex)
   Behavioral - coma
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   BIJOAK Biochemical Journal.  (Biochemical Soc. Book Depot, POB 32, Commerce
   Way, Colchester, Essex CO2 8HP, UK)  V.1-    1906- Volume(issue)/page/year:
   106,699,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 632 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
   Behavioral - muscle contraction or spasticity
   Endocrine - hypoglycemia
REFERENCE :
   ABBIA4 Archives of Biochemistry and Biophysics.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.31-    1951-  Volume(issue)/page/year:
   64,342,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 736 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FRXXBL French Demande Patent Document.  (U.S. Patent and Trademark Office,
   Foreign Patents, Washington, DC 20231)  Volume(issue)/page/year: #21967

其他信息

  • 极易潮解,易溶于水和醇。
  • 下游产品:1-叔丁基-3,5-二甲基-1H-吡咯-4-甲醛 --> 4-氨基-苯并吡喃-2-酮 --> 2-甲基-4-乙基-6-羟基嘧啶 --> 6-氟色胺盐酸盐 --> 3,4-二氨基吡啶 --> 2-氨基-4-苯基噻吩-3-甲酸甲酯 --> 2-氨基-4-(4-溴苯基)-3-噻吩甲酸乙酯 --> 2-氨基-4-(4-氟苯基)噻吩-3-甲酸乙酯 --> 2-氨基-4-苯基噻吩-3-羧酸乙酯 --> 5-(4-苯基-苯基)噻吩[2,3-D]嘧啶-4(3H)-酮 --> 4-氯-四吡啶 --> 奥洛前列素 --> 防水剂 YS --> 2,5-双(4-吡啶)-1,3,4-噻二唑 --> 2-((E)-2-羟基-3-苯基丙烯酸基)苯甲酸 --> 2-氨基-4-[1,1'-联苯基]-4-基-3-噻吩甲酸乙酯 --> (E)-3-苯亚甲基-3H-异苯并吡喃-1,4-二酮 --> 2,3-吡啶二酰亚胺 --> 孟鲁司特 --> 4-甲氧基多巴胺盐酸盐 --> DL-4-氟-α-甲基苄胺 --> 3-氨基-4,4,4-三氟巴豆酸乙酯 --> 3-氨基-3-(2-噻吩基)丙酸 --> 2-氰基-3-甲基-2-戊烯酸乙酯 --> 紫脲酸铵
  • 毒性分级:中毒
  • 可燃性危险特性:可燃;燃烧产生有毒氮氧化物和氨烟雾
  • 海关编码:29152900
  • 类别:有毒物品
  • Alfa Aesar:醋酸氨,ACS,97.0%min Ammonium acetate, ACS, 97.0% min(631-61-8)
  • F:3
  • Sigma Aldrich:631-61-8(sigmaaldrich)
  • 用途一:用作分析试剂、色层分析试剂和缓冲剂
  • 敏感性:Hygroscopic
  • 用途二:用于肉类防腐、电镀、水处理、制药等
  • 储运特性:库房通风低温干燥
  • 用途三:缓冲液配制,测定铅及铁,从其它硫酸盐分离硫酸铅
  • 图谱信息:乙酸铵(631-61-8)红外图谱(IR1) 乙酸铵(631-61-8)红外图谱(IR2) 乙酸铵(631-61-8)Raman光谱 乙酸铵(631-61-8)核磁图( 13 CNMR) 乙酸铵(631-61-8)质谱(MS) 乙酸铵(631-61-8)核磁图( 1 HNMR)
  • MSDS 信息:Ammonium acetate(631-61-8).msds
  • 急性毒性:腹腔-大鼠 LD50: 632 毫克/公斤; 静脉-小鼠LD50: 386 毫克/公斤
  • 乙酸铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K1783601 乙酸铵;乙酸铔;醋酸铵 50g 675元 2011/04/16 A2269 乙酸铵[用于一般有机化学] Ammonium Acetate [for General Organic Chemistry] 250G 171元 2010/06/21 423270250 乙酸铵 Acetic acid, ammonium salt 97+%, for analysis ACS 25 GR 322元
  • Acros Organics:乙酸铵 Acetic acid, ammonium salt, pure, 98%(631-61-8)
  • MOL 文件:631-61-8.mol
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 上游原料:乙酸

系列性分类


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