N-Benzyloxycarbonyl-D-proline (+)-Z-D-脯氨酸

CAS 6404-31-5 MFCD00063228

化学结构图

6404-31-5
SMILES: O=C(O)[C@H]1CCCN1C(=O)OCc1ccccc1

化学属性

Mol. FormulaC13H15NO4
Mol. Weight249.26
Melting Point76-78°C
TSCANo
Density1.309
Refractive index40 ° (C=2, EtOH)
Boiling Point432.3°C at 760 mmHg

别名和识别编码

Chemical Name(R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid
CAS Number6404-31-5
Alfabeta NamePROOH ZD---
MDL NumberMFCD00063228
PubChem Substance ID111208
EC Number229-021-5
Reaxys-RN485188
Beilstein Registry Number22(5)1,84
Synonym (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-car
Chemical Name Translation(+)-Z-D-脯氨酸
InChIKeyJXGVXCZADZNAMJ-LLVKDONJSA-N
LabNetwork Molecule IDLN00173605
InChIInChI=1S/C13H15NO4/c15-12(16)11-7-4-8-14(11)13(17)18-9-10-5-2-1-3-6-10/h1-3,5-6,11H,4,7-9H2,(H,15,16)/t11-/m1/s1
Canonical SMILESO=C(OCC1=CC=CC=C1)N(CCC2)[C@H]2C(O)=O
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分类

  • {SA} Amino Acid Derivatives, Chemical Biology, Chemical Synthesis, Peptide Chemistry, Proline
  • {SNA} Amino Acids & Derivatives, Chemical Biology, Chemical Synthesis, Peptide Chemistry, Proline

相关文献及参考

  • Beilstein:22(5)1,84

安全信息

Warnings IRRITANT
WGK Germany2
Hazard Codes Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

  • 外观性质:白色细粉末晶体。熔点:75-79°C
  • TCI Shanghai:N-苄氧羰基-D-脯氨酸 N-Carbobenzoxy-D-proline,>;98.0%(LC)(T)(6404-31-5)
  • Alfa Aesar:N-苄氧羰基-D-脯氨酸,98+% N-Benzyloxycarbonyl-D-proline, 98+%(6404-31-5)
  • 比旋光度:40 ° (c=2, EtOH)
  • Sigma Aldrich:6404-31-5(sigmaaldrich)
  • N-苄氧羰基-D-脯氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1730 N-苄氧羰基-D-脯氨酸 N-Carbobenzoxy-D-proline 5G 697元 2014/06/02 C1730 N-苄氧羰基-D-脯氨酸 N-Carbobenzoxy-D-proline 25G 2340元 2010/05/25 B25005 N-苄氧羰基-D-脯氨酸, 98+% N-Benzyloxycarbonyl-D-proline, 98+% 5g 4088元
  • MOL 文件:6404-31-5.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Proline 脯氨酸
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Proline 脯氨酸
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  4. Modified Amino Acids - Amino Acids
  5. Cbz-amino Acids
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Protected & Labeled Amino Acids