Di-p-tolylcarbodiimide 1,3-二对甲苯基碳二酰亚胺

CAS 726-42-1 MFCD00010701

化学结构图

726-42-1
SMILES: Cc1ccc(N=C=Nc2ccc(C)cc2)cc1

化学属性

Mol. FormulaC15H14N2
Mol. Weight222.29
Boiling Point221-223 °C at 20 mmHg
Melting Point56-58 °C

别名和识别编码

Chemical Name1,3-Di-p-tolylcarbodiimide
Synonym 1,3-Di-p-tolylcarbodiimide {LY} 1,3-Di-p-tolylcarbodiimide {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {} {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {} {} {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {} {} {} {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {} {} {} {} {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Di-p-tolylcarbodiimide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Di-p-tolylcarbod
MDL NumberMFCD00010701
PubChem Substance ID69763
CAS Number726-42-1
EC Number211-971-7
Chemical Name Translation1,3-二对甲苯基碳二酰亚胺
InChIKeyBOSWPVRACYJBSJ-UHFFFAOYSA-N
InChIInChI=1S/C15H14N2/c1-12-3-7-14(8-4-12)16-11-17-15-9-5-13(2)6-10-15/h3-10H,1-2H3
Canonical SMILESCC1=CC=C(C=C1)N=C=NC2=CC=C(C)C=C2
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Carbodiimides, Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Synthetic Reagents

相关文献及参考

  • 1. H. Shen, et al., Org. Lett. 13 , 4562-4565, (2011)
  • 2. K. Kaleta, et al., J. Am. Chem. Soc. 133 , 5463-5473, (2011)
  • 3. H. He, et al., Adv. Synth. Catal. 352 , 2905-2912, (2010)
  • 4. G. Shen and W. Bao, Adv. Synth. Catal. 352 , 981-986, (2010)
  • 5. F. Olimpieri, et al., Synthesis 4 , 651-660, (2010)
  • 6. J. A. Hyatt and P. W. Raynolds, Org. React. 45 , (1994)
  • Aldrich MSDS 1 , 841:C / Corp MSDS 1 (1), 1484:B / FT-IR 1 (2), 480:A / FT-IR 2 (2), 3202:A / IR-Spectra (3), 1144:F / IR-Spectra (2), 997:B / NMR-Reference 2 (2), 446:C / RegBook 1 (2), 2173:A / Structure Index 1 , 341:A:8 / Vapor Phase 3 , 1436:A
  • Beil. 12 ,955
  • Fieser 1 ,351
  • Short: IV/7b Title: Liquid Crystals: Two-Ring Systems with Bridging Group Author: Vill, V. Editor: Thiem, J. Source: Landolt-Börnstein, New Series Volume: IV/7b Year: 1992 Keyword: organic compounds; enthaly of fusion; melting point; phase transition; liquid crystals; glass transition ISBN: 3-540-55504-8 ISBN: 978-3-540-55504-9 Internet Resource: DOI:10.1007/b46099 RefComment: 10 figs., VIII, 653 pages.
  • Short: LC Title: Liq
  • Short: VIII/5A Title: Physical and Thermodynamic Properties of Liquid Crystalline Substances Author: Pestov, S. Editor: Vill, V. Source: Landolt-Börnstein, New Series Volume: VIII/5A Year: 2003 Keyword: density; molar volume; refractive index; surface tension; heat capacity; thermal conductivity; diffusion coefficient; liquid crystals; order parameter; polarizability; crystal data; viscosity; sound velocity; compressibility; dielectric constant; magnetic susceptibility; dipole moment; vapour pressure ISBN: 3-540-43365-1 ISBN: 978-3-540-43365-1 Internet Resource: DOI:10.1007/b71736 RefComment: 2003, VI, 492 pages. With CD-ROM. Hardcover

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Coupling - Synthetic Reagents
  4. Carbodiimides - Coupling
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Peptide Coupling - Peptide Chemistry
  5. Carbodiimides - Peptide Coupling

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