Aluminum Chloride 氯化铝，无水(易涉毒)

CAS 7446-70-0 MFCD00003422

化学结构图

7446-70-0
SMILES: [AlH3+3].[Cl-].[Cl-].[Cl-]

化学属性

Mol. FormulaAlCl3
Mol. Weight133.34
Density2.44
Melting Point190
Vapor Pressure1 mmHg ( 100 °C)
TSCAYes
SolubilityReacts violently with water with liberation of heat; soluble in HCl, ether, ethanol
Flash Point88 °C
Stability对湿度敏感
Boiling Point182.7°C
Appearance powder

别名和识别编码

Chemical NameAluminum Chloride
CAS Number7446-70-0
PubChem Substance ID24012
MDL NumberMFCD00003422
Synonym ALUMINIUM CHLORIDE (III) ALUMINUM AA STANDARD CONCENTRATE ALUMINUM CHLORIDE ALUMINUM TRICHLORIDE ALUMINUM(III) CHLORIDE AlCl3 Alluminio(cloruro di) Aluminium trichloride Aluminiumchlorid Aluminum trichloride Anhydrous Aluminum Chloride Drysol Trichloroaluminum alluminio(clorurodi) aluminiumchloridesolutions aluminum chloride aluminum chloride hexahydrate aluminum chloride, anhydrous aluminum trichloride 三氯化铝 溶液 氯化铝 氯化铝, 无水, 99.985%B(METALS BASIS) 纳米铝粉
EC Number231-208-1
Merck Number337
Chemical Name Translation氯化铝，无水(易涉毒)
Wiswesser Line NotationAL G3
LabNetwork Molecule IDLN00197168
InChIInChI=1S/Al.3ClH/h;3*1H/q+3;;;/p-3
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分类

  • {SA} Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents TLC, Sprays, TLC Reagents, A-C, TLC Visualization Reagents (alphabetic sort)
  • {SNA} Acids, Acids & Bases, Al, Alternative Energy, Aluminum, Aluminum Salts,
  • {SNA} 10.00 g/L, AAS, AAS Concentrates, Additional Standards, Analytical Standards, Elemental & Metal Standards, Elemental, Ions and Water (Karl Fischer) Standards, Single Solution, Spectroscopy, 分析/色谱
  • {SNA} Acids, Acids & Bases, Alternative Energy,

产品应用

  • 有机合成催化剂，强脱水剂，酸催化剂，制造人造橡胶、塑料、润滑剂等的催化剂，冶金，石油裂化。

相关文献及参考

  • Merck: 14,323
  • Merck: 14,337

安全信息

GHS Symbol
WGK Germany1
Hazard Codes 8 F,T T
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H303 May be harmfully swallowed 吞食可能有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, Gloves Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P330+P331
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P305+P351+P338
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P404 Store in a closed container. 贮存于密闭容器中。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
RTECSBD0525000
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
Packing GroupII
UN Number 1726
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R48/20
  • R48/23/24
  • R48/25
  • R51/53
  • R52 Harmful to aquatic organisms 对水生生物有害
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
Storage condition Moisture Sensitive 防潮、密封充氩保存。 2-8°C
Hazard Class8
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1130 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 30(4),16,1965

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 315 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 43(4),12,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History unknown.  Volume(issue)/page/year:
   8EHQ-0191-1109

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3450 mg/kg
TOXIC EFFECTS :
   Brain and Coverings - other degenerative changes
   Gastrointestinal - other changes
   Kidney, Ureter, Bladder - hematuria
REFERENCE :
   SRTCAC Science Reports of the Research Institutes, Tohoku University, Series
   C: Medicine. (Tohoku University, Research Institute for Tubercu

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Rodent - rat Ascites tumor
DOSE/DURATION           : 500 umol/L
REFERENCE :
   JBCHA3 Journal of Biological Chemistry.  (428 E. Preston St., Baltimore, MD
   21202)  V.1-    1905-  Volume(issue)/page/year: 261,3370,1986

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 444 mg/kg
REFERENCE :
   NULSAK Nucleus (Calcutta).  (Dr. A.K. Sharma, Centre of Advanced Studies in
   Cell and Chromosome Research, Calcutta, 35 Baliygunge Circular Rd., Calcutta
   700 019, India)  V.1-    1958-  Volume(issue)/page/year: 15,180,1972

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 500 mg/kg
SEX/DURATION            : female 14-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   ANANAU Anatomischer Anzeiger.  (VEB Gustav Fischer Verlag, Postfach 176,
   Jena DDR-6900, Ger. Dem. Rep.)  V.1-    1886-  Volume(issue)/page/year:
   138,365,1975

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 425 mg/kg
SEX/DURATION            : multigenerations
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   BJIMAG British Journal of Industrial Medicine.  (British Medical Journal,
   Box 560B, Kennebunkport, ME 04046)  V.1-    1944-  Volume(issue)/page/year:
   23,305,1966

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 5723 mg/kg
SEX/DURATION            : female 1-21 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - other neonatal measures or effects
   Reproductive - Effects on Newborn - behavioral
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 40,21,1989

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 11512 mg/kg
SEX/DURATION            : female 8-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - weaning or lactation index (e.g., #

Restrict 危险品

其他信息

  • 蒸气压:1 mm Hg ( 100 °C)
  • 用途四:用作有机合成的催化剂，如石油裂解、合成染料、合成橡胶、合成洗涤剂、医药、香料等。用于制造农药、有机铝化合物、酞菁系有机颜料用催化剂、乙基苯制造用催化剂。也用于金属冶炼、润滑油合成。食品级产品用作膨松剂、清酒等防变色剂及果胶的絮凝剂。
  • 用途一:用作有机合成的催化剂、洗涤剂，并用于医药、农药、染料、香料、塑料、润滑油等行业
  • 用途六:有机合成催化剂，强脱水剂，酸催化剂，制造人造橡胶、塑料、润滑剂等的催化剂，冶金，石油裂化。
  • Acros Organics:三氯化铝 Aluminium chloride, anhydrous, granules, extra pure, 99%(7446-70-0)
  • 方法一:金属铝法将铝锭放入密闭的氯化反应炉内，氯气由上顺导管送入炉内，与铝在800～900℃下反应生成三氯化铝，经升华、冷凝，即得无水氯化铝成品。尾气经碱水洗涤后排空。其 2A1+3C12→2AC13 铝氧粉沸腾床法 将一定粒度的铝氧粉和石油焦按一定配比投入焙烧炉中，由炉底部通入空气在800℃下进行焙烧，焙烧后的物料经溢流管加入氯化炉，然后通入氯气和氧气，于950℃在有石油焦还原剂的存在下，铝氧粉与氯气反应，生成氯化铝气相产物，经预冷分离器和预冷塔，将气体中夹带的灰粉和氯化物杂质除去，净化气体冷却至250℃左右，通人夹套水冷捕集器，再经冷却、结晶，制得无水氯化铝成品。其 A12O3+3C+3Cl2→2AlCl3+3CO尾气经烧碱溶液或亚硫酸钠溶液吸收处理后排空。
  • {Chemic
  • 用途二:用作分析试剂、防腐剂、媒染剂
  • 下游产品:2,3,5-三氯噻吩 --> 东莨菪内酯 --> 正丁基二茂铁 --> 4-羟基苯戊酮 --> 4-溴-2-噻吩甲醛 --> 4,4'-二乙酰联苯 --> 辛基苯基酮 --> 2-乙酰基-5-氯噻酚 --> 1,1'-二乙酰基二茂铁 --> 2-(三甲基乙酰基)噻吩 --> 4-苯甲酰基丁酸 --> 3-(4-甲氧基苯甲酰基)丙酸 --> 1,1,1,2,2,3,3-七氯丙烷 --> 还原棕BR --> 食品黄3:1 --> 1-(4'-溴联苯-4-基)-3-苯基-2-丙烯-1-酮 --> 2-氯-4'-氟二苯甲酮 --> 2-溴-2',4'-二氯苯乙酮 --> 甲氧滴滴涕,甲氧氯 --> 还原红 15 --> 1-(4-氯苯基)-1-苯基丙酮 --> 二苯基乙酮 --> 2,7-二叔丁基萘 --> 吩恶噻 --> 4-氯-4'-羟基二苯甲酮 --> 邻氯苯基二苯基氯甲烷 --> 5-乙酰基水杨酰胺 --> 2-乙酰芴 --> 四碘甲烷 --> 3-(4-氯苯甲酰)丙酸 --> 2,4,6-三叔丁基苯酚 --> 1-(3-甲基-2,4-二氯苯基)乙酮 --> 4,4'-二氯二苯砜 --> OZONE DEPLETING --> 酸性蓝 9 铝色淀[CI 42090:2] --> 2-萘乙酮 --> 氯代双(4-氟苯基甲烷) --> 1,1-双(4-甲基苯基)-2-丙酮
  • 用途五:主要用于有机合成的消化剂、合成染料、医药等。
  • 有氯化氢气味。177.8℃升华。易溶于水。溶于无水乙醇、氯仿、乙醚、四氯化碳。微溶于苯。极易潮解，露置空气中易吸收水分并水解生成氯化氢。遇水后会发热引起爆炸。有强腐蚀性。
  • 毒性:本品溅落在皮肤上时，先应干拭除掉，然后用水冲洗，否则，会因接触水而剧烈灼烧皮肤。如不慎溅入眼睛时立即用水冲洗15min，送医院治疗。 操作人员工作时应穿工作服，
  • 图谱信息:三氯化铝(7446-70-0)红外图谱(IR1)
  • 方法二:由氯气通人熔融的金属铝，反应、升华而捕得。 由三氧化二铝在碳的作用下通人氯气反应而得。
  • 三氯化铝价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 10000862 无水氯化铝（*）;无水三氯化铝 500g 19.5元 2011/08/23 10000861 无水氯化铝（*）;无水三氯化铝 500g 17元 2011/08/23 10000828 无水氯化铝（*）;无水三氯化铝 500g 17元
  • Sigma Aldrich:7446-70-0(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Aluminum - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Lewis Acids 路易斯酸
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Inorganic Salts, Solutions and Reagents - Essential Chemicals
  4. Reagent Grade - Inorganic Salts, Solutions and Reagents
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Inorganic Salts, Solutions and Reagents - Essential Chemicals
  4. Reagent Plus - Inorganic Salts, Solutions and Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Salts - Synthetic Reagents
  4. Aluminum - Inorganic Salts
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Lewis Acids 路易斯酸
  4. Aluminum - Lewis Acids
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents TLC - Derivatization Reagents
  5. TLC Visualization Reagents (alphabetic sort) - Derivatization Reagents TLC
  6. TLC Reagents, A-C - TLC Visualization Reagents (alphabetic sort)
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Spectroscopy - Analytical Standards
  4. AAS - Spectroscopy
  5. Single Solution - AAS
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  5. A-B, Puriss p.a. - Puriss p.a.
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Spectroscopy - Analytical Standards
  4. AAS - Spectroscopy
  5. AAS Concentrates - AAS
  6. 10.00 g/L - AAS Concentrates
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Spectroscopy - Analytical Standards
  4. AAS - Spectroscopy
  5. AAS Concentrates - AAS
  6. 10.00 g/L - AAS Concentrates
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Spectroscopy - Analytical Standards
  4. AAS - Spectroscopy
  5. AAS Concentrates - AAS
  6. 1.00 g/L - AAS Concentrates
  1. Analytical & Chromatography 分析化学与色谱
  2. Syringes
  3. Hamilton Syringe Products - Syringes
  4. Hamilton Needles - Hamilton Syringe Products
  5. Hamilton needles for LT and TLL syringes - Hamilton Needles
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Hydrazides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents
  1. Chemical Synthesis 化学合成
  2. 无机盐
  1. Chemical Synthesis 化学合成
  2. 无机盐
  1. CVD & ALD Precursors
  2. Aluminum

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