Triphenyltin Hydroxide 三苯基氢氧化锡

CAS 76-87-9 MFCD00013928

化学结构图

76-87-9
SMILES: O[Sn](c1ccccc1)(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC18H16OSn
Mol. Weight367
Melting Point124-126 °C(lit.)
Solubility<0.1 G/100 ML AT 21 ºC
TSCAYes
Density1.54

别名和识别编码

Chemical NameTriphenyltin Hydroxide
CAS Number76-87-9
Synonym K 19 Hydroxytriphenyltin 三苯基羟基锡 TRIPHENYLTIN HYDROXIDE DU-TER(R) Triphenyltin hy Duter extra 三苯羟基锡 Fintin idrossido SUZU H(R) Triphenyl tin hydroxide fentin hydroxide (ISO) FENTIN HYDROXIDE Haitin Triphenylstannyl hydroxide ######## Triphenylstannium hydroxide brestanh47.5wpfungicide. {Chemi {Chemicalb TUBOTIN 羟基三苯基锡 Fintine hydroxyde Fentinhydroxid (ISO) duter hydroxytriphenylstannate Suzu H {uni_hambu Triphenylzinnhydroxid ENT 28009 Tptoh Fentin hydroxide SuperTin Triphenylhydroxytin; Triphenyltin hydroxide SUPER-TIN OMS 1017 Fintin hydroxid Tubotin TRIPHENYLTIN(IV) HYDROXIDE 毒菌锡 氫氧化三苯錫 148-02 [3] Hydroxyde de triphenyl-etain TRIPHENYLHYDROXYTIN triph Tin, hydroxytriphenyl- Hydroxytriphenylzinn stannane, hydroxytriphenyl- 海丁 三苯基 Idrossido di stagno Fenolovo TPTOH Fentinhydroxid SUZU-H Duter Ashlade flotin Hydroxytriphenylstannane dowco186 Vancide KS TPTH Triphenylhydroxytin Phenostat-H 氢氧化三苯基锡 TUBOTIN(R) {uni_ham Sunitron H Fintin hydroxyde Du-Ter NCI-C00260
MDL NumberMFCD00013928
PubChem Substance ID6327657
Beilstein Registry Number4139186
EC Number200-990-6
Merck Number14,9745
Chemical Name Translation三苯基氢氧化锡
Wiswesser Line NotationQ-SN-R&R&R
InChIInChI=1S/3C6H5.H2O.Sn/c3*1-2-4-6-5-3-1;;/h3*1-5H;1H2;
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分类

  • Algicides, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Baby Food Directives 13/2003 EC & 14/2003 EC, Chromatography, E-G, Environmental Standards, European Community: ISO, DIN and DL 152, F, FA - FL, Fungicides, Method Specific, Molluscicides, Organotins, Others, Pesticides, Pesticides & Metabolites
  • {uni_hamburg} no charge; metal-organic; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SA} Algicides, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography,
  • {SNA} Chemical Synthesis, Organometallic

产品应用

  • ########

相关文献及参考

  • Short: EINECS
  • Short: IV/8A
  • Merck: 14,9745
  • Merck: 14,9745 Beilstein: 16,914
  • Soderquist, J.S. et al.: J. Agric. Food Chem., 28, 111 (1980); J. Toxicol. Environ. Health, 7, 281 (2004); Livingston, J.M. et al.: J. Georgia Entamol. Soc., 13, 148 (1978); Sarpa, M. et al.: J. Toxic

安全信息

RTECSWH8575000
GHS Symbol
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H330 Fatal if inhaled 吸入致命
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
Hazard Codes T+,N T+;N
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S1/2 None 上锁保管并避免儿童触及;
UN Number 3146 UN 3146 6.1/PG 2 UN3146
Risk Statements
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R48/23
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R50/53
  • R26 Very toxic by inhalation 吸入极毒
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
Packing GroupIII
Hazard Class6.1
Storage condition APPROX 4°C
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 8500 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   23,288,1972

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - mydriasis (pupillary dilation)
   Behavioral - convulsions or effect on seizure threshold
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   CTOXAO Clinical Toxicology.  (New York, NY)  V.1-18, 1968-81.  For publisher
   information, see JTCTDW.  Volume(i

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,302,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 46 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCILB* Progress Report for Contract No. NIH-NCI-E-C-72-3252, Submitted to
   the National Cancer Institute by Litton Bionetics, Inc.  (Bethesda, MD)
   Volume(issue)/page/year: NCI-E-C-72-3252,1973

TYPE OF TEST

T

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - rat Embryo
DOSE/DURATION           : 19 ng/plate
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 1,190,1981

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 60 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 300,5,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 105 mg/kg
SEX/DURATION            : female 8-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   CTOXAO Clinical Toxicology.  (New York, NY)  V.1-18, 1968-81.  For publisher
   information, see JTCTDW.  Volume(issue)/page/year: 13,281,1978

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 140 mg/kg
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - other measures of fertility
REFERENCE :
   TOANDB Toxicology Annual.  (New York, NY)  1974/75-79.  Discontinued.
   Volume(issue)/page/year: 3,281,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 140 mg/kg
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
REFERENCE :
   CTOXAO Clinical Toxicology.  (New York, NY)  V.1-18, 1968-81.  For publisher
   information, see JTCTDW.  Volume(issue)/page/year: 13,281,1978

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 130 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc.,

其他信息

  • 注意事项:[1]与春雷霉素的混剂对苹果、葡萄、大豆和藕等作物的嫩叶敏感,因此一定要注意浓度,宜在下午4点后喷药。 [2]不能与酸和多硫化钙混用
  • 灭火剂:砂土、干粉、泡沫
  • 外观性质:无味白色粉末。
  • 图谱信息:三苯基氢氧化锡(76-87-9)红外图谱(IR2) 三苯基氢氧化锡(76-87-9)质谱(MS) 三苯基氢氧化锡(76-87-9)核磁图( 13 CNMR) 三苯基氢氧化锡(76-87-9)红外图谱(IR1) 三苯基氢氧化锡(76-87-9)核磁图( 1 HNMR)
  • 类别:农药
  • 用途一:为非内吸保护性杀菌剂,能有效防治对铜类杀菌剂敏感的一些菌类,可防治甜菜褐斑病,马铃薯晚疫病等
  • Alfa Aesar:Triphenyltin hydroxide(76-87-9)
  • 毒性分级:剧毒
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 可燃性危险特性:受热分解有毒含锡气体
  • 用途二:保护性杀菌剂,无内吸作用。主要用于防治马铃薯晚疫病,甜菜褐斑病,大豆炭疽病、褐纹病、紫斑病,水稻稻瘟病、条斑病,胡麻叶枯病,洋葱黑班病,芹菜叶枯病,菜豆炭疽病等。除杀菌外,也可用于防治水田中的藻类和水蜗牛。用于甜菜、大豆,还有增糖、增产的作用。
  • 急救治疗:经口中毒,立即催吐、洗胃。解毒剂为依地酸二钠钙,并配合对症治疗。
  • MOL 文件:76-87-9.mol
  • 下游产品:三苯基锡醋酸盐
  • MSDS 信息:毒菌锡(76-87-9).msds
  • 急性毒性:口服-大鼠 LD50: 46 毫克/公斤; 口服-小鼠 LD50: 209 毫克/公斤
  • 刺激数据:眼睛-兔子 10 毫克 中度
  • 中毒症状:误食引起急性中毒,表现为头痛、头晕、乏力、口腔粘膜呈蓝色,口内有金属味,齿龈出血,舌发青,腹泻,腹绞痛,黑大便,重者昏迷、痉挛,血压下降等。
  • 职业标准:TWA 0.1 毫克 (锡)/立方米; STEL 0.2 毫克 (锡)/立方米
  • Sigma Aldrich:76-87-9(sigmaaldrich)
  • TSCA:Yes

系列性分类


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