Boron trifluoride 三氟化硼

CAS 7637-07-2 MFCD00011316

化学结构图

7637-07-2
SMILES: FB(F)F

化学属性

Mol. FormulaBF3
Mol. Weight68
Boiling Point-100 °C(lit.)
Melting Point-127 °C(lit.)
Density0.87 g/mL at 20 °C
TSCAYes
Vapor Density2.38 (21 °C, vs air)
Refractive indexn20/D 1.38

别名和识别编码

Chemical NameBoron trifluoride
MDL NumberMFCD00060263
CAS Number7637-07-2
PubChem Substance ID6356
EC Number231-569-5
Synonym Boron fluoride boron trifluoride 三氟化硼
Merck Number1349
Chemical Name Translation三氟化硼
LabNetwork Molecule IDLN01746724
Reaxys-RN3535140
InChIInChI=1S/BF3/c2-1(3)4
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分类

  • Alkylation Reagents, Analytical Reagents, Analytical/Chromatography, Applications, Derivatization, Derivatization Reagents, Derivatization of Fatty Acids to FAMEs, Esterification Reagents, Fats (fatty acids, FAMEs, glycerides), Edible Oils, Sterols, Food & Beverage Analysis, Reagents
  • {SNA} Boron, Catalysis and Inorganic Chemistry, Chemical Synthesis, Ionic Polymerization Initiators, Lewis Acids, Materials Science, Polymer Science, Polymerization Initiators,
  • {SA} Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents GC, Reagents for Alkylation & Esterification
  • {SNA} Acids,

相关文献及参考

  • 1. Solid State Ionics 86-88 , 581, (1996)
  • Merck 14 ,1349
  • Fieser 1 ,68 / Fieser 3 ,32 / Fieser 5 ,51 / Fieser 7 ,31 / Fieser 10 ,50 / Fieser 11 ,71
  • Corp MSDS 1 (1), 482:D / RegBook 1 (3), 3307:A / Vapor Phase 3 , 1687:B

安全信息

Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H280 Contains gas under pressure; may explode if heated 内含高压气体，遇热可能爆炸。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H330 Fatal if inhaled 吸入致命
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
GHS Symbol
WGK Germany1
Precautionary statements
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P308+P316
  • P309+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P316
  • P317
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P410+P403
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Codes T+,C
Personal Protective Equipment Faceshields, Gloves, Goggles, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
RTECSED2275000
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
UN Number 2920 UN1008
Risk Statements
  • R48/20
  • R26 Very toxic by inhalation 吸入极毒
  • R37 Irritating to respiratory system 刺激呼吸道
  • R14 Reacts violently with water 遇水会猛烈反应
  • R35 Causes severe burns 会导致严重灼伤
Storage condition Moisture Sensitive
Packing GroupII
Hazard Class8/3
Warnings 危化品目录(2015) 危险化学品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Boron 硼
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Boron 硼
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Specialty Gases 特种气体
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Alkylation & Esterification - Derivatization Reagents GC
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Lewis Acids 路易斯酸
  4. Aluminum - Lewis Acids
  1. Analytical & Chromatography 分析化学与色谱
  2. Applications
  3. Food & Beverage Analysis - Applications
  4. Fats (fatty acids and triglycerides), Edible Oils, and Sterols - Food & Beverage Analysis
  5. Derivatization of Fatty Acids to FAMEs - Fats (fatty acids, FAMEs, glycerides), Edible Oils, Sterols
  6. Reagents - Derivatization of Fatty Acids to FAMEs
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Gases - CVD and ALD Precursors by Metal
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物

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