1,2-Diethylhydrazine Dihydrochloride 1，2-二乙基肼二盐酸盐

CAS 7699-31-2 MFCD00012523

化学结构图

7699-31-2
SMILES: CCNNCC.Cl.Cl

化学属性

Mol. FormulaC4H14Cl2N2
Mol. Weight161.07
Melting Point168-169 °C
TSCANo

别名和识别编码

Chemical Name1,2-Diethylhydrazine Dihydrochloride
MDL NumberMFCD00012523
PubChem Substance ID24372
CAS Number7699-31-2
Beilstein Registry Number3668380
Synonym 1,2-Diethylhydrazine dihydrochloride {LY} 1,2-Diethylhydrazine dihydrochloride {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {} {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {} {} {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {} {} {} {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {} {} {} {} {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {} {} {} {} {} {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {} {} {} {} {} {} {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Diethylhydrazine dihydrochloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Diethylhydrazine dihydrochlor
Chemical Name Translation1，2-二乙基肼二盐酸盐
Wiswesser Line Notation2MM2 &GH 2
LabNetwork Molecule IDLN02141663
InChIInChI=1S/C4H12N2.2ClH/c1-3-5-6-4-2;;/h5-6H,3-4H2,1-2H3;2*1H
Canonical SMILESCCNNCC.Cl.Cl
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分类

  • Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks
  • {SNA} Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • 1. V. Chudasama, et al., Bromopyridazinedione-mediated protein and peptide bioconjugation Chem. Commun. 47 , 8781-8783, (2011)
  • 2. D. Dou, et al., Utilization of the 1,2,3,5-thiatriazolidin-3-one 1,1-dioxide scaffold in the design of potential inhibitors of human neutrophil proteinase 3 Bioorg. Med. Chem. 18 , 1093-1102, (2010)
  • 3. R. Grigg, et al., Regioselective Synthesis of N-Aminoisoindolones and Mono- N - and Di- N,N '-substituted Phthalazones Utilizing Hydrazine Nucleophiles in a Palladium-Catalyzed Three-Component Cascade Process J. Org. Chem. 73 , 8352-8356, (2008)
  • 4. D. Bevk, et al., Synthesis of substituted 2,3,5,6,7,8-hexahydropyrazolo[4,3- d ][1,2]diazepine-8-carboxylates Tetrahedron 62 , 8126-8132, (2006)
  • 5. Y. Ju and R. S. Varma, Aqueous N -Heterocyclization of Primary Amines and Hydrazines with Dihalides: Microwave-Assisted Syntheses of N -Azacycloalkanes, Isoindole, Pyrazole, Pyrazolidine, and Phthalazine Derivatives J. Org. Chem. 71 , 135-141, (2006)
  • Aldrich MSDS 1 , 673:C / Corp MSDS 1 (1), 1213:A / FT-IR 2 (1), 461:D / FT-IR 1 (1), 280:A / FT-NMR 1 (1), 473:B / RegBook 1 (1), 315:B / Sax 6 , 1018 / Structure Index 1 , 43:A:3

安全信息

RTECSMV2295000
WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H350 May cause cancer 可能致癌
Hazard Codes T
Personal Protective Equipment Eyeshields, Gloves, type P2 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R45 May cause cancer 可能致癌
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Packing GroupIII 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50 mg/kg
                          female 15 day(s) after conception
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Reproductive - Tumorigenic effects - transplacental tumorigenesis
   Brain and Coverings - tumors
REFERENCE :
   EXPEAM Experientia.  (Birkhaeuser Verlag, POB 133, CH-4010 Basel,
   Switzerland)  V.1-    1945-  Volume(issue)/page/year: 24,561,1968

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Multiple routes
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 395,229,1997

Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds

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