4-Nitro-1-naphthylamine 4-硝基-1-萘胺

CAS 776-34-1 MFCD00004026

化学结构图

776-34-1
SMILES: Nc1ccc([N+](=O)[O-])c2ccccc12

化学属性

Mol. FormulaC10H8N2O2
Mol. Weight188.18
Melting Point190-193°C
Solubility溶于乙醇、乙酸，微溶于热水。
Boiling Point419.0±25.0 °C at 760 mmHg

别名和识别编码

Chemical Name4-Nitro-1-naphthylamine
Synonym 4-Nitronaphthalen-1-amine {LY} 4-Nitronaphthalen-1-amine {} {LY} 4-Nitronaphthalen-1-amine {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {} {} { {} {} {} {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {} {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {} {} {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitronaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00004026
CAS Number776-34-1
PubChem Substance ID13057
Beilstein Registry Number12(3)2971
EC Number212-277-7
Alfabeta NameNITRONAPHTHYLAMINE 41---
Chemical Name Translation4-硝基-1-萘胺
Reaxys-RN2211897
InChIKeyBVPJPRYNQHAOPQ-UHFFFAOYSA-N
Wiswesser Line NotationL66J BZ ENW
LabNetwork Molecule IDLN00010351
Canonical SMILESNC1=CC=C([N+]([O-])=O)C2=C1C=CC=C2
InChIInChI=1S/C10H8N2O2/c11-9-5-6-10(12(13)14)8-4-2-1-3-7(8)9/h1-6H,11H2
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 1fragment
  • {SA} Amines, Building Blocks, C10, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Short: III/35D2 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 2: Aromatic Compounds Author: Mikhova, B. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D2 Year: 2005 Keyword: aromatic compounds; carbon-13; chemical shift; coupling constant; molecular structure ISBN: 978-3-540-20189-2 ISBN: 3-540-20189-0 Internet Resource: DOI:10.1007/b83345 RefComment: VIII, 291 p., Hardcover RefComment: Written for Science and engineers in the fields of physics, chemistry and physical chemistry who inted to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, orient by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei 11B and 31P, subvolume III/35B contains the nuclei 19F and 15N, subvolume III/35C contains the nucleus 1H, subvolume III/35D contains the nucleus 13C, subvolume III/35E contains the nucleus 17O, and subvolume III/35G contains the nucleus 77Se. More nuclei will be presented later.
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keywor

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSQM4370000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Hazard Codes Xi
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 25 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 118,49,1983

Storage condition RT, protect from light {LY} RT, protect from light {} {LY} RT, protect from light {} {} {LY} RT, protect from light {} {} {} {LY} RT, protect from light {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect

其他信息

  • 用途一:有机中间体。
  • 下游产品:
  • MSDS 信息:4-硝基萘胺(776-34-1).msds
  • Sigma Aldrich:776-34-1(sigmaaldrich)
  • 4-硝基1-萘胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0213 4-硝基-1-萘胺 4-Nitro-1-naphthylamine 5G 921元 2014/06/02 N0213 4-硝基-1-萘胺 4-Nitro-1-naphthylamine 25G 2940元
  • 方法一:由1-硝基萘和盐酸羟胺反应得到。将1-硝基萘和盐酸羟胺溶于95%乙醇，加热搅拌下将氢氧化钾甲醇溶液慢慢加入，加完料后，继续搅拌1h，将反应液倾入冰水中，析出4-硝基-1-萘胺，过滤，滤饼用水洗涤，在乙醇重结晶，得成品，收率约55%。
  • 4-硝基1-萘胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 N0213 4-硝基-1-萘胺 4-Nitro-1-naphthylamine 5G 1180元 2011/04/16 N0213 4-硝基-1-萘胺 4-Nitro-1-naphthylamine 25G 3620元
  • MOL 文件:776-34-1.mol
  • 上游原料:乙醇 --> 甲醇溶液 --> 1-硝基萘
  • TCI Shanghai:4-硝基-1-萘胺 4-Nitro-1-naphthylamine,>;98.0%(GC)(776-34-1)
  • 外观性质:金黄色粉末。
  • 图谱信息:4-硝基1-萘胺(776-34-1)质谱(MS) 4-硝基1-萘胺(776-34-1)红外图谱(IR2) 4-硝基1-萘胺(776-34-1)核磁图( 1 HNMR) 4-硝基1-萘胺(776-34-1)红外图谱(IR1)

系列性分类

  1. C13 - Amines

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