• 原料直供
• 试剂商城
• 直接询价

分类

• {SNA} Building Blocks, Chemical Synthesis, Isocyanate Monomers, Isocyanates, Monomers, Nitrogen Compounds, Organic Building Blocks, Polymer Science, 材料科学
• {SNA} Building Blocks, Chemical Synthesis, Isocyanate Monomers, Isocyanates, Materials Science, Monomers, Nitrogen Compounds, Organic Building Blocks, Polymer Science
• {uni_hamburg} no charge; isocyanate; 1fragment

产品应用

• HDI系是脂肪族二异氰酸酯（ADI）中最重要的单体。

相关文献及参考

• Short: III/35E
• Short: IV/20B
• Beilstein:4(2)711
• Short: III/38B

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 710 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 30 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,74,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 350 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TAKHAA Takeda Kenkyusho Ho.  Journal of the Takeda Research Laboratories.
   (Takeda Yakuhin Kogyo K.K., 2-17-85 Jusohon-machi, Yodogawa-ku, Osaka 532,
   Japan)  V.29-    1970-  Volume(issue)/page/year: 39,202,1980

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 60 mg/m3/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdun

其他信息

• 图谱信息:1,6-己二异氰酸酯(822-06-0)质谱(MS) 1,6-己二异氰酸酯(822-06-0)核磁图( 13 CNMR) 1,6-己二异氰酸酯(822-06-0)核磁图( 1 HNMR) 1,6-己二异氰酸酯(822-06-0)红外图谱(IR1) 1,6-己二异氰酸酯(822-06-0)Raman光谱 1,6-己二异氰酸酯(822-06-0)红外图谱(IR2)
• 用途一:用作生产聚氨酯涂料的原料，同时也用作干性醇酸树脂交联剂和合成纤维的原料
• Acros Organics:六亚甲基二异氰酸酯 1,6-Diisocyanatohexane, 99+%(822-06-0)
• Sigma Aldrich:822-06-0(sigmaaldrich)
• 蒸气压:0.05 mm Hg ( 25 °C)
• 敏感性:Moisture Sensitive
• 方法一:1.己二胺与二氧化碳或盐酸反应生成己二胺碳酸盐或盐酸盐，再经光化反应，然后经蒸馏除去溶液，经精馏得HDI。HDI与水和催化剂反应合成HDI缩二脲，然后经薄膜蒸发器蒸发，脱除残余HDI，加入溶纤剂配制成固含量75%的溶液，即得HDI缩二脲作为高档油漆用原料。每吨产品消耗已二胺（95%）约1280kg、光气4700kg。2.利用己二酸副产物己二酸盐酸盐与光气在溶剂氯苯中反应生成六亚甲基-1,6-二异氰酸酯，再经蒸馏脱溶剂及减压分馏制得成品。
• 外观性质:无色透明液体, 具有刺激性。
• 上游原料:乙醚 --> 四氢呋喃 --> 氨 --> 己二酸 --> 叠氮磷酸二苯酯 --> 1,6-已烷二胺 --> 薄膜蒸发器 --> 油漆 --> 缩二脲 --> 辛二酸 --> 1,8-双二甲氨基萘
• F:10-19-21
• TCI Shanghai:1,6-二异氰酰己烷 Hexamethylene Diisocyanate,>;98.0%(GC)(822-06-0)
• 稍有刺激性臭味，易燃。不溶于冷水，溶于苯、甲苯、氯苯等有机溶剂，与醇、酸、胺能反应，遇水、碱会分解。在铜、铁等金属氯化物存在下能聚合
• 1,6-己二异氰酸酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0324 二异氰酸六亚甲基酯 Hexamethylene Diisocyanate 25ML 137元 2014/06/02 H0324 二异氰酸六亚甲基酯 Hexamethylene Diisocyanate 500ML 574元 2010/06/21 115190250 1,6-己二异氰酸酯 1,6-Diisocyanatohexane 99+% 25 GR 300元
• MSDS 信息:六甲撑二异氰酸酯(822-06-0).msds
• 海关编码:29291090
• 下游产品:二异氰酸酯改性的EAM树脂用作口腔正畸胶粘剂 --> CC-2SH胶粘剂前牙复合树脂
• 用途三:HDI系是脂肪族二异氰酸酯（ADI）中最重要的单体。
• 用途二:HDI系是脂肪族二异氰酸酯（ADI）中最重要的单体，约占ADI总需求量的60%。大部分HDI被制备成HDI缩二脲或HDI三聚体。HDI及HDI缩二脲、三聚体是生产聚氨酯涂料及聚氨酯弹性体的重要原料。以HDI 、HDI缩二脲或三聚体为原料生产的聚氨酯涂料，具有不泛黄、耐候性强等特点，广泛用于航空、汽车、建筑、木器、塑料、皮革等方面。该产品也用作干性醇酸树脂交联剂和合成纤维的原料
• MOL 文件:822-06-0.mol
• Alfa Aesar:1,6-二异氰酰基己烷,98+% 1,6-Diisocyanatohexane, 98+%(822-06-0)