4-Phenoxyphenol 4-苯氧基苯酚

CAS 831-82-3 MFCD00002331

化学结构图

831-82-3
SMILES: Oc1ccc(Oc2ccccc2)cc1

化学属性

Mol. FormulaC12H10O2
Mol. Weight186.21
Melting Point80-84°C
Flash Point170°C
TSCAYes
Boiling Point177-180 °C at 11 mmHg
Solubility不溶
Appearance 4-羟基二苯醚纯品为白色结晶,m.p. 85~86℃,b.p. 177~180℃(1.46kPa),不溶于水,溶于苯、乙醚等有机溶剂。

别名和识别编码

Chemical Name4-Phenoxyphenol
Synonym 4-Phenoxyphenol {LY} 4-Phenoxyphenol {} {LY} 4-Phenoxyphenol {} {} {LY} 4-Phenoxyphenol {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number831-82-3
PubChem Substance ID87575067
EC Number212-611-1
Beilstein Registry Number6(2)841
MDL NumberMFCD00002331
Reaxys-RN2047182
Chemical Name Translation4-苯氧基苯酚
LabNetwork Molecule IDLN00197821
InChIInChI=1S/C12H10O2/c13-10-6-8-12(9-7-10)14-11-4-2-1-3-5-11/h1-9,13H
Canonical SMILESOC1=CC=C(OC2=CC=CC=C2)C=C1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {Chemicalbook} 农药中间体: 杀虫剂中间体: 氨基甲酸酯类杀虫剂
  • {SA} Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols

相关文献及参考

  • Beil. 6 ,IV,5724
  • Aldrich MSDS 1 , 1452:C / Corp MSDS 1 (2), 2751:D / FT-IR 1 (1), 1115:C / FT-IR 2 (2), 1901:D / FT-NMR 1 (2), 316:B / NMR-Reference 2 (1), 914:D / RegBook 1 (1), 1307:F / Structure Index 1 , 199:D:7 / Vapor Phase 3 , 1044:B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302+H312+H332
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P312+P362+P364
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P304+P340+P312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P305+P351+P338+P337+P313
  • P305+P351+P338
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Signal word Warning
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 方法一:4-羟基二苯醚的制备方法很多,其中两条工艺路线原料成本低,工艺简单。 对苯二酚与溴苯反应 以对苯二酚为原料,加入二甲基亚砜溶剂及96%氢氧化钾溶液,同时通入氮气,搅拌下加热至140℃时,缓慢滴加溴苯溶液,在(145±5)℃温度下反应8h;反应完毕,水相经盐酸酸化,析出结晶,收率为88%~89%。 对氯苯酚法 向装有温度计、分水器和磁力搅拌器的500mL三口瓶中加入235g(2.50mol)苯酚、42.1g(0.75mol)氢氧化钠和150mL甲苯,加热分出水。脱溶剂后,加入1.75g铜盐作催化剂,滴加64.3g(0.50 mol)对氯苯酚,在175℃下反应8h。回收苯酚后,用稀盐酸进行酸化。用乙醚提取,用水洗。干燥后蒸馏,收集145~152℃(800Pa)馏分,得产品60g,收率64%,m. p. 83~84℃(文献值m. p. 85~86℃)。
  • 用途一:用于高效、低毒农药双氧威、蚊蝇醚的合成
  • 4-苯氧基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0950 4-苯氧基苯酚 4-Phenoxyphenol 500G 6700元 2014/06/02 P0950 4-苯氧基苯酚 4-Phenoxyphenol 25G 847元 2010/06/21 213310250 4-苯氧基苯酚 4-Phenoxyphenol 99% 25 GR 1481元
  • 图谱信息:4-苯氧基苯酚(831-82-3)核磁图( 1 HNMR) 4-苯氧基苯酚(831-82-3)红外图谱(IR1) 4-苯氧基苯酚(831-82-3)核磁图( 13 CNMR) 4-苯氧基苯酚(831-82-3)红外图谱(IR2) 4-苯氧基苯酚(831-82-3)质谱(MS)
  • 上游原料:二甲基亚砜 --> 溴苯 --> 1,4-苯二酚 --> 氢氧化钾溶液 --> 分水器 --> 磁力搅拌器
  • 检测方法:GC
  • 海关编码:29095090
  • Acros Organics:4-苯氧基苯酚 4-Phenoxyphenol, 99%(831-82-3)
  • color:colorless to light brown
  • Alfa Aesar:4-苯氧基苯酚,99% 4-Phenoxyphenol, 99%(831-82-3)
  • Hazard Note:Irritant
  • TCI Shanghai:4-苯氧基苯酚 4-Phenoxyphenol,>;95.0%(GC)(831-82-3)
  • MOL 文件:831-82-3.mol
  • Sigma Aldrich:831-82-3(sigmaaldrich)
  • MSDS 信息:Hydroquinone monophenyl ether(831-82-3).msds
  • 用途二:4-羟基二苯醚又名4-苯氧基苯酚,是氨基甲酸酯类杀虫剂双氧威、卫生杀虫剂吡丙醚等的中间体。

系列性分类


相关产品推荐