(1S,1’S)-1,1’-Bis[Bis[3,5-Bis(Trifluoromethyl)Phenyl]Phosphino]-2,2’-Bis[(S)-(Dimethylamino)Phenylmethyl]Ferrocene (1S,1’S)-1,1’-双{双[3,5-双(三氟甲基)苯基]膦基}-2,2’-双[(S)-α-(二甲氨基)苯甲基]二茂铁
CAS 849925-10-6 MFCD08561144
化学结构图
SMILES: [Fe].CN(C)[C@@H](C1C=CC=CC=1)[C]1[CH][CH][CH][C]1P(C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F.CN(C)[C@@H](C1C=CC=CC=1)[C]1[CH][CH][CH][C]1P(C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F |^1:11,12,13,14,15,55,56,57,58,59|
化学属性
| Mol. Formula | C60H42F24FeN2P2 |
|---|---|
| Mol. Weight | 1364.74 |
别名和识别编码
| Chemical Name | (1S,1’S)-1,1’-Bis[Bis[3,5-Bis(Trifluoromethyl)Phenyl]Phosphino]-2,2’-Bis[(S)-(Dimethylamino)Phenylmethyl]Ferrocene |
|---|---|
| CAS Number | 849925-10-6 |
| Synonym | (RP,R′P)-1,1′-双{双[3,5-双(三氟甲基)苯基]膦基}-2,2′-双[(S)-α-(二甲氨基)苯甲基]二茂铁 Mandyphos SL-M003-2 (1S,1′S)-1,1′-双[双[3,5-双(三氟甲基)苯基]膦基]-2,2′-双[(S)-(二甲氨基)苯基甲基]二茂铁（符合 CAS 标准） Mandyphos SL-M003-2 (1S,1′S)-1,1′-双[双[3,5-双(三氟甲基)苯基]膦基]-2,2′-双[(S)-(二甲氨基)苯基甲基]二茂铁（符合 CAS 标准） |
| MDL Number | MFCD08561144 |
| PubChem Substance ID | 24886564 |
| Chemical Name Translation | (1S,1’S)-1,1’-双{双[3,5-双(三氟甲基)苯基]膦基}-2,2’-双[(S)-α-(二甲氨基)苯甲基]二茂铁 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Mandyphos Ligands, Privileged Ligands and Complexes, Solvias Ligands and Complexes
产品应用
- Used in the process for preparing ?-carboxamide pyrrolidine derivatives. Coordination compound.
相关文献及参考
- Lygo, B., et al.: Tetrahedron Lett., 50, 3363 (2009)
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