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分类

• A, A-B, AM to AQ, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Pesticides, Pesticides & Metabolites, Rodenticides
• {SA} A, A-B, AM to AQ, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Pesticides, Pesticides & Metabolites, Rodenticides

产品应用

• 作灭鼠药。

相关文献及参考

• Merck 14 ,722

安全信息

GHS Symbol

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : 2500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PSEBAA Proceedings of the Society for Experimental Biology and Medicine.
   (Academic Press, Inc., 1 E. First St., Duluth, MN 55802)  V.1-    1903/04-
   Volume(issue)/page/year: 62,22,1946

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BCFAAI Bollettino Chimico Farmaceutico.  (Societa Editoriale Farmaceutica,
   Via Ausonio 12, 20123 Milan, Italy)  V.33-    1894- Volume(issue)/page/year:
   97,289,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 380 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCOC** Pesticide Chemicals Official Compendium, Association of the American
   Pesticide Control Officials, Inc., 1966.  (Topeka, KS)
   Volume(issue)/pa

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       :

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 500 nmol/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 3,11,1981

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 1600 ug/L
REFERENCE :
   NCIMAV National Cancer Institute, Monograph.  (U.S. Government Printing
   Office, Supt. of Documents, Washington, DC 20402)  No.1-    1959-
   Volume(issue)/page/year: 58,243,1981

其他信息

• 外观性质:白色或灰色、无臭粉末或粒状结晶，味苦。
• 毒性分级:剧毒
• MSDS 信息:α-萘硫脲(86-88-4).msds
• 安妥价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 415430250 安妥 1-(1-Naphthyl)-2-thiourea 97% 25 GR 1601元
• 图谱信息:安妥(86-88-4)红外图谱(IR1) 安妥(86-88-4)红外图谱(IR2) 安妥(86-88-4)质谱(MS) 安妥(86-88-4)核磁图( 1 HNMR)
• 灭火剂:砂土、干粉、泡沫
• 储运特性:库房通风低温干燥; 与食品原料分开储运
• 类别:农药
• 用途一:硫脲类急性杀鼠剂。选择性强，主要用于防治褐家鼠及黄毛鼠，对其他鼠种毒性较低。该药剂有强胃毒作用，也可损害鼠类呼吸系统。一般食后6～72h内死亡。安妥适口性好，初次使用效果理想，但摄入亚致死剂量后会产生很强的耐药性，耐药能力可提高7～50倍，并对其他硫脲衍生物产生交互抗性。安妥以配制毒饵来防治鼠类，毒饵有效成分为0.5%～2%，配制方法同磷化锌杀鼠剂。例1，0.5%安妥胡萝卜毒饵（或用水果、蔬菜代替），每房间放2～3堆，每堆毒饵量10～20g,3d后回收剩余毒饵。例2， 安妥原粉1份、鱼骨粉1份、食用油1份、玉米面97份，混合均匀后加适量水和成面团，并制成黄豆粒大小毒饵丸，每房间放量2～3堆，每堆10～20g，防治褐家鼠效果甚好。也可制成2%安妥小麦毒饵应用。
• 可燃性危险特性:受热分解有毒氧化氮、氧化硫气体
• 方法二:用α-萘胺与硫氰酸铵（或硫氰酸钠、硫氰酸钾）反应而得。1.α-萘胺盐酸盐的制备。2.α-萘硫脲的制备。
• Acros Organics:1-(1-Naphthyl)-2-thiourea,97%(86-88-4)
• 急性毒性:口服-大鼠 LD50: 6 毫克/公斤; 口服-小鼠 LD50: 5 毫克/公斤
• MOL 文件:86-88-4.mol
• 下游产品:1-萘异硫氰酸酯
• 职业标准:TWA 0.3 毫克/立方米； 0.9 毫克/立方米
• Sigma Aldrich:86-88-4(sigmaaldrich)
• 方法一:制备方法一 α-萘胺与硫氰酸铵反应制得安妥。 制备方法二 制备方法三 以上3 种制备方法以第一种制备方法步骤最少，收率也高，为工业生产应用。
• 用途二:作灭鼠药。
• Alfa Aesar:1-萘基硫脲,97% N-(1-Naphthyl)thiourea, 97%(86-88-4)
• 25℃时在水中的溶解度为0.06g/100ml，在丙醇中的溶解度为2.43g/100ml，颇易溶于热乙醇。无臭，味苦，剧毒。
• 上游原料:硫氰酸铵 --> 硫氰酸钠 --> 1-萘胺 --> 硫氰酸钾 --> β-萘胺盐酸