Trichloroisocyanuric acid 三氯异氰尿酸

CAS 87-90-1 MFCD00006553

化学结构图

87-90-1
SMILES: O=c1n(Cl)c(=O)n(Cl)c(=O)n1Cl

化学属性

Mol. FormulaC3Cl3N3O3
Mol. Weight232
Melting Point245-251
Density2.19
Flash Point>250°(482°F)
TSCAYes
Solubility1.2 G/100ML (25 ºC)
Stability对湿度敏感

别名和识别编码

Chemical NameTrichloroisocyanuric Acid
Synonym 1,3,5-TRICHLORO-2,4,6-TRIAZINETRIONE 1,3,5-Triazine, 2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro- 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro- 1,3,5-Trichlor-1,3,5-triazin-2,4,6-trion 1,3,5-Trichlorhexahydro-1, 1,3,5-Trichloro-s-triazinetrione 1,3,5-trichloro-1,3,5-triazine-2,4,6(1H,3H,5H)-trione Fi Clor 91 Hi-Lite 90 Hi-Lite 90G Isocyanuric chloride Isocyanuric chloride, Symclosene Symclosen TCICA 三氯三嗪三酮 三氯 Trichlorocyanuric acid s-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro- s-Triazine-2,4,6(1H,3H,5H)-trione, trichloro- trichloroisocyanuric acid {} {} {} {} {Chemi {} {} {} {} {} {Chemi {} {} {} {} {} {} {Chemical {} {} {} {} {} {} {} {AL {} {} {} {} {} {} {} {} {Chemicalbook} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number87-90-1
PubChem Substance ID6909
EC Number201-782-8
Beilstein Registry Number202022
MDL NumberMFCD00006553
Reaxys-RN202022
Merck Number9641
Chemical Name Translation三氯异氰尿酸
Wiswesser Line NotationT6NVNVNVJ AG CG EG
LabNetwork Molecule IDLN00194511
InChIInChI=1S/C3Cl3N3O3/c4-7-1(10)8(5)3(12)9(6)2(7)11
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分类

  • Building Blocks, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Triazines
  • {SNA} Building Blocks, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Triazines
  • {uni_hamburg} no charge; nitrogen heterocycle; 6RingOnly; 6ring; urea; 1fragment

产品应用

  • 该品具有极强的杀菌、漂白作用，广泛用于民用卫生，畜牧养殖业以及植保等作高效杀菌消毒剂，棉、麻化纤织物的洗涤漂白剂，羊毛防缩剂，也可用于橡胶氯化，电池材料，有机合成工业以及衣物的干法漂白等。

相关文献及参考

  • Note: Confusion with Cyanuric chloride, L03442, exists in some earlier Fieser references.
  • Low-cost chlorinating and oxidizing agent; review: Org. Process Res. Dev., 6, 384 (2002). Aromatic compounds can be chlorinated either on the ring (ionic conditions) or on the side chain (free-radical conditions): J. Org. Chem., 35, 719 (1970). In the presence of BF3 etherate, ketones are ɑ-chlorinated at the more substituted position: Synth. Commun., 15, 385 (1985). In combination with pyridine, sulfides are selectively oxidized to sulfoxides: Synth. Commun., 31, 245 (2001), thiols to disulfides: Synth. Commun, 31, 1825 (2001), and secondary alcohols to ketones: Synth. Commun., 22, 1589 (1992). In the presence of methanol in acetonitrile, acetone or dichloromethane, the same reagent system converts aldehydes directly to methyl esters: Synth. Commun., 26, 2633 (1996). Effective co-oxidant for the TEMPO-catalyzed chemoselective oxidation of alcohols to aldehydes and ketones: Org. Lett., 3, 3041 (2001). In acetic acid, pyridines are converted to their N-oxides: Synth. Commun., 34, 247 (2004).
  • Merck: 14,9641 Beilstein:26,256
  • Short: III/31a
  • With NaNO2 and wet silica selective mononitration of phenols is accomplished under mild conditions: Synlett, 191 (2003). Effectively catalyzes both the protection and deprotection of alcohols as their tetrahydropyranyl ethers: Synth. Commun., 34, 3623 (2004).
  • For a brief feature on uses in synthesis, see: Synlett, 2265 (2005).
  • Merck: 14,9641

安全信息

GHS Symbol
WGK Germany2
Hazard Codes 5.1 O,Xn,N O;Xn;N
Hazard statements
  • H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSXZ1925000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施，避免与可燃物混合/...
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P301+P330+P331
  • P302+P350
  • P302+P352
  • P302+P361+P354
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2468
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S41 In case of fire and/or explosion do not breathe fumes 着火和/或爆炸时，不要吸入烟雾；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S8 Keep container dry 保持容器干燥；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R31 Contact with acids liberates toxic gas 与酸接触释放出有毒气体
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R50/53
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
Storage condition Moisture Sensitive
Packing GroupII
Hazard Class5.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1900 mg/kg
TOXIC EFFECTS :
   Behavioral - coma
REFERENCE :
   MONS** Monsanto Co. Toxicity Information.  (Monsanto Industrial Chemicals
   Co., Bancroft Bldg., Suite 204, 3411 Silverside Rd., Wilmington, DE 19810)
   Volume(issue)/page/year: -,-,1972

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 3570 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - ulceration or bleeding from stomach
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,167,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 406 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   42,417,1977

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >2 gm/m3/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   MONS** Monsanto Co. Toxicity Information.  (Monsanto Industrial Chemicals
   Co., Bancroft Bldg., Suite 204, 3411 Silverside Rd., Wilmington, DE 19810)
   Volume(issue)/page/year: -,-,1972

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 5010 mg/kg
TOXIC EFF

Restrict 危险品

其他信息

  • 类别:氧化剂
  • Alfa Aesar:三氯异三聚氰酸,97% Trichloroisocyanuric acid, 97%(87-90-1)
  • 毒性分级:中毒
  • 下游产品:2-氯喹啉 --> 1-氟-4-(三氟甲基硫代)苯 --> 6-氨基吲哚 --> 6-硝基吲哚
  • Acros Organics:三氯异氰尿酸 Trichloroisocyanuric acid, 97%(87-90-1)
  • 上游原料:氢氧化钠 --> 硫酸 --> 尿素 --> 氯 --> 氰尿酸
  • 外
  • MSDS 信息:三氯异氰尿酸(87-90-1).msds
  • 图谱信息:三氯异氰尿酸(87-90-1)红外图谱(IR1) 三氯异氰尿酸(87-90-1)红外图谱(IR2) 三氯异氰尿酸(87-90-1)质谱(MS) 三氯异氰尿酸(87-90-1)Raman光谱
  • TCI Shanghai:三氯异氰脲酸 Trichloroisocyanuric Acid,>;95.0%(T)(87-90-1)
  • 杀菌消毒作用:三氯异氰尿酸是一种极强的氧化剂和氯化剂，具有高效、广谱、较为安全的消毒作用，在氯代异氰尿酸类产品中杀菌能力最强，对细菌、病毒、真菌、霉菌、霍乱孤菌、芽孢等都有杀灭作用，对球虫卵囊也有一定杀灭作用,可用于环境、饮水、水果蔬菜、畜禽饲槽、鱼塘、蚕房等的消毒,使用方法为用粉剂配制4-6毫克/千克浓度饮水消毒，用200-400毫克/千克浓度的溶液进行环境、用具消毒。 三氯异氰尿酸具有灭藻、除臭、净水、漂白之功效，比二氯异氰尿酸钠的杀菌、漂白功能更强，效果更好，广泛用于棉、麻化纤织物的洗涤漂白剂、羊毛防缩剂、橡胶氯化，油钻井泥浆污水的灭菌处理、电池材料、游泳池消毒、饮用水消毒、工业污水和生活污水的处理、食品加工业、饮食卫生业、水产养殖业、日用化学工业、医院、托幼、防疫、垃圾处理、宾馆、餐厅及天灾、人祸后的大面积灭菌，防传染等。 使用方法: 1、游泳池消毒：按2-3g/m3计算投放量，作用30-60分钟。 2、公共场所及地面消毒：1500-3000倍水稀释液喷洒、擦拭，作用30分钟。传染病疫区，用150-200倍水稀释液喷洒消毒。 3、白色衣物、被单消毒：较清洁物品2000-3000倍稀释，浸泡10分钟；污染较重物品，500倍稀释，浸泡20分钟。 4、卫生间、便器刷洗消毒，300倍水稀释液，作用时间30分钟。 5、非金属医疗器械消毒：500-1000倍水稀释液，浸泡30分钟；带脓血器具消毒，用100倍水稀释液，作用时间30分钟。
  • 灭火剂:大量水
  • 用途二:该品具有极强的杀菌、漂白作用，广泛用于民用卫生，畜牧养殖业以及植保等作高效杀菌消毒剂，棉、麻化纤织物的洗涤漂白剂，羊毛防缩剂，也可用于橡胶氯化，电池材料，有机合成工业以及衣物的干法漂白等。
  • 三氯异氰尿酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0620 三氯异氰脲酸 Trichloroisocyanuric Acid 500G 393元 2014/06/02 T0620 三氯异氰脲酸 Trichloroisocyanuric Acid 25G 157元 2010/06/21 421540010 三氯异氰尿酸 Trichloroisocyanuric acid 99% 1 KG 719元
  • 海关编码:29336980
  • 敏感性:Hygroscopic
  • 刺激数据:皮肤-兔子 500 毫克/24小时 中度; 眼睛-兔子 50 微克/24小时 重度
  • 爆炸物危险特性:与铵盐、氨、尿素混合生成易爆三氯化氮
  • 储运特性:库房通风低温干燥; 与燃料、有机物、易氧化物分开存放
  • MOL 文件:87-90-1.mol
  • Sigma Aldrich:87-90-1(sigmaaldrich)
  • 散发次氯酸刺激性气味，水中溶解度: 12 g/L (25°C) ，溶于高极性溶剂并分解形成次氯酸HCLO 。工业品含量一般为90%左右。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Thiophenes 噻吩
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Triazines 三嗪
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Triazines - Halogenated Heterocycles
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Triazines - Halogenated Heterocycles
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Thiophenes
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Halogenation

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