Di-tert-butyl Azodicarboxylate 偶氮二甲酸二叔丁酯
CAS 870-50-8 MFCD00015001
化学结构图
SMILES: CC(C)(C)OC(=O)N=NC(=O)OC(C)(C)C
化学属性
| Mol. Formula | (CH3)3CO2C-N=N-CO2C(CH3)3 |
|---|---|
| Mol. Weight | 230 |
| Density | 1.06 |
| Melting Point | 89-92 |
| TSCA | No |
| Solubility | 不溶 |
别名和识别编码
| Chemical Name | Di-tert-butyl Azodicarboxylate |
|---|---|
| CAS Number | 870-50-8 |
| EC Number | 212-796-9 |
| Beilstein Registry Number | 1911434 |
| MDL Number | MFCD00015001 |
| Synonym | 1,2-Bis(tert-butoxycarbonyl)diazene 偶氮二甲酸二叔丁酯 Di-Tert-ButylAzodicarboxylate(Dbad) Bis(1,1-dimethylethyl)azodicarboxylate DBAD Di-tert-butyl azodiformate NSC 109889 Di-tert-B-butyl azodicarboxylate, 98% 偶氮二羧酸二叔丁酯 二叔丁基偶氮二异丁腈 Azobis(formic acid tert-butyl) ester Diazene-1,2-dicarboxylic acid di-tert-butyl ester DI-TERT-BUTYL AZODICARBOXYLATE 偶氮二羟酸二叔丁酯 Azodicarboxylic acid di-tert-butyl ester Di-tert-butyl Azodicarboxylate (20% in Toluene) |
| PubChem Substance ID | 97268 |
| Alfabeta Name | DIBUTYLAZODICARBOXYLATE TERT-- |
| Reaxys-RN | 1911434 |
| Chemical Name Translation | 偶氮二甲酸二叔丁酯 |
| InChIKey | QKSQWQOAUQFORH-VAWYXSNFSA-N |
| LabNetwork Molecule ID | LN00223217 |
| InChI | InChI=1S/C10H18N2O4/c1-9(2,3)15-7(13)11-12-8(14)16-10(4,5)6/h1-6H3 |
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} C-X Bond Formation (Non-Halogen), Chemical Synthesis, Mitsunobu, Synthetic Reagents
- {SNA} 12 Principles Aligned Products, C-X Bond Formation (Non-Halogen), Chemical Synthesis, Greener Alternative Products, Mitsunobu, Synthetic Reagents
相关文献及参考
- Useful "NH2 +" synthon for enantioselective amination reactions: J. Am. Chem. Soc., 108, 6394, 6395, 6397 (1986); Tetrahedron Lett., 29, 6765 (1988).
- Aza-dienophile. The ester groups are readily removed from adducts by acid: J. Org. Chem., 26, 4336 (1961); 38, 2043 (1973); 40, 563 (1975).
- Mitsunobu reaction with alcohols gives a direct route to the corresponding N,N'-di-Boc protected hydrazine derivatives: Tetrahedron Lett., 37, 4327 (1996).
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P332+P313
- P302+P352+P332+P313+P362+P364
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P303+P361+P353
- P337+P313
- P403+P233
- P201 Obtain special instructions before use. 使用前获取专门指示。
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
其他信息
- Alfa Aesar:偶氮二羧酸二叔丁酯,98% Di-tert-butyl azodicarboxylate, 98%(870-50-8)
- 不溶于水，溶于二氯甲烷和其它的有机氯溶剂。
- Sigma Aldrich:870-50-8(sigmaaldrich)
- 偶氮二甲酸二叔丁酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D3544 偶氮二甲酸二叔丁酯(20%的甲苯溶液) Di-tert-butyl Azodicarboxylate (20% in Toluene) 25G 580元 2010/06/21 366920250 偶氮二甲酸二叔丁酯 Di-tert-butyl azodicarboxylate 98% 25 GR 1809元 2010/06/21 366920050 偶氮二甲酸二叔丁酯 Di-tert-butyl azodicarboxylate 98% 5 GR 480元
- 图谱信息:偶氮二甲酸二叔丁酯(870-50-8)质谱(MS) 偶氮二甲酸二叔丁酯(870-50-8)红外图谱(IR1)
- TCI Shanghai:偶氮二甲酸二叔丁酯(20%的甲苯溶液) Di-tert-butyl Azodicarboxylate (20% in Toluene)(870-50-8)
- Hazard Note:Irritant
- MOL 文件:870-50-8.mol
- Acros Organics:偶氮二甲酸二叔丁酯 Di-tert-butyl azodicarboxylate, 98%(870-50-8)
- 敏感性:Light Sensitive
京ICP备2020036287号