4-(Bromomethyl)-6,7-Dimethoxy-2H-Chromen-2-One 4-(溴甲基)-6,7-二甲氧基-2H-苯并吡喃-2-酮

CAS 88404-25-5 MFCD00011570

化学结构图

88404-25-5
SMILES: COC1=CC2C(CBr)=CC(=O)OC=2C=C1OC

化学属性

Mol. FormulaC12H11BrO4
Mol. Weight299
Melting Point211.0 to 216.0 deg-C
TSCANo

别名和识别编码

Chemical Name4-(Bromomethyl)-6,7-Dimethoxy-2H-Chromen-2-One
CAS Number88404-25-5
Synonym 4-(Bromomethyl)-6,7-dimethoxy-2H-1-benzopyran-2-one 4-溴甲基-6,7-二甲氧基香豆素
MDL NumberMFCD00011570
PubChem Substance ID87563187
Beilstein Registry Number4750487
Reaxys-RN4750487
Chemical Name Translation4-(溴甲基)-6,7-二甲氧基-2H-苯并吡喃-2-酮
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分类

  • Analytical Reagents, Analytical/Chromatography, Biochemicals and Reagents, Building Blocks, Chemical Synthesis, Coumarins, Derivatization Reagents, Derivatization Reagents HPLC, Fluorescence, Fluorescent Labels, Fluorescent Probes, Labels, Particles and Stains, Halogenated, Halogenated Heterocycles, Heterocyclic Building Blocks, Luminescent Compounds/Detection, Other Fluorescent Labels, Wavelength Index
  • {SNA} Building Blocks, Chemical Synthesis, Coumarins, Derivatization Reagents, Derivatization Reagents HPLC, Fluorescence, Fluorescent Labels,

产品应用

  • A fluorescent labeling reagent for the reversed-phase HPLC separation and detection of carboxylic acids.

相关文献及参考

  • J. Chromatogr., 269, 81 (1983),
  • J. Chromatogr., 309, 403 (1984),
  • 1. J. Chromatogr. 309 , 403, (1984) 摘要
  • 2. J. Chromatogr. 269 , 81, (1983)
  • Corp MSDS 1 (1), 548:D / FT-IR 2 (2), 2908:C / RegBook 1 (2), 1943:H / Structure Index 1 , 312:B:7

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P304+P340
  • P304+
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Storage condition 0-10 0-10°C
UN Number 3261 UN3261
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Packing GroupII
Hazard Class8

系列性分类


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