1-​Naphthalenamine, N-​phenyl- N-苯基-1-萘胺

CAS 90-30-2 MFCD00003878

化学结构图

90-30-2
SMILES: c1ccc(Nc2cccc3ccccc23)cc1

化学属性

Mol. FormulaC16H13N
Mol. Weight219.28
Density1.1
Boiling Point226°C at 760 mmHg
Melting Point60-62°C
TSCAYes
Solubility不溶
Stability对光敏感
Flash Point>110°C

别名和识别编码

Chemical Name1-​Naphthalenamine, N-​phenyl-
CAS Number90-30-2
EC Number201-983-0
Beilstein Registry Number12,1224
MDL NumberMFCD00003878
Synonym N-Phenylnaphthalen-1-amine {LY} N-Phenylnaphthalen-1-amine {} {LY} N-Phenylnaphthalen-1-amine {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} { {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenyl
Reaxys-RN2211174
PubChem Substance ID7013
Chemical Name TranslationN-苯基-1-萘胺
Wiswesser Line NotationL66J BMR
LabNetwork Molecule IDLN00196883
InChIInChI=1S/C16H13N/c1-2-9-14(10-3-1)17-16-12-6-8-13-7-4-5-11-15(13)16/h1-12,17H
Canonical SMILESC12=CC=CC=C1C(NC3=CC=CC=C3)=CC=C2
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 1fragment

相关文献及参考

  • Short: IV/20C
  • Short: II/3
  • Short: EINECS
  • Beilstein:12,1224

安全信息

Signal word
GHS Symbol
WGK Germany2
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S29 Do not empty into drains 不要排入下水道;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P302+P352+P333+P313+P362+P364
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P301+P312+P330
  • P308+P311
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
RTECSQM4500000
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Packing GroupIII
UN Number UN3077 3077
Hazard Codes Xn;N Xn,N
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class9
TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 17280 mg/kg/9W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Kidney, Ureter, Bladder - Kidney tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   44,3098,1984

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5400 mg/kg/9W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Kidney, Ureter, Bladder - Kidney tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   44,3098,1984

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 8 gm/kg
TOXIC EFFECTS :
   Liver - other changes
   Kidney, Ureter, Bladder - other changes
   Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0535072

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1231 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(issue)/page/year: TR-74-78,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1625 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(issue)/page/year: TR-74-78,1974

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human Lung
DOSE/DURATION           : 50 mg/L
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A041-973

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Human Cells - not otherwise specified
DOSE/DURATION           : 27500 ug/L
REFERENCE :
   ITCSAF In Vitro.  (Rockville, MD)  V.1-20, 1965-85.  For publisher
   information, see ICDBEO.  Volume(issue)/page/year: 17,719,1981

TYPE OF TEST            : Dominant lethal test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 830 mg/kg/5D (Intermittent)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A041-973

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   SYSWAE Shiyan Shengwu Xuebao.  Journal of Experimental Biology.  (China
   International Book Trading Corp., POB 2820, Beijing, Peop. Rep. China) V.1- 
     1953-    Suspended 1966-77.  Volume(issue)/page/year: 12,41,1979

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 500 nL/plate
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A041-973

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 60 mg/L
REFERENCE

其他信息

  • 图谱信息:1-萘氨基苯(90-30-2)红外图谱(IR3) 1-萘氨基苯(90-30-2)核磁图( 13 CNMR) 1-萘氨基苯(90-30-2)红外图谱(IR1) 1-萘氨基苯(90-30-2)核磁图( 1 HNMR) 1-萘氨基苯(90-30-2)红外图谱(IR2) 1-萘氨基苯(90-30-2)质谱(MS)
  • 外观性质:白色至淡黄色晶体, 遇日光逐渐变紫色。
  • 下游产品:碱性蓝 26
  • TCI Shanghai:N-苯基-1-萘胺 N-Phenyl-1-naphthylamine,>;97.0%(N)(90-30-2)
  • 用途二:该品系芳香族仲胺类防老剂。用于天然橡胶、二烯类合成橡胶、氯丁橡胶。是再生胶通用型防老剂,也用于氯丁胶乳。对热、氧、屈挠、天候老化、疲劳有良好的防护作用。在氯丁橡胶中兼有抗臭氧老化的性能,对有害金属也有一定的抑制作用。该品常与其他防老剂如AP,DNP,尤其是4010和4010N并用。在干胶中易分散,亦易分解于水中。在橡胶中的溶解度高达5%,用量为3-4份时不喷霜。由于其具有污染性、迁移性及在日光下颜色变深的特性,因此不适用于白色及浅色制品,主要用于制造轮胎、胶管、胶带、胶辊、胶鞋、海底电缆绝缘层等。在塑料工业中,该品可作聚乙烯的热稳定剂。工业品因含有1-萘胺和苯胺,故有毒性。
  • 海关编码:29214980
  • 上游原料:氨基苯 --> 对氨基苯磺酸 --> 1-萘胺
  • 1-萘氨基苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0197 N-苯基-1-萘胺 N-Phenyl-1-naphthylamine 500G 764元 2014/06/02 P0197 N-苯基-1-萘胺 N-Phenyl-1-naphthylamine 25G 135元 2010/06/21 147162500 1-萘氨基苯 N-Phenyl-1-naphthylamine 98% 250 GR 834元
  • 用途一:适用于天然橡胶和氯丁橡胶,可与其他防老剂混合使用
  • 方法一:由1-萘胺与苯胺在对氨基苯磺酸催化下,于250℃进行缩合而得。将苯胺、对氨基苯磺酸、熔化好的1-萘胺投入缩合锅,在250℃进行缩合,反应结束后进行分馏。在低真空下蒸出苯胺入混合馏分(套用),根据馏分的实测凝固点决定馏分的分割点。蒸出防老剂甲和高沸物。熔融的防老剂甲经冷却切片、包装即为成品。原料消耗(kg/t)1-萘胺(99%) 710苯胺(99.2) 425
  • 遇日光逐渐变为紫色。溶于乙醇、乙酸、乙醚、氯仿和苯,微溶于水。低毒,半数致死量(大鼠,经口)1625mg/kg。有刺激性。
  • Alfa Aesar:N-苯基-1-萘胺,97% N-Phenyl-1-naphthylamine, 97%(90-30-2)
  • MOL 文件:90-30-2.mol
  • Acros Organics:N-苯基-1-萘胺 N-Phenyl-1-naphthylamine, 98%(90-30-2)
  • Sigma Aldrich:90-30-2(sigmaaldrich)
  • 用途三:制造染料和其他有机化合物。橡胶抗氧剂。防老剂。对空气、热和屈挠老化都有防护作用,但制品遇光变色。适用于天然橡胶和氯丁橡胶。
  • MSDS 信息:N-苯基-α萘胺(90-30-2).msds

系列性分类


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