Lithium bis(trifluoromethanesulphonyl)imide 双三氟甲烷磺酰亚胺锂

CAS 90076-65-6 MFCD00210017

化学结构图

90076-65-6
SMILES: [Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

化学属性

Mol. FormulaC2F6LiNO4S2
Mol. Weight287
Melting Point234-238
TSCAT
Density1.334
Appearance 白色结晶或粉末。
SolubilitySoluble in water (10 mg/ml).,
Stability对湿度敏感

别名和识别编码

Chemical NameLithium bis(trifluoromethanesulphonyl)imide
CAS Number90076-65-6
Alfabeta NameLITHIUMBISTRIFLUOROMETHANESULFONYLIMIDE ()
MDL NumberMFCD00210017
Synonym 1,1,1-trifluoro-n-[(trifluoromethyl)sulfonyl]-methanesulfonamidlithiumsalt BISTRIFLUOROMETHANESULFONIMIDE LITHIUM SALT Bis(trifluoromethane)sulfonimide lithium salt LITHIUM TRIFLUOROMETHANESULFONIMIDE Lithiumbis(trifluoromethanesulphonyl)imide99% Methanesulfonamide,1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-,lithiumsalt N-LITHIOTRIFLUOROMETHANESULFONIMIDE bis(Trifluoromethanesulphonyl)imide, lithium salt lithiumbis(trifluoromethylsulfonyl)imide 双(三氟甲基磺酰)胺 锂盐 双(三氟甲烷)磺酰亚胺 锂盐
PubChem Substance ID24878293
EC Number415-300-0
Beilstein Registry Number6625414
Reaxys-RN6625414
Chemical Name Translation双三氟甲烷磺酰亚胺锂
LabNetwork Molecule IDLN00120347
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分类

  • {SNA} Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Inorganic Salts, Lithium, Synthetic Reagents
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonimides/Sulfinimides, Sulfur Compounds
  • {SNA} Chemical Synthesis, Inorganic Salts, Lithium,

产品应用

  • An electrolyte

相关文献及参考

  • 1. M. Liu et al. J. Electrochem. Soc. 138 , 1891, (1991)
  • 2. A. Webber J. Electrochem. Soc. 138 , 2586, (1991)
  • 3. M.M. Doeff et al. J. Appl. Electrochem. 22 , 307, (1992)
  • FT-IR 2 (3), 4500:D

安全信息

Warnings MOISTURE SENSITIVE, TOXIC, CORROSIVE
GHS Symbol
WGK Germany3
Hazard statements
  • H301+H311
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes 8 T T,C
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2923
Safety Statements
  • S1/2 None 上锁保管并避免儿童触及；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R34 Causes burns 会导致灼伤
  • R48/22
  • R52/53
Storage condition Moisture Sensitive 对湿度敏感， 充氩保存
Packing GroupII
Hazard Class8/6.1

其他信息

  • Sigma Aldrich:90076-65-6(sigmaaldrich)
  • Bistrifluoromethanesulfonimidate is used in the preparation of electrolyte suitable for lithium batteries showing very high conductivity.

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organolithium 有机锂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Salts - Synthetic Reagents
  4. Lithium - Inorganic Salts
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonimides/Sulfinimides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonimides/Sulfinimides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfonic/Sulfinic Acids 磺酸/亚磺酸
  1. Analytical & Chromatography 分析化学与色谱
  2. Inorganic Salts
  3. Cesium

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