Amaranth 苋菜红
CAS 915-67-3 MFCD00004076
化学结构图
SMILES: O=S(=O)([O-])c1ccc2c(/N=N/c3ccc(S(=O)(=O)[O-])c4ccccc34)c(O)c(S(=O)(=O)[O-])cc2c1.[Na+].[Na+].[Na+]
化学属性
| Mol. Formula | C20H11N2Na3O10S3 |
|---|---|
| Mol. Weight | 604 |
| Melting Point | 218-220°C |
| Density | 1.5 |
| Solubility | 50 G/L (20 ºC) |
| Stability | 对光敏感 |
别名和识别编码
| Chemical Name | Amaranth |
|---|---|
| Synonym | 1-(4-磺酸-1-萘偶氮)-2-羟基-3,6-萘二磺酸三钠盐 ACID AMARANTH ACID RED 27 AZO RUBIN AZO RUBINE S Acid Red 27 Acilan Red SE Aizen Amaranth Amaranth S Specially Pure Bordeaux S Bordeaux S Extra Pure A C.I. Acid Red 27 C.I.酸性红27 CI 16185 Calcocid Amaranth Cerven potravinarska 9 C红2号 Dye FDC Red 2 EEC No. 123 FD & C Red Dye No. 2 FD AND C RED DYE NO 2 FD and C Red No FD&C; Red No. 2 FOOD RED NO 2 H HIDACID AMARANTH Hexacol Amaranth B Extra NAPHTHYLAMINE RED 萘酚 酸性红27 食用苋菜红 鸡冠花红 |
| Beilstein Registry Number | 4122311 |
| MDL Number | MFCD00004076 |
| CAS Number | 915-67-3 |
| EC Number | 213-022-2 |
| Reaxys-RN | 4122311 |
| PubChem Substance ID | 13506 |
| Merck Number | 375 |
| Chemical Name Translation | 苋菜红 |
| Wiswesser Line Notation | L66J BSWQ ENUN- BL66J CQ DSWQ HSWQ &-NA- 3 |
| LabNetwork Molecule ID | LN01739920 |
| InChI | InChI=1S/C20H14N2O10S3.3Na/c23-20-18(35(30,31)32)10-11-9-12(33(24,25)26)5-6-13(11)19(20)22-21-16-7-8-17(34(27,28)29)15-4-2-1-3-14(15)16;;;/h1-10,23H,(H,24,25,26)(H,27,28,29)(H,30,31,32);;;/q;3*+1/p-3 |
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信息真实价格透明
资金保障
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现货库存
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分类
- {SNA} A, AM to AQ, All Alphabetically Sorted, All alphabetical sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Colors, E numbers (Food Additives), E100–E199 (color additives), E123,
产品应用
- 生物染色剂。
相关文献及参考
- Merck: 14,375
安全信息
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1200 gm/kg/78W-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Blood - lymphoma, including Hodgkin's disease REFERENCE : GASTAB Gastroenterology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1943- Volume(issue)/page/year: 23,1,1953
TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1643 gm/kg/78W-C TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Gastrointestinal - tumors REFERENCE : NEZAAQ Nippon Eiseigaku Zasshi. Japanese Journal of Hygiene. (Nippon Eisei Gakkai, c/o Kyoto Daigaku Igakubu, Konoe-cho, Yoshida, Sakyo-ku, Kyoto 606, Japan) V.1- 1946- Volume(issue)/page/year: 37,714,1982
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 680 gm/kg/14W-I TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Gastrointestinal - tumors Blood - lymphoma, including Hodgkin's disease REFERENCE : VPITAR Voprosy Pitaniya. Problems of Nutrition. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1932-41; V.11- 1952- Volume(issue)/page/year: 29,61,1970
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1 gm/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) REFERENCE : FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 14,163,1976
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : SCPHA4 Scientia Pharmaceutica. (Oesterreichische Apotheker-Verlagsgesellschaft MBH, Spitalgasse 31, 1094 Vienna 9, Austria) V.1- 1930- Volume(issue)/page/year: 47,39,1979
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : SCPHA4 Scientia Pharmaceutica. (Oesterreichische Apotheker-Verlagsgesellschaft MBH, Spitalgasse 31, 1094 Vienna 9, Austria) V.1- 1930- Volume(issue)/page/year: 47,39,1979
TYPE OF TEST : Gene conversion and mitotic recombination TEST SYSTEM : Yeast - Saccharomyces cerevisiae DOSE/DURATION : 20 mg/L REFERENCE : ENVIDV Environment International. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1978- Volume(issue)/page/year: 9,145,1983
TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Rodent - hamster Fibroblast DOSE/DURATION : 1 gm/L/48H REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 48,337,1977
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 20 ug/L REFERENCE : ENVIDV Environment International. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1978- Volume(issue)/page/year: 9,145,1983
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 20 ug/L REFERENCE : ENVIDV Environment International. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1978- Volume(issue)/page/year: 9,145,1983
TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Rodent - hamster Lung DOSE/DURATION : 2 gm/L REFERENCE : GMCRDC Gann Monograph on Cancer Research. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No. 11- 1971- Volume(issue)/page/year: 27,95,1981
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 296 mg/kg SEX/DURATION : multigenerations TOXIC EFFECTS : Reproductive - Effects on Newborn - viability index (e.g., # alive at day 4 per # born alive) Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight gain) REFERENCE : TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year
{hTYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE : 250 mg/kg SEX/DURATION : male 1 day(s) pre-mating TOXIC EFFECTS : Reproductive - Fertility - male fertility index (e.g. # males impregnating females per # males exposed to fertile nonpregnant females) Reproductive - Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea) REFERENCE : FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 14,163,1976
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 33 m
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - hamster DOSE : 100 mg/kg SEX/DURATION : female 8 day(s) after conception TOXIC EFFECTS : Reproductive - Specific Developmental Abnormalities - musculoskeletal system REFERENCE : BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way
其他信息
- 稳定性:Stable. Incompatible with strong oxidizing agents.
- 图谱信息:酸性红 27(915-67-3)红外图谱(IR2) 酸性红 27(915-67-3)红外图谱(IR1) 酸性红 27(915-67-3)核磁图( 1 HNMR)
- 毒害物质数据:915-67-3(Hazardous Substances Data)
- 含量分析:按OT-15中方法二测定。称取试样约3g(准确至0.0002g)溶于新煮沸并已冷却到室温的水中，移人500ml容量瓶中，稀释至刻度，摇匀。吸取50ml试样液置于250ml锥形瓶中，加入柠檬酸三钠15g，水150ml，在液面下通入二氧化碳气流的同时加热至沸，并用0.1mol/L三氯化钛标准液滴定至无色为终点。 同时以50ml水代替试样液，以相同方法做一空白试验。
- MOL 文件:915-67-3.mol
- 所属类别一:食品添加剂: 着色剂
- RTECS号:QJ6550000
- 所属类别二:食品添加剂: 食用色素与护色剂: 食用色素(着色剂)
- 毒性:ADI 0～0.5mg/kg(FAO/WHO，2001)。LD 50 >10g/kg(小鼠，经口)。HACSG(欧共体儿童保护集团)不准用于儿童。挪威、美国、不准使用。
- 酸性红 27价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 71003043 苋菜红;鸡冠花红;蓝光酸性红;对磺基萘偶氮-R-盐 10g 23.1元 2011/08/23 71003060 苋菜红;鸡冠花红;蓝光酸性红;对磺基萘偶氮-R-盐 10g 26.5元 2011/08/23 71003080 苋菜红;鸡冠花红;蓝光酸性红;对磺基萘偶氮-R-盐 10g 48元
- 使用限量:GB 2。760-2002(g/kg)：果汁(味)饮料类、碳酸饮料、配制酒、糖果、糕点上彩装、青梅、山楂制品，渍制小菜、威化饼干夹心、果冻、糖果包衣，均0.05；红绿丝、染色樱桃罐头(装饰用)，0.10；冰棍、冰激凌、雪糕，0.025。
- EPA化学物质信息:2,7-Naphthalenedisulfonic acid, 3-hydroxy-4-[(4-sulfo-1-naphthalenyl) azo]-, trisodium salt(915-67-3)
- 易溶于水，水中溶解度:50 G/L (20°C)，呈带蓝光的红色溶液，可溶于甘油和丙二醇，微溶于乙醇，不溶于大多数有机溶剂。本品遇铜﹑铁易褪色，易被细菌分解，耐氧化﹑还原性差。
- 生产方法:由对氨基萘磺酸重氮化后与R酸(2-萘酚-3，6-二磺酸)偶合，经盐析、精制而得。
- 用途:作食品着色剂，我国规定可用于红绿丝、染色樱桃罐头(系装饰用)中，最大使用量为0.10g/kg；在各种饮料类、配制酒、糖果、糕点上彩装、青梅、山楂制品和浸渍小菜中，最大使用量0.05g/kg。
- 色指数:16185
- 参考质量标准:GB 4479.1-1999 苋菜红60 苋菜红85 含量/% ≥60.0 ≥85.0 水不溶物/% ≤0.30 ≤0.30 干燥减量、氯化物(以氯化钠计)及硫酸盐(以硫酸钠计)总量/% 一 ≤15 干燥减量/% ≤10.0 一 副染料/% ≤3.0 ≤3.0 砷(As)/% ≤0.0001 ≤0.0001 重金属(以Pb计)/% ≤0.001 ≤0.001 GB 4479．2-1996(苋菜红铝色淀) 含量(以色酸计)/%@≥20.0 盐酸和氨不溶物/%@≤0.5 水溶性氯化物和硫酸盐/%@≤2.0 干燥失重(135℃，6h)/%@≤30.0 副染料/%@≤1.2 重金属(以Pb计)/%@≤0.002 砷(As)/%@≤0.0003 钡/%@≤0.05
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