4,7-Dimethoxy-1,10-Phenanthroline 4,7-二甲氧基-1,10-菲咯啉

CAS 92149-07-0 MFCD00233883

化学结构图

92149-07-0
SMILES: COC1=CC=NC2C3N=CC=C(OC)C=3C=CC1=2

化学属性

Mol. FormulaC14H12N2O2
Mol. Weight240.26
Melting Point197-212
Density1.422
Appearance white to off-white pwdr.
Stabilityair sensitive

别名和识别编码

Chemical Name4,7-Dimethoxy-1,10-Phenanthroline
CAS Number92149-07-0
Alfabeta NameDIMETHOXYPHENANTHROLINE 47110---,,
MDL NumberMFCD00233883
PubChem Substance ID24885413
EC Number250-023-7
Beilstein Registry Number2384789
Synonym 4,7-二甲氧基-1,10-菲咯啉
Chemical Name Translation4,7-二甲氧基-1,10-菲咯啉
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分类

  • {SNA} Building Blocks, C9 to C20+, Catalysis and Inorganic Chemistry, Chemical Synthesis, Organic Building Blocks, Other Ligands, Oxygen Compounds, Phenols
  • Building Blocks, C9 to C20+, Catalysis and Inorganic Chemistry, Chemical Synthesis, Organic Building Blocks, Other Ligands, Oxygen Compounds, Phenols

相关文献及参考

  • 1. Buchwald et al. Org. Lett. 8 , 2779, (2006) 摘要
  • 2. Buchwald et al. J. Org. Chem. 72 , 6190, (2007) 摘要
  • Klapars, A.; Huang, X.; Buchwald, S. L. J. Am. Chem. Soc. 124 , 7421, (2002) 摘要
  • Li, C. S.; Dixon, D. D. Tetrahedron Lett. 45 , 4257, (2004)
  • Altman, R. A.; Buchwald, S. L. Org. Lett. 9 , 643, (2007) 摘要

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word
Hazard statements
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
Hazard Codes
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number
Packing GroupIII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Other Ligands - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C9 to C20+ - Phenols
  1. Photocatalyst
  2. Nitrogen
  1. Ligands
  2. Nitrogen

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