Salicylhydrazide 水杨酰肼

CAS 936-02-7 MFCD00007599

化学结构图

936-02-7
SMILES: NNC(=O)c1ccccc1O

化学属性

Mol. FormulaC7H8N2O2
Mol. Weight152.15
Melting Point147-150°C
TSCAYes
Density1.422
Boiling Point274.61 °C at 760 mmHg

别名和识别编码

Chemical NameSalicylhydrazide
CAS Number936-02-7
Alfabeta NameHYDROXYBENZHYDRAZIDE 2-
MDL NumberMFCD00007599
Synonym 2-Hydroxybenzohydrazide {LY} 2-Hydroxybenzohydrazide {} {LY} 2-Hydroxybenzohydrazide {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {} {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {} {} {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {} {} {} {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxybenzohydrazide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY}
PubChem Substance ID87575775
EC Number213-311-3
Beilstein Registry Number10,100
Reaxys-RN472355
Chemical Name Translation水杨酰肼
InChIKeyXSXYESVZDBAKKT-UHFFFAOYSA-N
Wiswesser Line NotationZMVR BQ
LabNetwork Molecule IDLN00158588
InChIInChI=1S/C7H8N2O2/c8-9-7(11)5-3-1-2-4-6(5)10/h1-4,10H,8H2,(H,9,11)
Canonical SMILESO=C(NN)C1=CC=CC=C1O
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分类

  • {SNA} Building Blocks, Carbonyl Compounds, Chemical Synthesis, Hydrazides, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; amide; alcohol; 1fragment
  • Building Blocks, Carbonyl Compounds, Chemical Synthesis, Hydrazides, Organic Building Blocks

相关文献及参考

  • Beil. 10 ,100
  • Corp MSDS 1 (2), 3066:D / FT-IR 2 (2), 3023:B / FT-IR 1 (2), 383:B / FT-NMR 1 (2), 1414:C / IR-Spectra (3), 1086:D / IR-Spectra (2), 948:E / NMR-Reference 2 (2), 364:A / RegBook 1 (2), 2041:A / Sigma FT-IR 1 (2), 887:A / Structure Index 1 , 324:C:6
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Warnings IRRITANT
WGK Germany3
RTECSVO3700000
Hazard Codes Xi
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P305+P351+P338
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Biochemical - Enzyme inhibition, induction, or change in blood or tissue
   levels - monoamine oxidase
REFERENCE :
   JMPCAS Journal of Medicinal and Pharmaceutical Chemistry.  (Washington, DC)
   V.1-5, 1959-62.  For publisher information, see JMCMAR.
   Volume(issue)/page/year: 4,259,1961

Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • TCI Shanghai:水杨酰肼 Salicyl Hydrazide,>;98.0%(T)(936-02-7)
  • Alfa Aesar:2-羟基亚苯基肼,98+% 2-Hydroxybenzhydrazide, 98+%(936-02-7)
  • MOL 文件:936-02-7.mol
  • 图谱信息:水杨酰肼(936-02-7)质谱(MS) 水杨酰肼(936-02-7)红外图谱(IR1) 水杨酰肼(936-02-7)Raman光谱 水杨酰肼(936-02-7)红外图谱(IR2)
  • 水杨酰肼价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 S0242 水杨酰肼 Salicyl Hydrazide 25G 567元 2014/06/02 S0242 水杨酰肼 Salicyl Hydrazide 500G 4840元 2010/06/21 132611000 水杨酰肼 Salicylhydrazide 98% 100 GR 1561元
  • Acros Organics:水杨酰肼 Salicylhydrazide, 98%(936-02-7)
  • MSDS 信息:Salicylhydrazide(936-02-7).msds
  • Sigma Aldrich:936-02-7(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Hydrazides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Hydrazides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters
  6. C8 to C9