(Trimethyl)methylcyclopentadienylplatinum(IV), (MeCp)PtMe3 三甲基(甲基环戊二烯)铂(IV)

CAS 94442-22-5 MFCD00079665

化学结构图

94442-22-5
SMILES: CC1=C([Pt](C)(C)C)CC=C1

化学属性

Mol. FormulaC5H4CH3Pt(CH3)3
Mol. Weight319.30
Melting Point30-31 °C(lit.)
TSCAYes
Boiling Point23°/0.053mm subl.
Density1.88
Appearance off-white pwdr.
Stabilityair sensitive, store cold
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical Name(Trimethyl)methylcyclopentadienylplatinum(IV), (MeCp)PtMe3
Synonym (Trimethyl)methylcyclopentadienylplatinum(IV) Methylcyclopentadienyl-tridimethyl-platinum (Methylcyclopentadienyl)trimethylplatinum MeCpPtMe3 Platinum, trimethyl[(1,2,3,4,5-η)-1-methyl-2,4-cyclopentadien-1-yl]- 三甲基(甲基环戊二烯基)铂(IV)
PubChem Substance ID24883390
CAS Number94442-22-5
MDL NumberMFCD00079665
Chemical Name Translation三甲基(甲基环戊二烯)铂(IV)
InChIKeyAGQKROMSWCHOND-UHFFFAOYSA-N
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分类

  • {SNA} 78: Platinum, CVD and ALD Precursors Packaged for Deposition Systems, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Platinum, Vapor Deposition Precursors, 材料科学
  • {uni_hamburg} no charge; metal-organic; other heterocycle; carbocycle; alicycle; fused rings; 3ring; 4ring; 5ring; 6ring; 1fragment; z
  • {SNA} CVD and ALD Precursors by Metal, Materials Science, Micro/NanoElectronics, Platinum, Vapor Deposition Precursors
  • {SA} 78: Platinum, CVD and ALD Precursors Packaged for Deposition Systems, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Platinum, Vapor Deposition Precursors

相关文献及参考

  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: III/35D5 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 5: Organometallic Compounds Author: Mikhova, Bozhana Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D5 Year: 2008 Keyword: Carbon-13; chemical shift; magnetic properties of nuclei; nuclear magnetic resonance data ISBN: 978-3-540-74188-6 (print) ISBN: 978-3-540-74189-3 (electronic) Internet Resource: DOI:10.1007/978-3-540-74189-3 RefComment: VIII, 241 p., Hardcover RefComment: Written for Scientists and engineers in the fields of physics, chemistry and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum.

安全信息

Hazard Codes T+,N
WGK Germany3
GHS Symbol
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P302+P350
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P301+P310+P330
  • P302+P352+P310
  • P333+P313
Hazard statements
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H300+H310
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R27/28 Very toxic in contact with skin and if swallowed 皮肤接触及吞食都有剧毒
Restrict -

系列性分类


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