N,N-Dimethyl-p-phenylenediamine 4-氨基-N,N-二甲基苯胺

CAS 99-98-9 MFCD00007860

化学结构图

99-98-9
SMILES: CN(C)c1ccc(N)cc1

化学属性

Mol. FormulaC8H12N2
Mol. Weight136.19
Boiling Point262
Melting Point34-36
Density1.09
Flash Point130°(266°F)
TSCAYes
Solubility11 G/L (20 ºC)
Stability对光敏感;对空气敏感
Appearance crystalline

别名和识别编码

Chemical NameN,N-Dimethyl-p-phenylenediamine
Alfabeta NameDIMETHYLBENZENEDIAMINE NN1114------,,
MDL NumberMFCD00007860
CAS Number99-98-9
Synonym N,N-Dimethyl-p-phenylenediamine N,N-dimethyl-p-phenylenediamine {} {LY} N,N-Dimethyl-p-phenylenediamine {} {} {LY} N,N-Dimethyl-p-phenylenediamine {} {} {} {LY} N,N-Dimethyl-p-phenylenediamine {} {} {} {} {LY} N,N-Dimethyl-p-phenylenediamine {} {} {} {} {} {LY} N,N-Dimethyl-p-phenylenediamine {} {} {} {} {} {} {LY} N,N-Dimethyl-p-phenylenediamine {} {} {} {} {} {} {} {LY} N,N-Dimethyl-p-phenylenediamine {} {} {} {} {} {} {} {} {LY} N,N-Dimethyl-p-phenylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Dimethyl-p-phenylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Dimethyl-p-phenylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Dimethyl-p-phenylenediamine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Dimethyl-p-phenylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Dimethyl-
EC Number202-807-5
Beilstein Registry Number508105
Merck Number3254
PubChem Substance ID7472
Reaxys-RN508105
Chemical Name Translation4-氨基-N,N-二甲基苯胺
Wiswesser Line NotationZR DN1&1
LabNetwork Molecule IDLN00154110
InChIInChI=1S/C8H12N2/c1-10(2)8-5-3-7(9)4-6-8/h3-6H,9H2,1-2H3
Canonical SMILESNC1=CC=C(N(C)C)C=C1
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • {Chemicalbook} 农药中间体: 杀菌剂中间体: 芳香族苯类杀菌剂
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SA} Analytical Reagents, Analytical/Chromatography, Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy
  • {SNA} Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy, 分析/色谱, 分析试剂
  • {SNA} Analytical Reagents, Analytical/Chromatography, Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy

产品应用

  • 光谱测定SO42-, S2-、V的试剂。

相关文献及参考

  • Short: III/35D2
  • Merck: 14,3254
  • Short: III/20a
  • Short: III/35B
  • Redox indicator. Readily forms stable, red radical cation, involved in a variety of redox reactions. Compare N,N,N',N'-Tetramethyl-p-phenyl­enediamine, L00559.
  • Merck: 14,3254 Beilstein: 13,IV,106

安全信息

Warnings IRRITANT 危化品目录(2015) 危险化学品
GHS Symbol
WGK Germany3
Hazard statements
  • H300 Fatal if swallowed 吞食致命
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H331 Toxic if inhaled 吸入中毒
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RTECSST0874000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P301+P316
  • P302+P350
  • P302+P352
  • P302+P352+P312+P361+P364
  • P304+P340
  • P304+P340+P311
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupII
UN Number 2811
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes 6.1 T
Hazard Class6.1
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - coma
REFERENCE :
   JIDHAN Journal of Industrial Hygiene.  (Cambridge, MA)  V.1-17, 1919-35. For
   publisher information, see AEHLAU.  Volume(issue)/page/year: 4,386,1923

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Human
DOSE/DURATION           : 14 ug/kg
TOXIC EFFECTS :
   Blood - hemorrhage
   Skin and Appendages - primary irritation (after topical exposure)
   Skin and Appendages - dermatitis, allergic (after topical exposure)
REFERENCE :
   JIDHAN Journal of Industrial Hygiene.  (Cambridge, MA)  V.1-17, 1919-35. For
   publisher information, see AEHLAU.  Volume(issue)/page/year: 4,386,1923

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Cardiac - pulse rate increase, without fall in BP
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   JIDHAN Journal of Industrial Hygiene.  (Cambridge, MA)  V.1-17, 1919-35. For
   publisher information, see AEHLAU.  Volume(issue)/page/year: 4,386,1923

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 240 ppb
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   JID

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - hamster Liver
DOSE/DURATION           : 100 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 136,255,1984

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 10 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 241,175,1990

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 100 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 136,255,1984

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 ug/plate
REFERENCE :
   AEMIDF Applied and Environmental Microbiology.  (American Soc. for
   Microbiology, 1913 I St., NW, Washington, DC 20006)  V.31-    1976-
   Volume(issue)/page/year: 42,641,1981

其他信息

  • 下游产品:4-二甲氨基苯异氰酸酯 --> 6-溴-2,4-二甲氧基嘧啶 --> 亚甲兰 --> 敌克松
  • 用途二:N,N-甲基对苯二胺是杀菌剂敌磺钠的中间体。
  • Hazard Note:Toxic/Keep Cold
  • 方法二:以二甲苯胺为原料,经亚硝化,还原而得:工艺过程:(1)亚硝化 将稀盐酸及二甲基苯胺搅匀冷却至5℃以下,加亚硝酸钠溶液进行亚硝化,加毕,放置,过滤结晶,用1:1盐酸洗,再用盐酸与酒精的混合液再洗涤一次,抽干,得亚硝化物。(2)还原 将上述粗品有水搅拌成糊状,再加工业浓盐酸,外面用冰水冷却,慢慢加入锌粉,加入温度不宜超过45℃。(3)提取 加氢氧化钠溶液至碱性后,再用苯提取,苯溶液用无水碳酸钾干燥,用水浴回收苯,再减压蒸馏收集成品。其它制法 由甲基橙还原或由对硝基二甲基苯胺用硫化钠或硫化钾还原而制得。工业上用香兰素萃取后废液为原料,经中和、萃取、蒸馏而得。该品对皮肤有刺激性,毒性比对苯二胺大8倍。
  • 方法一:其制备方法是用N,N-二甲苯胺与亚硝酸钠和盐酸进行亚硝化,再在铁粉和盐酸存在下进行还原,得到的N,N-二甲基对苯二胺盐酸盐用碱中和得产品。 也可以从香豆素生产中的废水用氨水中和至pH=7~8,加热至约40℃,沉淀8~12h,清除沉淀渣,用苯萃取中和液,然后减压脱苯即得N,N-二甲基对苯二胺。
  • 用途一:用作医药、偶氮染料、显影剂及农药等的原料
  • 敏感性:Light Sensitive
  • 用途四:光谱测定SO42-, S2-、V的试剂。
  • MSDS 信息:4-氨基-N,N-二甲基苯胺(99-98-9).msds
  • Acros Organics:N,N-二甲基对苯二胺/对氨基二甲基苯胺 N,N-Dimethyl-p-phenylenediamine, pract., 85%(99-98-9)
  • 易溶于乙醇、水、苯和氯仿。纯品在空气中稳定,不纯时易液化。见光颜色易变深。
  • Alfa Aesar:N,N-二甲基对苯二胺,96% N,N-Dimethyl-p-phenylenediamine, 96%(99-98-9)
  • 上游原料:乙醇 --> 碳酸钾 --> 锌粉 --> N,N-二甲基苯胺 --> 间苯二胺 --> 硝化物 --> 香豆素 --> 甲基橙 --> 二甲苯胺
  • 4-氨基-N,N-二甲基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K0775001 4-氨基-N.N-二甲苯胺》97%(+4℃) 25g 543元 2011/08/23 80004680 4-氨基-N,N-二甲苯胺 25g 395元 2011/04/16 D0779 N,N-二甲基-1,4-苯二胺 N,N-Dimethyl-1,4-phenylenediamine 25G 342元
  • 图谱信息:4-氨基-N,N-二甲基苯胺(99-98-9)红外图谱(IR1) 4-氨基-N,N-二甲基苯胺(99-98-9)核磁图( 1 HNMR) 4-氨基-N,N-二甲基苯胺(99-98-9)质谱(MS) 4-氨基-N,N-二甲基苯胺(99-98-9)红外图谱(IR2) 4-氨基-N,N-二甲基苯胺(99-98-9)核磁图( 13 CNMR)
  • 用途三:为测定钒的试剂。用于染料、农药和显影剂的生产。对氨基二甲苯胺和对异硫氰基苯丁醚加成可得抗麻疯病药丁氨苯硫脲。
  • F:8-10-23
  • Sigma Aldrich:99-98-9(sigmaaldrich)
  • 外观性质:灰色至黑色固体。
  • TCI Shanghai:N,N-二甲基-1,4-苯二胺 N,N-Dimethyl-1,4-phenylenediamine,>;98.0%(GC)(T)(99-98-9)
  • 存储注意事项:空气敏感;光敏感
  • color:black
  • MOL 文件:99-98-9.mol

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