Cobalt(II) acetylacetonate 乙酰丙酮钴(II)

CAS 14024-48-7 MFCD00000014

化学结构图

14024-48-7
SMILES:

化学属性

Mol. FormulaC10H14CoO4·2H2O
Mol. Weight257.15(as Anhydrous)
Melting Point165-170 °C(lit.)
TSCAYes
Stability易吸潮

别名和识别编码

Chemical NameCobalt(II) acetylacetonate
CAS Number14024-48-7
Beilstein Registry Number1,783
PubChem Substance ID87565505
MDL NumberMFCD00000014
Synonym 2,4-戊二酮 钴(II) 衍生物 Co(acac)2 乙酰丙酮合钴 乙酰丙酮钴 乙酰丙酮钴 乙酰丙酮钴(II) 乙酰丙酮钴(II) Co(acac)2 乙酰丙酮合钴 2,4-戊二酮 钴(II) 衍生物 Bis(acetylacetonato)cobalt(II) hydrate
EC Number237-855-6
Chemical Name Translation乙酰丙酮钴(II)
Reaxys-RN4157956
InChIKeyBKFAZDGHFACXKY-UHFFFAOYSA-N
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分类

  • {SNA} Cobalt, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Cobalt
  • Cobalt, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • {SNA} Cobalt, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学

产品应用

  • 有机反应催化剂。添加剂。油漆的催干剂。

相关文献及参考

  • Catalyst which mediates the coupling of vinylic halides with organomagnesium reagents, or with organozinc reagents with retention of alkene stereochemistry: Tetrahedron Lett., 39, 6159, 6163 (1998), respectively.
  • Beilstein:1,783
  • Used catalytically with NaBH4, promotes the Pauson-Khand type reaction of an akyne, an alkene and CO: Tetrahedron Lett., 37, 3145 (1996):

安全信息

Signal word Danger
Hazard statements
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H350 May cause cancer 可能致癌
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H302+H312+H332
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P308+P313
  • P332+P313
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P304+P340+P312
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P337+P313
  • P405 Store locked up. 上锁保管。
  • P302+P352+P312+P362+P364
WGK Germany3
GHS Symbol
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S37 Wear suitable gloves 戴适当手套;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Storage condition 密封保存 密封保存;充氩保存 Hygroscopic

其他信息

  • 难溶于冷的四氯化碳和苯、微溶于水、氯仿,溶于甲醇、乙醇。

系列性分类


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