Chromium(III) acetylacetonate 乙酰丙酮铬

CAS 21679-31-2 MFCD00000015

化学结构图

21679-31-2
SMILES: CC(=O)[CH-]C(C)=O.CC(=O)[CH-]C(C)=O.CC(=O)[CH-]C(C)=O.[Cr+3]

化学属性

Mol. FormulaC15H21CrO6
Mol. Weight349.32
Boiling Point340
Melting Point210
Density1.35
SolubilityInsoluble in water. Soluble in toluene, acetic acid
TSCAYes
Appearance maroon xtl.

别名和识别编码

Chemical NameChromium(III) acetylacetonate
Synonym (OC-6-11)-tris(2,4-pentanedionato-O,o')-chromium 2,4-戊二酮铬 Chrom(III)-acetylacetonat Chromium acetylacetonate Chromium triacetylacetonate Chromium tris(acetylacetonate) Chromium(3+) acetylacetonate Chromium(III) 2,4-pentanedionate Chromium(III) acetylacetonate Chromium, tris(2,4-pentanedionato-O,O')-, (OC-6-11)- Chromium, tris(2,4-pentanedionato-κO,κO')-, (OC-6-11)- Tris(2,4-pentanedionato)chromium Tris(2,4-pentanedionato)chromium(III) Tris(acetylacetonato)chromium(III) Tris-(2,4-pentandionato)-chrom chromium tris(4-oxopent-2-en-2-olate) chromium(III) 4-oxopent-2-ene-2-olate chromium, tris(2,4-pentanedionato-O,o')-, (OC-6-11)-
CAS Number21679-31-2
PubChem Substance ID87565477
EC Number244-526-0
Beilstein Registry Number4148971
MDL NumberMFCD00000015
Chemical Name Translation乙酰丙酮铬
InChIKeyGMJCSPGGZSWVKI-UHFFFAOYSA-N
Wiswesser Line Notation1V1V1 3 &.CR
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分类

  • Chromium, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • {SNA} Chromium, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • {SNA} Chromium, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
  • {uni_hamburg} no charge; ketone; 4fragments; ionic

相关文献及参考

  • Lipatov, Y.S. J. Polym. Mater. 14 , 263, (1997)
  • Beil. 1 ,IV,3673
  • Aldrich MSDS 1 , 469:D / Corp MSDS 1 (1), 879:B / FT-IR 2 (3), 4526:A / FT-IR 1 (2), 1277:D / IR-Spectra (2), 296:E / RegBook 1 (2), 3087:A / Sax 6 , 2696 / Structure Index 1 , 489:E:4
  • Short: III/5b Title: Structure Data of Organic Crystals: C 14 ... C 120 Author: Schudt, E.; Weitz, G. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/5b Year: 1971 ISBN: 3-540-05177-5 ISBN: 978-3-540-05177-0 Internet Resource: DOI:10.1007/b19970 RefComment: XXI, 736 pages, and VII, 890 pages. Hardcover Abstract: Volume III/5 offers a compitation as complete as possible of the space groups and lattice con-stants of all crystals which have been studied by means of X-rays, neutron and electron diffraction.
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Catalyzes the oxidative cleavage of methacrylic to pyruvic esters by hydrogen peroxide: Chem. Lett., 99 (1989).

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H303 May be harmfully swallowed 吞食可能有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
RTECSGB7575000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word Warning
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 6350 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3360 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Chromium Catalysis 铬催化剂
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Chromium - Solution Deposition Precursors
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. CVD & ALD Precursors
  2. Chromium
  1. Metal Beta-diketonates
  2. Chromium

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