Vanadium, oxobis(2,4-pentanedionato-O,O')-, (SP-5-21)- 乙酰丙酮氧钒
CAS 3153-26-2 MFCD00000032
化学结构图
SMILES: CC(=O)C=C(C)O.CC(=O)C=C(C)O.O=[V]
化学属性
| Mol. Formula | C10H14O5V |
|---|---|
| Mol. Weight | 265.16 |
| Density | 1.0 |
| Melting Point | 240-242 |
| Solubility | Moderately soluble in acetone, ether and chloroform. Soluble in ethanol and benzene |
| TSCA | Yes |
| Boiling Point | 140 °C at 13 mmHg |
| Flash Point | 79 ºC |
| Stability | 对湿度和空气敏感 |
| Appearance | bluish green pwdr. |
别名和识别编码
| Chemical Name | Vanadium(IV) Oxide Acetylacetonate |
|---|---|
| MDL Number | MFCD00000032 |
| CAS Number | 3153-26-2 |
| EC Number | 221-590-8 |
| Beilstein Registry Number | 4138236 |
| PubChem Substance ID | 11821519 |
| Synonym | Vanadium(IV)bis(acetylacetonato)oxide {LY} Vanadium(IV)bis(acetylacetonato)oxide {} {LY} Vanadium(IV)bis(acetylacetonato)oxide {} {} {LY} Vanadium(IV)bis(acetylacetonato)oxide {} {} {} {LY} Vanadium(IV)bis(acetylacetonato)oxide {} {} {} {} {LY} Vanadium(IV)bis(acetylacetonato)oxide {} {} {} {} {} {LY} Vanadium(IV)bis(acetylacetonato)oxide {} {} {} {} {} {} {LY} Vanadium(IV)bis(acetylacetonato)oxide {} {} {} {} {} {} {} {LY} Vanadium(IV)bis(acetylacetonato)oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vanadium(IV)bis(acetylacetonato)oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vanadium(IV)bis(acetylacetonato)oxide {} {} {} {} {} {} {} {} {} {} {LY} Vanadium(IV)bis(acetylacetonato)oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vanadium(IV)bis(acetylacetonato)oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vanadium(IV)bis(acetylacetonato)oxide |
| Chemical Name Translation | 乙酰丙酮氧钒 |
| InChIKey | WVPMIMFMIGMEHW-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN03267725 |
| InChI | InChI=1S/2C5H8O2.O.V/c2*1-4(6)3-5(2)7;;/h2*3,6H,1-2H3;;/b2*4-3-;; |
| Canonical SMILES | CC(O1)=CC(C)=O[V]1=O.[2] |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Vanadium
- {uni_hamburg} no charge; ketone; 3fragments; ionic
- Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Vanadium
- {SNA} Micro/NanoElectronics, Solution Deposition Precursors, Vanadium, 材料科学
产品应用
- 有机合成中的氧化催化剂；金属表面处理。
相关文献及参考
- Readily oxidized to a vanadium(V) species which is a preferred catalyst for epoxidation of allylic alcohols with TBHP (tert-Butyl hydroperoxide, A13926): J. Am. Chem. Soc., 95, 6136 (1973); Chem. Rev., 89, 431 (1989). This system has been used for diastereoselective epoxidation in the synthesis of substituted tetrahydrofurans: Tetrahedron Lett., 35, 6453 (1994). Propargylic alcohols are oxidized to the corresponding carbonyl compounds: Tetrahedron Lett., 42, 8877 (2001).
- Short: EINECS
- Short: IV/20B
- Beilstein: 1,IV,3672
- Other functional groups which can be selectively oxidized using this system include: tert-amines to N-oxides: J. Org. Chem., 33, 588 (1968); Org. Synth. Coll, 6, 501 (1988), and sulfides to sulfoxides: J. Chem. Soc., Perkin 2, 979 (1978).
安全信息
GHS Symbol
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S22 Do not breathe dust 不要吸入粉尘；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R22 Harmful if swallowed 吞咽有害
- R25 Toxic if swallowed 吞咽有毒
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P301+P312+P330
- P301+P317
- P302+P352
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- 检测方法:HPLC,SPECTRA CHEMICAL ANALYSIS,IR
- 氧化二乙酰丙酮合钒价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 V0016 双(2,4-戊二酮酸)合氧化钒(IV) Bis(2,4-pentanedionato)vanadium(IV) Oxide 25G 519元 2010/06/21 199590500 氧化二乙酰丙酮合钒 Vanadyl(IV) acetylacetonate 99% 50 GR 649元 2010/06/21 199592500 氧化二乙酰丙酮合钒 Vanadyl(IV) acetylacetonate 99% 250 GR 1604元
- MOL 文件:3153-26-2.mol
- 几乎不溶于水，溶于甲醇(6.4 g/100 ml)、乙醇、 醚、氯仿、丙酮、二氧六环、苯(0.9 g/100 ml)和吡啶。
- TCI Shanghai:氧化二乙酰丙酮合钒 Bis(2,4-pentanedionato)vanadium(IV) Oxide,>;95.0%(T)(3153-26-2)
- EPA Substance Registry System:3153-26-2(EPA Substance)
- TSCA:Yes
- Alfa Aesar:双（乙酰丙酮）氧化钒(IV),99% Vanadium(IV) oxide bis(2,4-pentanedionate), 99%(3153-26-2)
- 上游原料:乙醇 --> 硫酸 --> 二氯甲烷 --> 碳酸钠 --> 三氯甲烷 --> 丙酮 --> 亚硫酸钠 --> 活性炭 --> 乙酰丙酮 --> 五氧化二钒 --> 1-氯丁烷 --> [1,1'-双(二苯基膦基)二茂铁]二氯化钯 --> 草酸
- 图谱信息:氧化二乙酰丙酮合钒(3153-26-2)红外图谱(IR1) 氧化二乙酰丙酮合钒(3153-26-2)质谱(MS) 氧化二乙酰丙酮合钒(3153-26-2)红外图谱(IR2)
- 存储注意事项:空气敏感
- 海关编码:29420000
- 用途一:有机合成中的氧化催化剂；金属表面处理。
- 下游产品:(R)-(+)-叔丁基亚磺酰胺 --> beta-丙内酯
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