CAS 584-13-4 MFCD00000105-4'-Bromoacetophenone 4-氨基-1,2,4-三氮唑 -LabNovo

4'-Bromoacetophenone 4-氨基-1,2,4-三氮唑

CAS 584-13-4 MFCD00000105

化学结构图

SMILES: Nn1cnnc1

化学属性

Mol. Formula	C2H4N4
Mol. Weight	84.08
Density	1.64
Flash Point	>110°(230°F)
TSCA	Yes
Boiling Point	267.6°C at 760 mmHg
Melting Point	84-86°C
Appearance	具吸湿性的针状结晶。
Solubility	methanol: 0.1 g/mL, clear

别名和识别编码

Chemical Name	4'-Bromoacetophenone
CAS Number	584-13-4
Synonym	4H-1,2,4-Triazol-4-amine {LY} 4H-1,2,4-Triazol-4-amine {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {} {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {} {} {} {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {} {} {} {} {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4H-1,2,4-Triazol-4-amine {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number	202-799-3
Beilstein Registry Number	386015
MDL Number	MFCD00003099
Merck Number	1403
PubChem Substance ID	11432
Reaxys-RN	386015
Chemical Name Translation	4-氨基-1,2,4-三氮唑
InChI	InChI=1S/C2H4N4/c3-6-1-4-5-2-6/h1-2H,3H2
Canonical SMILES	C1=NN=C[N]1N

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产品应用

有机合成中间体。用于染料、医药及试剂。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S22 Do not breathe dust 不要吸入粉尘；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S37 Wear suitable gloves 戴适当手套；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R42/43
R22 Harmful if swallowed 吞咽有害

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P302+P352+P332+P313+P362+P364
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P332+P313
P342+P311
P305+P351+P338+P337+P313
P302+P350

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
H335 May cause respiratory irritation 可能导致呼吸道刺激
H302 Harmful if swallowed 吞食有害

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Hazard Codes Xn Xn,Xi Xi

RTECSXZ3850200

Storage condition RT, protect from light {LY} RT, protect from light {} {LY} RT, protect from light {} {} {LY} RT, protect from light {} {} {} {LY} RT, protect from light {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect

其他信息

TCI Shanghai:4-氨基-1,2,4-三氮唑 4-Amino-1,2,4-triazole,>;98.0%(T)(584-13-4)
溶于乙醇、乙醚、冰醋酸、苯、二硫化碳和石油醚，不溶于水。易随水蒸气挥发。
用途二:用于有机合成。
F:8
Sigma Aldrich:584-13-4(sigmaaldrich)
Alfa Aesar:4-氨基-1,2,4-三唑,99% 4-Amino-1,2,4-triazole, 99%(584-13-4)
MOL 文件:584-13-4.mol
Acros Organics:4-氨基-4H-1,2,4-三唑 4-Amino-4H-1,2,4-triazole, 99%(584-13-4)
方法一:由甲酰肼加热制得。将甲酰肼在常压下加热3h，浴温由50℃升至200℃，再冷至100℃左右，并将糖浆状物溶于95%乙醇中，再加活性炭脱色，然后将滤液用乙醚稀释，冷却结晶，过滤。用1：2乙醇-乙醚混合溶剂洗涤并干燥得粗品，再用95%热乙醇和乙醚重结晶而得纯品。甲酰肼可由甲酸乙酯和水合肼反应得到。
Hazard Note:Irritant
图谱信息:4-氨基-1,2,4-三氮唑(584-13-4)红外图谱(IR1) 4-氨基-1,2,4-三氮唑(584-13-4)质谱(MS) 4-氨基-1,2,4-三氮唑(584-13-4)核磁图( 1 HNMR) 4-氨基-1,2,4-三氮唑(584-13-4)红外图谱(IR2) 4-氨基-1,2,4-三氮唑(584-13-4)核磁图( 13 CNMR)
4-氨基-1,2,4-三氮唑价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 A1137 4-氨基-1,2,4-三氮唑 4-Amino-1,2,4-triazole 25G 855元 2014/06/02 A1137 4-氨基-1,2,4-三氮唑 4-Amino-1,2,4-triazole 250G 4280元 2010/06/21 104701000 4-氨基-1,2,4-三氮唑 4-Amino-4H-1,2,4-triazole 99% 100 GR 1908元
上游原料:乙醇 --> 糖浆 --> 甲酰肼
下游产品:4-(4-溴苯氧基)吡啶-3-醛
用途一:用于制造农药、医药的中间体及有机合成