Oxalyl Bromide 草酰溴

CAS 15219-34-8 MFCD00000113

化学结构图

15219-34-8
SMILES: O=C(Br)C(=O)Br

化学属性

Mol. FormulaBrCOCOBr
Mol. Weight215.83
Refractive indexn20/D 1.522(lit.)
Boiling Point16-17 °C/10 mmHg(lit.)
Melting Point-19 °C(lit.)
Density1.517 g/mL at 25 °C

别名和识别编码

Chemical NameOxalyl Bromide
Synonym {uni_hamburg} Oxalyl dibromide oxalyl bromide Ethanedioyl dibromide Ethanedioyl dibromide NSC 96957 NSC 96957 Oxalsäuredibromid Ethanedioyl dibromide solution NSC 96957 草酰溴 草酰溴 溶液 Ethanedioyl bromide Oxalylbromid Ethanedioyl dibromide solution
PubChem Substance ID24859231
EC Number239-271-7
Beilstein Registry Number1744437
MDL NumberMFCD00000113
CAS Number15219-34-8
Chemical Name Translation草酰溴
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分类

  • {SNA} Chemical Synthesis, Others, Oxidizing Agents, Synthetic Reagents
  • {SNA} Chemical Synthesis, Other Oxidizing Agents, Oxidizing Agents, Synthetic Reagents
  • {uni_hamburg} no charge; carbonyl bromide; 1fragment

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H332 Harmful if inhaled 吸入有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Hazard Codes C
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R20 Harmful by inhalation 吸入有害
  • R14 Reacts violently with water 遇水会猛烈反应
  • R37 Irritating to respiratory system 刺激呼吸道
  • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R34 Causes burns 会导致灼伤

系列性分类


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