CAS 20769-85-1 MFCD00000122-2-Bromo-2-methylpropionyl Bromide 2-溴-2-甲基丙酰溴 -LabNovo

2-Bromo-2-methylpropionyl Bromide 2-溴-2-甲基丙酰溴

CAS 20769-85-1 MFCD00000122

化学结构图

SMILES: CC(C)(Br)C(=O)Br

化学属性

Mol. Formula	C4H6Br2O
Mol. Weight	229.90
Refractive index	1.5070 to 1.5120
Boiling Point	162-164 °C at 760 mmHg
Density	1.86
Flash Point	>110°(230°F)
TSCA	Yes
Solubility	起反应
Appearance	带红色液体。沸点162-164℃，相对密度1.860，折光率1.5080。溶于卤代烃，遇水、醇分解。
Stability	对湿度敏感，对光线敏感

别名和识别编码

Chemical Name	2-Bromo-2-methylpropionyl Bromide
Synonym	2-Bromoisobutyryl bromide {LY} 2-Bromoisobutyryl bromide {} {LY} 2-Bromoisobutyryl bromide {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {} {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {} {} {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {} {} {} {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoisobutyryl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo
PubChem Substance ID	88685
EC Number	244-017-3
Beilstein Registry Number	1746128
MDL Number	MFCD00000122
CAS Number	20769-85-1
Reaxys-RN	1746128
Chemical Name Translation	2-溴-2-甲基丙酰溴
LabNetwork Molecule ID	LN00227303
InChI	InChI=1S/C4H6Br2O/c1-4(2,6)3(5)7/h1-2H3
Canonical SMILES	CC(C)(Br)C(Br)=O

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产品应用

α-Bromoisobutyryl bromide has been used:
as atom transfer radical polymerization (ATRP) initiator for functionalization of hydroxyl groups present on the surface of graphene oxide
to form an N-protected halodienamide which provided four- and five-membered lactams in the presence of copper (I) and a tertiary amine
in preparation of polycaprolactone macroinitiator via reaction with oligomeric caprolactone diol and mesoporous silica nanoparticles with ATRP initiator anchored on the exterior surface

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H290 May be corrosive to metals 可能腐蚀金属。
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H302 Harmful if swallowed 吞食有害

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Precautionary statements

P234 Keep only in original container. 只保留在原来的容器中。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331
P301+P330+P331+P310
P303+P361+P353
P303+P361+P353+P310+P363
P304+P340
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
P405 Store locked up. 上锁保管。
P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Packing GroupII

UN Number 3265 UN3265

Risk Statements

R14 Reacts violently with water 遇水会猛烈反应
R22 Harmful if swallowed 吞咽有害
R34 Causes burns 会导致灼伤
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Storage condition -20°C {LY} -20°C Moisture Sensitive {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Codes 8 C

Hazard Class8

其他信息

溶于卤代烃，遇水、醇分解。
Used to form an N-protected halodienamide which provided four- and five-membered lactams in the presence of copper(I) and a tertiary amine.