3-Methylbenzyl Bromide 3-甲基苄溴

CAS 620-13-3 MFCD00000177

化学结构图

620-13-3
SMILES: Cc1cccc(CBr)c1

化学属性

Mol. FormulaC8H9Br
Mol. Weight185.06
Refractive index1.5640 to 1.5680
Boiling Point185
Density1.370
Flash Point82°C(lit.)
TSCAYes
Solubility难溶

别名和识别编码

Chemical Name3-Methylbenzyl Bromide
Synonym 1-(BROMOMETHYL)-3-METHYLBENZENE 1-bromomethyl-3-methyl-benzene 3-(Bromomethyl)toluene {} {} {Chemicalbook} m-Xylene, alpha-bromo- {} {} {} {Chemicalbook} alpha-bromo-m-xylen {} {} {} {} {Chemicalbook} alpha-Dibromo-m-xylene {} {} {} {} {} {} {} {} {} {} {Chemblink} alpha-Bromo-m-xylene; m-Xylyl bromide {} {} {} {} {} {} {ALFA} alpha-Bromo-m-xylene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} M-METHYLBENZYL BROMIDE {} {} {} {} {} {} {} {} {uni_hamburg} Benzene, 1-(bromomethyl)-3-methyl- {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {Chemicalbook} ALPHA-溴间甲二苯 {} {} {} {} {} {} {} {} {} {} {Chemicalbook} ALPHA-BROMO-M-XYLENE {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} A-Brom-m-xylol {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} meta-Xylylbromide {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} m-Xylene
CAS Number620-13-3
PubChem Substance ID87563962
EC Number210-625-2
MDL NumberMFCD00000177
Beilstein Registry Number2076425
Reaxys-RN2076425
Merck Number10090
Alfabeta NameBROMOMETHYLMETHYLBENZENE 13()---
Chemical Name Translation3-甲基苄溴
LabNetwork Molecule IDLN00174260
InChIInChI=1S/C8H9Br/c1-7-3-2-4-8(5-7)6-9/h2-5H,6H2,1H3
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分类

  • {SNA} Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Aldrich MSDS 1 , 296:A / Corp MSDS 1 (1), 591:A / FT-IR 1 (1), 985:D / FT-IR 2 (2), 1698:A / FT-NMR 1 (2), 83:B / IR-Spectra (3), 594:F / IR-Spectra (2), 530:A / NMR-Reference 2 (1), 788:C / RegBook 1 (1), 1175:G / Sigma FT-IR 1 (2), 348:C / Structure Index 1 , 180:C:6 / Vapor Phase 3 , 903:B
  • Beil. 5 ,374
  • Merck 14 ,10090
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 6.1 C
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S4 Keep away from living quarters 远离生活区;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭,置于通风良好的场所;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Risk Statements
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
RTECSCY9039200
UN Number 1701
Packing GroupII
Warnings IRRITANT
Hazard Class6.1
Storage condition +4°C 4℃

其他信息

  • 3-甲基苄溴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1010 α-溴间二甲苯 alpha-Bromo-m-xylene 500G 6560元 2014/06/02 B1010 α-溴间二甲苯 alpha-Bromo-m-xylene 25G 728元 2014/06/02 B3585 α-溴-间二甲苯 alpha-Bromo-m-xylene 25G 1950元
  • MOL 文件:620-13-3.mol
  • 下游产品:
  • Hazard Note:Corrosive
  • 图谱信息:3-甲基苄溴(620-13-3)质谱(MS) 3-甲基苄溴(620-13-3)核磁图( 1 HNMR) 3-甲基苄溴(620-13-3)红外图谱(IR1) 3-甲基苄溴(620-13-3)核磁图( 13 CNMR)
  • Sigma Aldrich:620-13-3(sigmaaldrich)
  • Acros Organics:alpha-溴间甲二苯 alpha-Bromo-m-xylene, 96%(620-13-3)
  • 检测方法:GC,NMR
  • Alfa Aesar:3-甲基苄溴,97% 3-Methylbenzyl bromide, 97%(620-13-3)
  • MSDS 信息:m-Xylyl bromide(620-13-3).msds
  • TCI Shanghai:α-溴间二甲苯 alpha-Bromo-m-xylene,>;80.0%(GC)(620-13-3)

系列性分类