Vinyl Bromide 乙烯基溴

CAS 593-60-2 MFCD00000183

化学结构图

593-60-2
SMILES: C=CBr

化学属性

Mol. FormulaC2H3Br
Mol. Weight106.95
Density0.927
Vapor Pressure12.46 psi ( 55 °C)
Refractive indexn20/D 1.410
Autoignition Point986 °F
Vapor Density3.8 (15 °C, vs air)
Boiling Point16°C
Melting Point-139°C
Flash Point5 ºC
Solubility不溶于水,溶于乙醇。

别名和识别编码

Chemical NameVinyl Bromide
Synonym 1-Bromoethylene BROMOETHYLENE Bromethen Bromethylen Bromoethene Bromoethylene Bromure de vinyle Bromäthylen C2H3Br Ethene, bromo- Ethylene, bromo- Ethylene,bromo- NCI-C50373 R 1140B1 SAYTEX VBR SAYTEX(R) VBR FLAME RETARDANT VINYL BROMIDE Vinile (bromuro di) Vinyl bromide Vinylbromid Vinyle (bromure de) bromethylene bromo-ethen bromo-ethene bromo-ethylen bromoethene bromuredevinyle bromuredevinyle(french) ethene, bromo- ethene,bromo- monobromoethylene vinyl bromide 乙烯基溴 乙烯基溴 溶液 {Chemicalbook
CAS Number593-60-2
EC Number209-800-6
Beilstein Registry Number1361370
MDL NumberMFCD00000183
PubChem Substance ID253661892
Chemical Name Translation乙烯基溴
Wiswesser Line NotationE1U1
LabNetwork Molecule IDLN00163595
Reaxys-RN1361370
InChIInChI=1S/C2H3Br/c1-2-3/h2H,1H2
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分类

  • {SNA} Chemical Synthesis, Materials Science, Monomers, Polymer Science, Specialty Gases, Synthetic Reagents, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Materials Science, Monomers, Polymer Science, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers
  • {SNA} Monomers, Polymer Science, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers, 材料科学

产品应用

  • 作为合成树脂的中间体

相关文献及参考

  • Short: II/19c
  • Short: II/19b
  • Short: II/14a
  • Beilstein: 1,IV,718

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R45 May cause cancer 可能致癌
  • R12 Extremely flammable 极端易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P312+P330
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P304+P340+P312
  • P305+P351+
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P311
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P330 Rinse mouth. 漱口
  • P337+P313
  • P370+P378
  • P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. 漏气着火:切勿灭火,除非漏气能够被安全地制止。
  • P381 Eliminate all ignition sources if safe to do so. 如果安全的话,消除所有点火源。
  • P403 Store in a well-ventilated place. 储存在通风良好的地方。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P410+P403
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H220 Extremely flammable gas 极易燃气体。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H280 Contains gas under pressure; may explode if heated 内含高压气体,遇热可能爆炸。
  • H302 Harmful if swallowed 吞食有害
  • H350 May cause cancer 可能致癌
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECSKU8400000
Hazard Codes T F+,T
UN Number 1993
Packing GroupII
Hazard Class3
Storage condition 0-10°C 2-8°C 密封2-8°C保存
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : TC - Toxic concentration (other than lowest)
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 52 ppm/6H/2Y-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Vascular - tumors
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   64,367,1982

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10 ppm/6H/2Y-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Vascular - tumors
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   64,367,1982

TYPE OF TEST            : TC - Toxic concentration (other than lowest)
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10 ppm
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   CHWKA9 Chemical Week.  (McGraw-Hill, Inc., 1221 Ave. of the Americas, New
   York, NY 10020) V.68-    1951-  Volume(issue)/page/year: 123(24),25,1978

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50000 ppm/7H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
   Indices," 5th ed., Cincinnati, OH, American Conference of Governmental
   Industrial Hygienists, Inc., 1986  Volume(issue)/page/year: 6,1690,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DOWCC* Dow Chemical Company Reports.  (Dow Chemical USA, Health and
   Environment Research, Toxicology Research Lab., Midland, MI 48640)
   Volume(issue)/page/year: -,12,1966

TYPE OF TEST            : Morphological transformation
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 2000 ppm/14W (Intermittent)
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   47,71,1981

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2 pph/16H
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   41,249,1979

其他信息

  • 下游产品:三丁基乙烯基锡 --> 乙烯基溴化镁 --> 孟鲁司特 --> 17-乙炔基-17-羟基-18-甲基雌甾-5(10),9(11)-二烯-3-酮-3-乙二醇缩酮 --> 13-乙基-3Β-甲氧基甾烷-2,5(10)-二烯-17-酮-17-环亚乙基缩酮 --> 盐酸金刚乙胺 --> 13-乙基-3-甲氧基甾烷-1,3,5(10)-三烯-17-酮-17-环亚乙基缩酮 --> 17Α-乙炔基-3Β,17Β-二羟基-18-甲基雌甾-2,5(10)-二烯-3-甲醚 --> 17Α-乙炔基-18-甲基-雌甾-5(10),9(11)-二烯-17Β-醇-3-酮 --> 13-乙基-17Β-羟基-18,19-二去甲孕甾-5(10)-烯-20-炔-3-酮 17Α-乙炔基-17Β-羟基-18-甲基雌甾-5(10)-烯-3-酮
  • 急性毒性:口服- 大鼠 LD50: 500 毫克/ 公斤; 吸入-大鼠 LCL0: 50000 PPM/ 7小时
  • Sigma Aldrich:593-60-2(sigmaaldrich)
  • F:3-10
  • 外观性质:无色液体或气体。
  • MOL 文件:593-60-2.mol
  • 灭火剂:雾状水、二氧化碳、泡沫、干粉
  • 无色液体或气体,不溶于水。
  • 爆炸物危险特性:与空气混合明火、受热可爆
  • 图谱信息:溴乙烯(593-60-2)核磁图( 1 HNMR)
  • MSDS 信息:溴乙烯(593-60-2).msds
  • 用途一:作为合成树脂的中间体
  • 毒性分级:中毒
  • TCI Shanghai:乙烯溴(置于无阀气瓶中)(含稳定剂甲氧基氢醌) Vinyl Bromide (stabilized with MEHQ) (in cylinder without valve) [To use this product charged in cylinder, a valve is required which is sold separately (Product Code:V0030)],>;99.0%(GC)(593-60-2)
  • 储运特性:库房通风低温干燥; 轻装轻卸; 与氧气、空气等助燃气体钢瓶分开存放
  • 可燃性危险特性:明火、受热可燃; 燃烧产生有毒溴化物烟雾
  • 职业标准:TWA 5 毫克/ 立方米; STEL 10 毫克/ 立方米
  • 蒸气压:1551 mm Hg ( 37.8 °C)
  • 类别:有害气体
  • 蒸气密度:3.8 (15 °C, vs air)

系列性分类


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