1-Bromopinacolone 1-溴频哪酮

CAS 5469-26-1 MFCD00000206

化学结构图

5469-26-1
SMILES: CC(C)(C)C(=O)CBr

化学属性

Mol. FormulaC6H11BrO
Mol. Weight179.05
Refractive index1.4640 to 1.4680
Boiling Point188-194 °C at 760 mmHg
Density1.331 g/mL at 25 °C(lit.)
Melting Point-10 °C
Flash Point66°C(lit.)
TSCANo
Appearance 白色或淡黄色透明液体。

别名和识别编码

Chemical Name1-Bromopinacolone
MDL NumberMFCD00000206
CAS Number5469-26-1
Synonym 1-Bromo-3,3-dimethyl-2-butanone {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {}
PubChem Substance ID21642
EC Number226-794-0
Beilstein Registry Number506485
Reaxys-RN506485
Chemical Name Translation1-溴频哪酮
InChIKeySAIRZMWXVJEBMO-UHFFFAOYSA-N
LabNetwork Molecule IDLN00182896
InChIInChI=1S/C6H11BrO/c1-6(2,3)5(8)4-7/h4H2,1-3H3
Canonical SMILESCC(C)(C)C(=O)CBr
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分类

  • {SNA} Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSEL7010000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Signal word Warning
Packing GroupII
UN Number UN2810 1224
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Hazard Codes Xi,F Xi
Hazard Class3.2
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   BDKS** "Studien uber die Pharmakologie des Pinakolins und einiger seiner
   Derivate mit besonderer Berucksichtigung der Kreislaufwirkung,
   Dissertation," Bang, L., Pharmakologischen Abteilung des Karolinischen
   Instituts, Stockholm, Sweden, 1934  Volume(issue)/page/year: -,-,1934

其他信息

  • F:8-10-21
  • Acros Organics:1-溴频哪酮 1-Bromopinacolone, 93%(5469-26-1)
  • Sigma Aldrich:5469-26-1(sigmaaldrich)
  • Hazard Note:Irritant/Flammable
  • MOL 文件:5469-26-1.mol
  • 1-溴频哪酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1490 1-溴-3,3-二甲基-2-丁酮 1-Bromo-3,3-dimethyl-2-butanone 25G 1440元 2014/06/02 B1490 1-溴-3,3-二甲基-2-丁酮 1-Bromo-3,3-dimethyl-2-butanone 5G 539元 2010/06/21 CD08380EB 1-溴频哪酮 1-bromo-3,3-dimethylbutan-2-one 25 GR 1035元
  • MSDS 信息:Bromomethyl tert-butyl ketone(5469-26-1).msds
  • Alfa Aesar:1-溴频哪酮,97% 1-Bromopinacolone, 97+%(5469-26-1)
  • TCI Shanghai:1-溴-3,3-二甲基-2-丁酮 1-Bromo-3,3-dimethyl-2-butanone,>;95.0%(GC)(5469-26-1)
  • 上游原料:甲醇 --> 乙醚 --> 二氯甲烷 --> 频哪酮 --> 四丁基三溴化铵

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C3 to C6 - Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C15 to C38