Geranyl Bromide 溴化香叶酯

CAS 6138-90-5 MFCD00000243

化学结构图

6138-90-5
SMILES: CC(C)=CCC/C(C)=C/CBr

化学属性

Mol. FormulaC10H17Br
Mol. Weight217
Refractive indexn20/D 1.504(lit.)
Boiling Point101-102 °C/12 mmHg(lit.)
Density1.094 g/mL at 25 °C(lit.)
Flash Point95°(203°F)
TSCAYes

别名和识别编码

Chemical NameGeranyl Bromide
CAS Number6138-90-5
MDL NumberMFCD00000243
Synonym 3,7-Dimethyl-2,6-octadienyl bromide (E)-3,7-Dimethyl-2,6-octadienyl bromide (E)-1-bromo-3,7-dimethylocta-2,6-diene (2E)-1-Bromo-3,7-dimethyl-2,6-octadiene [(2E)-3,7-Dimethyl-2,6-octadienyl] bromide (6E)-2,6-Dimethyl-8-bromo-2,6-octadiene 7-dimethyl-6-octadien(e)-1-bromo-3 Geranylbromide,97% 1-BROMO-3,7-DIMETHYL-2,6-OCTADIENE (2E)-1-Bromo-3,7-dimethyl-2,6-octadienine 溴化香叶酯 香叶基溴 反式-1-溴-3,7-二甲基-2,6-辛二烯 TRANS-1-BROMO-3,7-DIMETHYL-2,6-OCTADIENE GERANYL BROMIDE
PubChem Substance ID5365867
EC Number228-123-7
Beilstein Registry Number1703631
Chemical Name Translation溴化香叶酯
LabNetwork Molecule IDLN00201760
InChIKeyJSCUZAYKVZXKQE-JXMROGBWSA-N
InChIInChI=1S/C10H17Br/c1-9(2)5-4-6-10(3)7-8-11/h5,7H,4,6,8H2,1-3H3/b10-7+
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分类

  • {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • Terpene building block.
  • The Horner reaction with Methyl­diphenyl­phosphine oxide, A11484, provides a convenient access to the natural product (3Z,6E)-ɑ-farnesene, greatly superior to earlier multistep approaches: J. Org. Chem., 60, 6211 (1995):

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Risk Statements
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Hazard Codes Xi
Packing GroupIII
Hazard Class6.1(b)
Storage condition Light Sensitive 2-8°C
UN Number 2810

其他信息

  • MOL 文件:6138-90-5.mol
  • F:8-10-19
  • 香叶基溴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 A14093 溴化香叶酯, 96% Geranyl bromide, 96% 5g 557元 2010/05/25 A14093 溴化香叶酯, 96% Geranyl bromide, 96% 25g 1568元 2010/05/25 A14093 溴化香叶酯, 96% Geranyl bromide, 96% 100g 5306元
  • Sigma Aldrich:6138-90-5(sigmaaldrich)
  • Alfa Aesar:溴化香叶酯,96% Geranyl bromide, 96%(6138-90-5)

系列性分类


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