1,5-Dibromopentane 1,5-二溴戊烷

CAS 111-24-0 MFCD00000268

化学结构图

111-24-0
SMILES: BrCCCCCBr

化学属性

Mol. FormulaC5H10Br2
Mol. Weight229.94
Density1.688
Refractive index1.5110 to 1.5130
Flash Point79°C
TSCAYes
Boiling Point110°C at 760 mmHg
Melting Point-34°C
Vapor Density8 (vs air)
Solubility不溶于水，溶于苯和氯仿。
Stability对光敏感

别名和识别编码

Chemical Name1,5-Dibromopentane
MDL NumberMFCD00000268
CAS Number111-24-0
EC Number203-849-7
Beilstein Registry Number1209245
Synonym 1,5-Dibromopentane {LY} 1,5-Dibromopentane {} {LY} 1,5-Dibromopentane {} {} {LY} 1,5-Dibromopentane {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {} {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {} {} {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {} {} {} {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,5-Dibromopentane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID8100
Reaxys-RN1209245
Chemical Name Translation1,5-二溴戊烷
Wiswesser Line NotationE5E
LabNetwork Molecule IDLN00192880
InChIInChI=1S/C5H10Br2/c6-4-2-1-3-5-7/h1-5H2
Canonical SMILESBrCCCCCBr
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分类

  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用于有机合成。1,5 - 二 - 格氏试剂的来源。

相关文献及参考

  • Short: III/20a
  • Short: III/20b
  • Beilstein:1,131
  • Short: III/38B

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSSA0320000
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn Xi Xi,Xn
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} 
TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 10 mg/plate
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   34,2576,1974

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 umol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 141,11,1984

其他信息

  • 1,5-二溴戊烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K3426001 1.5-二溴戊烷 100ml 1308元 2011/04/16 D0198 1,5-二溴戊烷 1,5-Dibromopentane 500G 989元 2011/04/16 D0198 1,5-二溴戊烷 1,5-Dibromopentane 25G 139元
  • 上游原料:溴化物 --> 四氢吡喃
  • Acros Organics:1,5-二溴戊烷 1,5-Dibromopentane, 97%(111-24-0)
  • TCI Shanghai:1,5-二溴戊烷 1,5-Dibromopentane,>;98.0%(GC)(111-24-0)
  • MOL 文件:111-24-0.mol
  • Sigma Aldrich:111-24-0(sigmaaldrich)
  • 下游产品:西司他丁 --> 壬二酸 --> 硫化环戊烷
  • 蒸气密度:8 (vs air)
  • 方法一:由四氢吡喃开环溴化而得。在500ml烧瓶中，依次加入250g48%氢溴酸、75g浓硫酸、 21.5g重蒸过的四氢吡喃（86.5-87.5℃馏分）装上回流冷凝器，将棕色混合物加热温和地回流3h。冷至室温后，分出下层的二溴化物，用饱和碳酸钠溶液和水各洗一次。以无水氯化钙干燥。减压蒸馏，收集104-106℃（2.53kPa）馏分即为成品，产量为46-47g，产率为80-82%。
  • 用途二:用于有机合成。
  • 用途一:用作有机合成中间体
  • Alfa Aesar:1,5-二溴戊烷,98% 1,5-Dibromopentane, 98%(111-24-0)
  • 图谱信息:1,5-二溴戊烷(111-24-0)质谱(MS) 1,5-二溴戊烷(111-24-0)红外图谱(IR1) 1,5-二溴戊烷(111-24-0)Raman光谱 1,5-二溴戊烷(111-24-0)红外图谱(IR2) 1,5-二溴戊烷(111-24-0)核磁图( 13 CNMR)
  • 外观:无色或浅黄色液体，有芳香气味。
  • 检测方法:GC,NMR
  • 海关编码:29033036
  • 溶于苯和氯仿，不溶于水。有芳香气味。
  • 用途三:1,5-二溴戊烷（111-24-0）是生产2-(5-溴戊基)-1,3-二噻烷-2-羧酸乙酯的原料药。
  • MSDS 信息:1,5-Dibromopentane(111-24-0).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkanes 烷烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl