N,N-Bis(trifluoromethanesulfonyl)aniline N-苯基双(三氟甲烷磺酰)亚胺

CAS 37595-74-7 MFCD00000404

化学结构图

37595-74-7
SMILES: O=S(=O)(N(c1ccccc1)S(=O)(=O)C(F)(F)F)C(F)(F)F

化学属性

Mol. FormulaC8H5F6NO4S2
Mol. Weight357.25
Melting Point100-102°C
TSCANo
Density1.766
Stability对湿度敏感
Boiling Point305.3°C at 760 mmHg

别名和识别编码

Chemical NameN,N-Bis(trifluoromethanesulfonyl)aniline
CAS Number37595-74-7
Alfabeta NamePHENYLTRIFLUOROMETHANESULFONIMIDE N-
MDL NumberMFCD00000404
Synonym N,N-Bis(trifluoromethylsulfonyl)aniline {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {} {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {} {} {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {} {} {} {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {} {} {} {} {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {} {} {} {} {} {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {} {} {} {} {} {} {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {} {} {} {} {} {} {} {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {} {} {} {} {} {} {} {} {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {} {} {} {} {} {} {} {} {} {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Bis(trifluoromethylsulfonyl)aniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Bis(trifluoromethylsulfonyl)anil
PubChem Substance ID87575352
Beilstein Registry Number1269141
EC Number250-023-7
Reaxys-RN1269141
Chemical Name TranslationN-苯基双(三氟甲烷磺酰)亚胺
LabNetwork Molecule IDLN00008442
InChIInChI=1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H
Canonical SMILESO=S(N(C1=CC=CC=C1)S(C(F)(F)F)(=O)=O)(C(F)(F)F)=O
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分类

  • {SNA} Chemical Synthesis, Coupling, Synthetic Reagents, Triflate Formation

产品应用

  • 三氟甲基磺酰化(Triflating)试剂。

相关文献及参考

  • Convenient reagent for preparation of triflates of phenols and amines: Tetrahedron Lett., 4607 (1973); Org. Lett., 4, 1231 (2002); or of enol triflates from carbonyl compounds: Tetrahedron Lett., 24, 979 (1983); J. Org. Chem., 51, 277 (1986). For discussion of the reactivity of triflates, see Trifluoromethanesulfonic anhydride, A11767.

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C
Hazard Codes Xi

系列性分类


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