Ethyl trifluoromethanesulfonate 三氟甲烷磺酸乙酯

CAS 425-75-2 MFCD00000410

化学结构图

425-75-2
SMILES: CCOS(=O)(=O)C(F)(F)F

化学属性

Mol. FormulaC3H5F3O3S
Mol. Weight178.13
Boiling Point115 °C at 760 mmHg
Refractive index1.3360 to 1.3390
Density1.374
Flash Point35°C
TSCAYes
Stability对湿度敏感
Melting Point115-118°C

别名和识别编码

Chemical NameEthyl trifluoromethanesulfonate
CAS Number425-75-2
Alfabeta NameETHYLTRIFLUOROMETHANESULFONATE
MDL NumberMFCD00000410
PubChem Substance ID67924
EC Number207-037-3
Beilstein Registry Number1770746
Synonym Ethyl trifluoromethanesulfonate {LY} Ethyl trifluoromethanesulfonate {} {LY} Ethyl trifluoromethanesulfonate {} {} {LY} Ethyl trifluoromethanesulfonate {} {} {} {LY} Ethyl trifluoromethanesulfonate {} {} {} {} {LY} Ethyl trifluoromethanesulfonate {} {} {} {} {} {LY} Ethyl trifluoromethanesulfonate {} {} {} {} {} {} {LY} Ethyl trifluoromethanesulfonate {} {} {} {} {} {} {} {LY} Ethyl trifluoromethanesulfonate {} {} {} {} {} {} {} {} {LY} Ethyl trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {LY} Ethyl trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {LY} Ethyl trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl trifluoromethanesul
Reaxys-RN1770746
Chemical Name Translation三氟甲烷磺酸乙酯
InChIKeyUVECLJDRPFNRRQ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00112051
InChIInChI=1S/C3H5F3O3S/c1-2-9-10(7,8)3(4,5)6/h2H2,1H3
Canonical SMILESO=S(C(F)(F)F)(OCC)=O
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分类

  • {SNA} Acylation Reagents, Derivatization Reagents, Derivatization Reagents GC, Reagents for Acylation, 分析/色谱, 分析试剂
  • {SNA} Acylation Reagents, Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents GC, Reagents for Acylation
  • {SNA} Alkyl Transfer, C-X Bond Formation (Non-Halogen), Chemical Synthesis, Synthetic Reagents

安全信息

Warnings TOXIC, FLAMMABLE
GHS Symbol
WGK Germany2
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P203
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P317
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P317
  • P318
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 2920 2924
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} { {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C
Hazard Codes 8 C
Hazard Class3/8

其他信息

  • Sigma Aldrich:425-75-2(sigmaaldrich)
  • TCI Shanghai:三氟甲基磺酸乙酯 Ethyl Trifluoromethanesulfonate,>;98.0%(GC)(425-75-2)
  • Acros Organics:Ethyl trifluoromethanesulfonate, 98%(425-75-2)
  • Hazard Note:Highly Toxic
  • 三氟甲烷磺酸乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1191 三氟甲基磺酸乙酯 Ethyl Trifluoromethanesulfonate 25G 1950元 2014/06/02 T1191 三氟甲基磺酸乙酯 Ethyl Trifluoromethanesulfonate 5G 588元 2010/06/21 311850250 三氟甲烷磺酸乙酯 Ethyl trifluoromethanesulfonate 98% 25 GR 2500元
  • MSDS 信息:Ethyl trifluoromethanesulfonate (425-75-2).msds
  • F:3
  • MOL 文件:425-75-2.mol
  • Alfa Aesar:三氟甲烷磺酸乙酯,99% Ethyl trifluoromethanesulfonate, 99%(425-75-2)
  • 敏感性:Hygroscopic

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Acylation Reagents - Derivatization Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Acylation - Derivatization Reagents GC
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Non-Halogen) - Synthetic Reagents
  4. Alkyl Transfer - C-X Bond Formation (Non-Halogen)
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Non-Halogen) - Synthetic Reagents
  4. Alkyl Transfer - C-X Bond Formation (Non-Halogen)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Tosylates - Sulfur Compounds

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