N-Methyl-bis(trifluoroacetamide) N-甲基-双(三氟乙酰胺)

CAS 685-27-8 MFCD00000412

化学结构图

685-27-8
SMILES: CN(C(=O)C(F)(F)F)C(=O)C(F)(F)F

化学属性

Mol. FormulaC5
Mol. Weight223
Density1.547
Refractive indexn20/D 1.346(lit.)
Boiling Point121-122
Flash Point45°C(lit.)

别名和识别编码

Chemical NameN-Methyl-bis(trifluoroacetamide)
CAS Number685-27-8
Alfabeta NameTRIFLUOROMETHYLTRIFLUOROACETYLACETAMIDE NN222222()------,,,,
MDL NumberMFCD00000412
Synonym 2,2,2-Trifluoro-N-methyl-N-(2,2,2-trifluoroacetyl)acetamide 2,2,2-trifluoro-N-methyl-N-(trifluoroacetyl)acetamide Acetamide, 2,2,2-tr MBTFA (N-methyl-bis(trifluoroacetami MBTFA (N-methyl-bis(trifluoroacetamide)or BTFA (bis(TFA)) MBTFA MBTFA~N-Methyl(trifluoroacetyl)imide N,N-BIS(TRIFLUOROACETYL)METHYLAMINE N-METHYLBIS(TRIFLUOROACETAMIDE), 97%, DERIVATIZATION GRADE N-Methyl-bis-trifluoracetamid N-Methylbis(trifluoracetamid) N-Methylbis(trifluoroacetamide) 99+% N-Methylbis(trifluoroacetamide)(trifluoroacylatingagent) N-Methylbis(trifluoroacetamide)98% N-methyl-bis(trifluoroacetamide) N-methyl-bis-(tri-fluoroacetamide) N-methyl-bis-trifluoroacetamide N-甲基-双(三氟乙酰胺) N-甲基二(三氟乙酰胺) N-甲基双三氟乙酰胺 N-甲基对三氟乙酰胺
EC Number211-680-5
Beilstein Registry Number1878402
PubChem Substance ID69635
Reaxys-RN1878402
Chemical Name TranslationN-甲基-双(三氟乙酰胺)
InChIKeyAWGBWLXGUPTXHF-UHFFFAOYSA-N
LabNetwork Molecule IDLN00159632
InChIInChI=1S/C5H3F6NO2/c1-12(2(13)4(6,7)8)3(14)5(9,10)11/h1H3
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分类

  • {SNA} β-Glucuronidase, β-Glucuronidase Drug Analysis Bundle, Acylation Reagents, Analytical Reagents, Analytical and Industrial Enzymes, Analytical/Chromatography, Biochemicals and Reagents, Derivatization Reagents, Derivatization Reagents GC, Enzymes, Inhibitors, and Substrates, MBTFA - N-methyl-bis-trifluoroacetamide,

产品应用

  • 用于引入三氟乙酰基团的试剂。

相关文献及参考

  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard Codes C
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number
Packing GroupII
Storage condition 2-8℃储存 2-8°C
Hazard Class8/3

其他信息

  • MSDS 信息:2,2,2-Trifluoro-N-methyl-N-(trifluoroacetyl)acetamide(685-27-8).msds
  • 图谱信息:N-甲基二(三氟乙酰胺)(685-27-8)核磁图( 1 HNMR) N-甲基二(三氟乙酰胺)(685-27-8)核磁图( 13 CNMR) N-甲基二(三氟乙酰胺)(685-27-8)红外图谱(IR1) N-甲基二(三氟乙酰胺)(685-27-8)质谱(MS)
  • N-甲基二(三氟乙酰胺)价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0671 N-甲基双(三氟乙酰胺)[三氟酰化剂] N-Methylbis(trifluoroacetamide) [Trifluoroacylating Agent] 5ML 1720元 2014/06/02 M0671 N-甲基双(三氟乙酰胺)[三氟酰化剂] N-Methylbis(trifluoroacetamide) [Trifluoroacylating Agent] 1ML 554元
  • 敏感性:Moisture Sensitive
  • Sigma Aldrich:685-27-8(sigmaaldrich)
  • F:10-21
  • TCI Shanghai:N-甲基双(三氟乙酰胺)[三氟酰化剂] N-Methylbis(trifluoroacetamide) [Trifluoroacylating Agent],>;97.0%(GC)(685-27-8)
  • Hazard Note:Corrosive/Moisture Sensitive
  • MOL 文件:685-27-8.mol

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Luminescent Compounds/Detection - Biochemicals and Reagents
  4. Derivatization agents - Luminescent Compounds/Detection
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Luminescent Compounds/Detection - Biochemicals and Reagents
  4. Luminescent conjugates - Luminescent Compounds/Detection
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Acylation - Derivatization Reagents GC
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Amides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Enzymes, Inhibitors, and Substrates - Biochemicals and Reagents
  4. Analytical Enzymes - Enzymes, Inhibitors, and Substrates
  5. β-Glucuronidase - Analytical Enzymes
  6. β-Glucuronidase Drug Analysis Bundle - β-Glucuronidase
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents

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