2,2,2-Trifluoroethyl trifluoroacetate 2,2,2-三氟乙基三氟乙酯

CAS 407-38-5 MFCD00000418

化学结构图

407-38-5
SMILES: O=C(OCC(F)(F)F)C(F)(F)F

化学属性

Mol. FormulaC4H2F6O2
Mol. Weight196
Boiling Point55
Melting Point-65.5°
Refractive indexn20/D 1.277(lit.)
Density1.464
Flash Point0°C(lit.)
TSCANo
Vapor Pressure3.34 psi ( 20 °C)

别名和识别编码

Chemical Name2,2,2-Trifluoroethyl trifluoroacetate
CAS Number407-38-5
Alfabeta NameTRIFLUOROETHYLTRIFLUOROACETATE 222-,,
MDL NumberMFCD00000418
PubChem Substance ID67888
EC Number206-985-5
Reaxys-RN1783427
Beilstein Registry Number1783427
Synonym 2,2,2-TRIFLUOROETHYL TRIFLUOROACETATE 2,2,2-Trifluoroethyl trifluoroacetate 98% 2,2,2-Trifluoroethyltrifluoroacetate98% 2,2,2-trifluoroethyl trifluoroacetate 2,2,2-三氟乙基三氟乙酯 Trifluoressigsäure-2,2,2-trifluorethylester Trifluoroacetic acid 2,2,2-trifluoroethyl ester Trifluoroacetic acid 2,2,2-trifluoroethylester Trifluoroacetic acid trifluoroethyl ester acetic acid, trifluoro-, 2,2,2-trifluoroethyl ester ethanol, 2,2,2-trifluoro-, trifluoroacetate ethanol,2,2,2-trifluoro-,trifluoroacetate {} {} {} {} {uni_hamburg}
Chemical Name Translation2,2,2-三氟乙基三氟乙酯
InChIKeyZKUJOCJJXCPCFS-UHFFFAOYSA-N
LabNetwork Molecule IDLN00115422
InChIInChI=1S/C4H2F6O2/c5-3(6,7)1-12-2(11)4(8,9)10/h1H2
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {uni_hamburg} no charge; ester; 1fragment
  • Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • {SNA} Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

相关文献及参考

  • Short: IV/18B
  • Short: IV/20B
  • In the conversion of ketones to diazo ketones, was found to be superior to other acylating agents for activation of the ketone enolates to diazo transfer by sulfonyl azides: J. Org. Chem., 55, 1959 (1990).
  • Short: IV/20A
  • Short: EINECS

安全信息

Warnings FLAMMABLE, CORROSIVE
GHS Symbol
WGK Germany3
Hazard Codes 3 F,C
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2924 UN2924
Risk Statements
  • R11 Highly flammable 非常易燃
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Packing GroupII
Hazard Class3/8
Storage condition Flammables area

其他信息

  • Sigma Aldrich:407-38-5(sigmaaldrich)
  • TCI Shanghai:三氟乙酸-2,2,2-三氟乙酯 2,2,2-Trifluoroethyl Trifluoroacetate,>;96.0%(GC)(407-38-5)
  • 三氟乙酸2,2,2-三氟乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1697 三氟乙酸2,2,2-三氟乙酯 2,2,2-Trifluoroethyl Trifluoroacetate 25G 422元 2010/06/21 385321000 三氟乙酸2,2,2-三氟乙酯 Trifluoroacetic acid 2,2,2-trifluoroethyl ester 98% 100 GR 1000元 2010/06/21 385320250 三氟乙酸2,2,2-三氟乙酯 Trifluoroacetic acid 2,2,2-trifluoroethyl ester 98% 25 GR 305元
  • 蒸气压:3.34 psi ( 20 °C)
  • Hazard Note:Flammable/Corrosive
  • Acros Organics:Trifluoroacetic acid 2,2,2-trifluoroethyl ester, 98%(407-38-5)
  • Alfa Aesar:2,2,2-三氟乙基三氟乙酯,98% 2,2,2-Trifluoroethyl trifluoroacetate, 98%(407-38-5)
  • MOL 文件:407-38-5.mol

系列性分类


相关产品推荐