1,1,1,5,5,5-Hexafluoroacetylacetone 六氟乙酰丙酮
CAS 1522-22-1 MFCD00000426
化学结构图
SMILES: O=C(CC(=O)C(F)(F)F)C(F)(F)F
化学属性
| Mol. Formula | C5H2F6O2 |
|---|---|
| Mol. Weight | 208 |
| Boiling Point | 70-71 |
| TSCA | T |
| Refractive index | 1.3310 to 1.3360 |
| Density | 1.47 |
| Flash Point | 32°C(lit.) |
| Stability | 易吸潮 |
别名和识别编码
| Chemical Name | 1,1,1,5,5,5-Hexafluoroacetylacetone |
|---|---|
| CAS Number | 1522-22-1 |
| Alfabeta Name | HEXAFLUOROPENTANEDIONE 11155524---,,,,,, |
| MDL Number | MFCD00000426 |
| Synonym | 1,1,1,5,5,5-HEXAFLUOROACETYLACETONATE 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione 1,1,1,5,5,5-Hexafluoroacetylacetone 1,1,1,5,5,5-Hexafluoroacetylacetone 99% 1,1,1,5,5,5-Hexafluoropentane-2,4-dione [HFAA] 1,1,1,5,5,5-hexafluoro-pentan-2,4-dione 1,1,1,5,5,5-六氟戊烷-2,4-二酮 1,1,1,5,5-HEXAFLUORO-2,4-PENTANDIONE 1,3-Bis(trifluoromethyl)propane-1,3-dione 3H,3H-hexafluoro-pentane-2,4-dione 3H,3H-hexafluoroacetylacetone Acetylacetone, hexafluoro C5H2F6O2 (1,1,1,5,5,5-hexafluoro-pentan-2,4-dione) HFAA HFAC |
| PubChem Substance ID | 87570873 |
| EC Number | 216-191-0 |
| Beilstein Registry Number | 1790138 |
| Reaxys-RN | 1790138 |
| Chemical Name Translation | 六氟乙酰丙酮 |
| InChIKey | QAMFBRUWYYMMGJ-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00116674 |
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分类
- {uni_hamburg} no charge; ketone; 1fragment
- {SNA} Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
- Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
相关文献及参考
- Beil. 1 ,IV,3681
- Aldrich MSDS 1 , 1023:B / Corp MSDS 1 (1), 1847:A / FT-IR 2 (1), 668:B / FT-IR 1 (1), 426:A / FT-NMR 1 (1), 662:C / RegBook 1 (1), 465:L / Structure Index 1 , 66:E:5 / Vapor Phase 3 , 511:D
- Short: IV/15A Title: Diffusion in Gases, Liquids and Electrolytes: Gases in Gases, Liquids and their Mixtures Author: Winkelmann, J Editor: Lechner, Manfred Dieter Source: Landolt-Börnstein, New Series Volume: IV/15A Year: 2007 Keyword: binary mixture; diffusion; electrolyte; gas; liquid; quaternary mixture; self-diffusion; supercritical fluid system; ternary mixture; vapor ISBN: 978-3-540-62429-5 (print) ISBN: 978-3-540-49718-9 (online) Internet Resource: doi:10.1007/978-3-540-49718-9 RefComment: VIII, 409 p., Hardcover RefComment: Written for: Science and engineers in the fields of physics, chemistry, physical chemistry, and material sciences Abstract: Diffusion – defined as mass, amount, or particle transport process – is the most essential transport property besides viscosity and thermal conductivity. Diffusion is widely used in nature, technical and scientific applications, ranging from diffusion in all kinds of gases, liquids, solids, electrolytes and their mixtures. Due to the large amount of data, the volume LB IV/15 "Diffusion in Gases, Liquids, and Electrolytes" is divided into three subvolumes. Part A: Gases in Gases, Liquids and their Mixtures; Part B: Liquids in Liquids and Liquid Mixtures; Part C: Ions and Electrolytes in Liquids, Electrolytes and Molten Salts. The presented subvolume A includes the main chapters Measurement Methods, Diffusion in Pure Gases, Diffusion in Gaseous Mixtures, Diffusion of Gas/Vapor in Gases or Liquids and Diffusion of Gases in Solution. Due to the very different and widespread measurement methods, a precise description of these methods is given.
- Short: IV/18B Title: Viscosity of Pure Organic Liquids and Binary Liquid
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H332 Harmful if inhaled 吸入有害
- H312 Harmful in contact with skin 皮肤接触有害
- H302 Harmful if swallowed 吞食有害
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- R10 Flammable 易燃
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R22 Harmful if swallowed 吞咽有害
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R37 Irritating to respiratory system 刺激呼吸道
其他信息
- MOL 文件:1522-22-1.mol
- 检测方法:GC
- 六氟乙酰丙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0476 六氟乙酰丙酮 Hexafluoroacetylacetone 5G 301元 2014/06/02 H0476 六氟乙酰丙酮 Hexafluoroacetylacetone 25G 1020元 2010/06/21 218530250 六氟乙酰丙酮 1,1,1,5,5,5-Hexafluoroacetylacetone 99% 25 GR 1515元
- 上游原料:乙醇 --> 甲醇 --> 乙醚 --> 硫酸 --> 四氢呋喃 --> 钠 --> N,N-二甲基甲酰胺 --> 甲苯 --> 镁 --> 甲醇钠 --> 甲基叔丁基醚 --> 二丁醚 --> 三氟乙酸乙酯 --> 1,1,1-三氟丙酮
- TSCA:T
- F:3
- Sigma Aldrich:1522-22-1(sigmaaldrich)
- 图谱信息:六氟乙酰丙酮(1522-22-1)红外图谱(IR1) 六氟乙酰丙酮(1522-22-1)质谱(MS) 六氟乙酰丙酮(1522-22-1)核磁图( 13 CNMR)
- Hazard Note:Flammable/Corrosive
- 敏感性:Hygroscopic
- 下游产品:2,2,2-三氟-1-(1-甲基-3-三氟甲基-1H-吡唑-4-基)乙酮 --> 1-苯基-5-三氟甲基-1H-吡唑 --> 1-(1-甲基-3-三氟甲基-1H-吡唑-4-基) -2,2,2-三氟-乙酮
- Acros Organics:六氟乙酰丙酮 1,1,1,5,5,5-Hexafluoroacetylacetone, 96%(1522-22-1)
- TCI Shanghai:六氟乙酰基丙酮 Hexafluoroacetylacetone,>;95.0%(GC)(1522-22-1)
- Alfa Aesar:1，1，1，5，5，5-六氟代-乙酰丙酮,98+% 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 98+%(1522-22-1)
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