Perfluorotributylamine 二十七氟三丁基胺
CAS 311-89-7 MFCD00000436
化学结构图
SMILES: FC(F)(F)C(F)(F)C(F)(F)C(F)(F)N(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
化学属性
| Mol. Formula | C12F27N |
|---|---|
| Mol. Weight | 671.10 |
| Boiling Point | 178 |
| TSCA | Y |
| Density | 1.883 |
| Refractive index | 1.2890 |
| Melting Point | -52 °C |
| Vapor Density | 23.3 (vs air) |
| Vapor Pressure | 1.3 mmHg ( 25 °C) |
| Solubility | 不溶 |
| Flash Point | None |
| Appearance | liquid 全氟三丁胺(311-89-7)为无色液体。熔点-66℃，沸点177℃，相对密度1.872（25/4℃），折光率1.2910（25℃）。溶于丙酮。是一种惰性液体。 |
别名和识别编码
| Chemical Name | Perfluorotributylamine |
|---|---|
| CAS Number | 311-89-7 |
| Alfabeta Name | PERFLUOROTRIBUTYLAMINE N-- |
| MDL Number | MFCD00000436 |
| Synonym | Perfluorotributylamine {LY} Perfluorotributylamine {} {LY} Perfluorotributylamine {} {} {LY} Perfluorotributylamine {} {} {} {LY} Perfluorotributylamine {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} { |
| PubChem Substance ID | 125309938 |
| EC Number | 206-223-1 |
| Beilstein Registry Number | 2(4)819 |
| Reaxys-RN | 1813883 |
| Chemical Name Translation | 二十七氟三丁基胺 |
| LabNetwork Molecule ID | LN00119252 |
| InChI | InChI=1S/C12F27N/c13-1(14,7(25,26)27)4(19,20)10(34,35)40(11(36,37)5(21,22)2(15,16)8(28,29)30)12(38,39)6(23,24)3(17,18)9(31,32)33 |
| Canonical SMILES | FC(N(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)(F)C(F)(F)C(F)(F)C(F)(F)F |
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分类
- {SNA} Alphabetic, Analytical Standards, Analytical/Chromatography, H, HA -HT, MS Markers, MS Standards, Physical Properties, Single Compounds, Spectroscopy
- {SA} Alphabetic, Analytical Standards, Analytical/Chromatography, H, HA -HT, MS Markers, MS Standards, Physical Properties, Single Compounds, Spectroscopy
- {SNA} Additional Standards, Analytical Standards, MS Markers, MS Standards, Organic Pollutant Standards, Perfluoro Compounds, Physical P
相关文献及参考
- Short: II/27B
- Short: II/5
- Standard for use in mass spectrometry.
- Short: III/38B
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P302+P352+P332+P313+P362+P364
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >10 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0533842
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 12 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : MIVRA6 Microvascular Research. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1968- Volume(issue)/page/year: 8,320,1974
其他信息
- 图谱信息:全氟三丁胺(311-89-7)质谱(MS) 全氟三丁胺(311-89-7)红外图谱(IR2) 全氟三丁胺(311-89-7)红外图谱(IR1)
- 全氟三丁胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 P0074 全氟三丁胺[用于质谱法] Heptacosafluorotributylamine [for Mass spectrometry] 25G 780元 2010/06/21 123772500 全氟三丁胺 Perfluoro-compound FC-43™ 250 GR 8453元 2010/06/21 123770100 全氟三丁胺 Perfluoro-compound FC-43™ 10 GR 533元
- 全氟三丁胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0074 全氟三丁胺[用于质谱法] Heptacosafluorotributylamine [for Mass spectrometry] 25G 350元 2010/06/21 123772500 全氟三丁胺 Perfluoro-compound FC-43™ 250 GR 8453元 2010/06/21 123770100 全氟三丁胺 Perfluoro-compound FC-43™ 10 GR 533元
- Alfa Aesar:全氟三正丁胺,tech.90% Perfluorotri-n-butylamine, tech. 90%(311-89-7)
- 用途二:该品对热和化学稳定性好，有良好的润滑性和耐磨性、优良的介电性能和耐腐蚀性能，可用作仪表隔离液、导热冷却剂，在高频系统的无件中作为绝缘介质，利用其表面张力小的特点，可用作石油破乳剂。还可与四氟乙烯混合制备氟酯。
- 蒸气密度:23.3 (vs air)
- 方法一:由三丁胺与氟化氢通过电解氟化而得。电解产物经水洗、碱洗、干燥、精馏而得成品。
- 用途一:导热热冷却剂
- 上游原料:三正丁胺
- MOL 文件:311-89-7.mol
- 凝固点:-60℃
- 蒸气压:1.3 mm Hg ( 25 °C)
- Acros Organics:全氟三丁胺 Perfluoro-compound FC-43?(311-89-7)
- Sigma Aldrich:311-89-7(sigmaaldrich)
- MSDS 信息:Heptacosafluorotributylamine(311-89-7).msds
- TSCA:T
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